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Properties of barium hexaferrite prepared by electric field assisted self-propagating high-temperature synthesis

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Inorganic Materials Aims and scope

Abstract

We have prepared ferromagnetic barium hexaferrite powders by self-propagating high-temperature synthesis (SHS) in an electric field applied by a contactless method. Our results indicate that the field strength has a significant effect on the phase composition of the synthesis product. This effect is interpreted in terms of the decomposition kinetics of the solid oxidant and reactant diffusion. Microstructural examination demonstrates that an electric field has a marked effect on the morphology of SHS materials. The magnetic properties of the synthesized powders depend significantly on both the strength and direction of the applied field.

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References

  1. Merzhanov, A.G., Combustion and Detonation Processes in the Physical Chemistry and Technology of Inorganic Materials, Usp. Khim., 2003, vol. 72, no. 3, pp. 323–345.

    Google Scholar 

  2. Parkin, I.P., Elwin, G.E., Komarov, A.V., et al., Convenient, Low Energy Routs to Hexagonal Ferrites MFe12O19 (M = Sr, Ba) from SHS Reactions of Iron, Iron Oxide, and MO2 in Air, J. Mater. Chem., 1998, vol. 8, no. 3, pp. 573–578.

    Article  CAS  Google Scholar 

  3. Martirosyan, K.S., Avakyan, P.B., and Nersesyan, M.D., Ferrite Formation by Self-propagating High-Temperature Synthesis, Neorg. Mater., 2002, vol. 38, no. 4, pp. 489–492 [Inorg. Mater. (Engl. Transl.), vol. 38, no. 4, pp. 400–403].

    Article  Google Scholar 

  4. Maksimov, Yu.M., Itin, V.I., Smolyakov, V.K., et al., SHS in Electric and Magnetic Fields, Int. J. Self-Propag. High-Temp. Synth., 2001, vol. 10, no. 7, pp. 295–331.

    CAS  Google Scholar 

  5. Affleck, L., Aguas, M.D., Parkin, I.P., et al., Microstructural Aspects of the Self-propagating High-Temperature Synthesis of Hexagonal Barium Ferrite in External Magnetic Field, J. Mater. Chem., 2000, vol. 10, no. 8, pp. 1925–1932.

    Article  CAS  Google Scholar 

  6. Aguas, M.D., Affleck, L., Parkin, I.P., et al., The Effect of Large Magnetic Fields on Solid State Combustion Reactions: Novel Microstructure, Lattice Contraction, and Reduced Coercivity in Barium Hexaferrite, J. Mater. Chem., 2000, vol. 10, no. 2, pp. 235–237.

    Article  CAS  Google Scholar 

  7. Morozov, Yu.G., The Role of Ions Thermal Diffusion in Self-propagating High-Temperature Synthesis, Adv. Sci. Technol., 2000, vol. 29, pp. 913–924.

    CAS  Google Scholar 

  8. Munir, Z.A., Electrically Stimulated SHS, Int. J. Self-Propag. High-Temp. Synth., 1997, vol. 6, no. 2, pp. 165–185.

    CAS  Google Scholar 

  9. Graeve, O.A. and Munir, Z.A., The Effect of An Electric Field on the Microstructural Development during Combustion Synthesis of TiNi-TiC Composites, J. Alloys Compd., 2002, vol. 340, nos. 1–2, pp. 79–87.

    Article  CAS  Google Scholar 

  10. Busurin, S.M., Morozov, Yu.G., Kuznetsov, M.V., et al., Effect of a DC Electric Field on the Self-propagating High-Temperature Synthesis of Manganese Ferrite, Fiz. Goreniya Vzryva, 2005, vol. 41, no. 4, pp. 67–73.

    CAS  Google Scholar 

  11. Martirosyan, K.S., Avakyan, P.B., Morozov, Yu.G., et al., Self-propagating High-Temperature Synthesis of Barium Hexaferrite, Preprint of Inst. of Structural Macrokinetics, USSR Acad. Sci., Chernogolovka, 1990.

  12. Efimov, A.I., Belorukova, L.P., Vasil’kova, I.V., et al., Svoistva neorganicheskikh soedinenii (Properties of Inorganic Compounds), Moscow: Khimiya, 1983.

    Google Scholar 

  13. Busurin, S.M., Morozov, Yu.G., Kuznetsov, M.V., et al., Role of Solid Oxidants in Electric Field Assisted Self-propagating High-Temperature Synthesis of Ferrites, I Vserossiiskaya shkola-konferentsiya Molodye uchenye—Novoi Rossii “Fundamental’nye issledovaniya v oblasti khimii i innovatsionnaya deyatel’nost’” (I All-Russia School-Conf. Young Scientists for New Russia: Basic Research and Innovative Technologies in Chemistry), Ivanovo: Izd. Ivanovo, 2005, p. 10.

    Google Scholar 

  14. Parkansky, N., Alterkop, B., Goldsmith, S., et al., The Effect of an Electric Field on the High Temperature Oxidation of Copper in Air, Surf. Coat. Technol., 1999, vols. 120–121, pp. 668–671.

    Article  Google Scholar 

  15. Dem’yanets, L.N., Ivanov-Shits, A.K., Kireev, V.V., and Ksenofontov, D.A., Electric-Field Effect on Crystallization in the Li3PO4-Li4GeO4-Li2MoO4-LiF System, Neorg. Mater., 2004, vol. 40, no. 8, pp. 1001–1005 [Inorg. Mater. (Engl. Transl.), vol. 40, no. 8, pp. 874–877].

    Google Scholar 

  16. Cross, W.B., Affleck, L., and Kuznetsov, M.V., Self-propagating High-Temperature Synthesis of Ferrites MFe2O4 (M = Mg, Ba, Co, Ni, Cu, Zn): Reactions in an External Magnetic Field, J. Mater. Chem., 1999, vol. 9, no. 10, pp. 2545–2552.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Institutskaya ul. 8, Chernogolovka, Moscow oblast, 142432, Russia

    S. M. Busurin, Yu. G. Morozov, M. V. Kuznetsov, M. L. Chernega & A. A. Chobko

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  1. S. M. Busurin
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  2. Yu. G. Morozov
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  3. M. V. Kuznetsov
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  4. M. L. Chernega
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  5. A. A. Chobko
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Additional information

Original Russian Text © S.M. Busurin, Yu.G. Morozov, M.V. Kuznetsov, M.L. Chernega, A.A. Chobko, 2006, published in Neorganicheskie Materialy, 2006, Vol. 42, No. 12, pp. 1503–1507.

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Busurin, S.M., Morozov, Y.G., Kuznetsov, M.V. et al. Properties of barium hexaferrite prepared by electric field assisted self-propagating high-temperature synthesis. Inorg Mater 42, 1374–1378 (2006). https://doi.org/10.1134/S0020168506120168

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  • DOI: https://doi.org/10.1134/S0020168506120168

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