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Temperature effect on the structure of ZnSe layers grown by chemical vapor deposition

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Abstract

The heat exchange between the substrate, growing layer, and gas flow in a CVD reactor is analyzed theoretically. The results indicate that the temperature of the gas mixture in the reactor influences the surface temperature of the polycrystalline zinc selenide deposit. Experimental data are presented on the variation of the average grain size across the ZnSe deposit. The thermal conditions of CVD and secondary crystallization during long-term deposition are shown to have a significant effect on the depth distribution of the grain size.

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References

  1. Gavrishchuk, E.M., Polycrystalline Zinc Selenide for IR Optical Applications, Neorg. Mater., 2003, vol. 39, no. 9, pp. 1031–1049 [Inorg. Mater. (Engl. Transl.), vol. 39, no. 9, pp. 883–898].

    Google Scholar 

  2. Devyatykh, G.G., Dadanov, A.Yu., and Gavrishchuk, E.M., Pressure and Temperature Effects on Zinc Selenide Chemical Vapor Deposition, Dokl. Akad. Nauk SSSR, 1990, vol. 311, no. 2, pp. 368–369.

    CAS  Google Scholar 

  3. Volkov, S.Y., Kozlov, D.N., Smirnov, V.V., and Marowsky, G., Temperature Distribution above a Heated Surface in a CVD Reactor with Hydrocarbon-Containing Gaseous Mixtures, Appl. Phys. B, 2000, vol. 70, pp. 123–126.

    Article  CAS  Google Scholar 

  4. Markham, J.R., Best, P.E., and Solomon, P.R., Spectroscopic Method for Measuring Surface Temperature That Is Independent of Material Emissivity, Surrounding Radiation Sources, and Instrument Calibration, Appl. Spectrosc., 1994, vol. 48, no. 2, pp. 265–270.

    Article  CAS  Google Scholar 

  5. Isachenko, V.P., Osipova, V.A., and Sukomel, A.S., Teploperedacha (Heat Transfer), Moscow: Energoizdat, 1981.

    Google Scholar 

  6. Schlichting, H., Boundary Layer Theory, New York: McGraw-Hill, 1974.

    Google Scholar 

  7. Lucheva, N.V., Luchev, S.M, and Dunaev, A.A., Thermal Conductivity of Polycrystalline Zinc Selenide, Fiz. Tverd. Tela (S.-Peterburg), 2003, vol. 45, no. 3, pp. 424–428.

    Google Scholar 

  8. Krainov, V.P., Kachestvennye metody v fizicheskoi kinetike i gidrogazodinamike (Qualitative Methods in Physical Kinetics and Fluid Dynamics), Moscow: Vysshaya Shkola, 1989.

    Google Scholar 

  9. Vargaftik, N.B., Spravochnik po teplofizicheskim svoistvam gazov i zhidkostei (Thermophysical Properties of Gases and Liquids: A Handbook), Moscow: Nauka, 1972.

    Google Scholar 

  10. Izbrannye metody issledovaniya v metallografii (Selected Metallographic Techniques), Hunger, R., Ed., Moscow: Metallurgiya, 1985, pp. 73–103.

    Google Scholar 

  11. Vladyko, M.N., Kolchin, V.A., Tatarchenko, V.A., et al., Structure and Properties of High-Purity Polycrystalline Zinc Selenide, Vysokochist. Veshchestva, 1988, no. 2, pp. 217–221.

  12. Gavrishchuk, E.M., Salganskii, Yu.M., and Sidorov, V.A., Effect of Reagent Concentrations on the Grain Size of Chemical-Vapor-Deposited ZnSe, Neorg. Mater., 2001, vol. 37, no. 3, pp. 278–282 [Inorg. Mater. (Engl. Transl.), vol. 37, no. 3, pp. 216–219].

    Article  Google Scholar 

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Original Russian Text © E.M. Gavrishchuk, V.B. Ikonnikov, L.A. Kuznetsov, S.M. Mazavin, 2006, published in Neorganicheskie Materialy, 2006, Vol. 42, No. 12, pp. 1428–1433.

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Gavrishchuk, E.M., Ikonnikov, V.B., Kuznetsov, L.A. et al. Temperature effect on the structure of ZnSe layers grown by chemical vapor deposition. Inorg Mater 42, 1302–1307 (2006). https://doi.org/10.1134/S0020168506120041

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  • DOI: https://doi.org/10.1134/S0020168506120041

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