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Effects of iso-and heterovalent substitutions on the luminescent properties of CdS in the systems Zn, Cd ‖ S, Te and In(III), Cd ‖ S, Te

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Abstract

We have studied the luminescent properties of three CdS-based solid-solution series, resulting from isovalent anion substitution (CdS1−x Tex), isovalent cation and anion substitutions (Cd1−x ZnxS1−x Tex), and heterovalent cation substitution in combination with isovalent anion substitution (Cd1−x In2x/3S1−x Tex). The last two systems have been studied for the first time. The results demonstrate that red or near-IR lumiescence occurs in the three systems, but CdS crystals codoped with In and Te are more attractive because of the high impurity-related emission intensity at rather low In and Te concentrations.

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Original Russian Text © I.N. Odin, M.V. Chukichev, E.V. Visitskii, M.E. Rubina, N.A. Mazov, 2006, published in Neorganicheskie Materialy, 2006, Vol. 42, No. 10, pp. 1159–1163.

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Odin, I.N., Chukichev, M.V., Visitskii, E.V. et al. Effects of iso-and heterovalent substitutions on the luminescent properties of CdS in the systems Zn, Cd ‖ S, Te and In(III), Cd ‖ S, Te. Inorg Mater 42, 1053–1057 (2006). https://doi.org/10.1134/S0020168506100013

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  • DOI: https://doi.org/10.1134/S0020168506100013

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