Skip to main content
Log in

LiCoO2-and LiMn2O4-based composite cathode materials

  • Published:
Inorganic Materials Aims and scope

Abstract

We have prepared composite cathode materials based on two electrochemically active compounds, LiCoO2 and LiMn2O4, and investigated their properties. The results indicate that the discharge capacities of all the materials studied exceed the additivity rule values calculated from the discharge capacities of the starting materials. The effect of heat treatment on the physicochemical properties of the composites is analyzed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Tarascon, J.M. and Guyomard, D., Li Metal-Free Rechargeable Batteries Based on Li1−x Mn2O4 Cathodes (0 ≤ x ≤ 1) and Carbon Anodes, J. Electrochem. Soc., 1991, vol. 138, pp. 2864–2868.

    Article  CAS  Google Scholar 

  2. Xia, Y. and Yoshio, M., An Investigation of Lithium Ion Insertion into Spinel Structure Li-Mn-O Compounds, J. Electrochem. Soc., 1996, vol. 143, pp. 825–833.

    Article  CAS  Google Scholar 

  3. Delmas, C. and Saadoune, I., Electrochemical and Physical Properties of the LixNi1−y CoyO2 Phases, Solid State Ionics, 1992, vol. 53/56, pp. 370–375.

    Article  Google Scholar 

  4. Todorov, Y.M., Hideshima, Y., Noguchi, H., and Yoshio, M., Determination of Theoretical Capacity of Metal Ion-Doped LiMn2O4 as the Positive Electrode in Li-Ion Batteries, J. Power Sources, 1999, vol. 77, pp. 198–201.

    Article  CAS  Google Scholar 

  5. Ehrlich, G.M., Puglia, F.J., Gizendanner, R., et al., Flat Plate Prismatic Li-Ion Cells Using Advanced Cathode Materials, J. Power Sources, 1999, vol. 81/82, pp. 863–866.

    Article  Google Scholar 

  6. Kumagai, N., Fujiwara, T., Tanno, K., and Hariba, T., Physical and Electrochemical Characterization of Quaternary Li-Mn-V-O Spinel as Positive Materials for Rechargeable Lithium Batteries, J. Electrochem. Soc., 1996, vol. 143, pp. 1007–1013.

    Article  CAS  Google Scholar 

  7. Cho, J., Kim, Y.J., and Park, B., Structural Changes of Li3.1Mn0.91Cr1.09O4 Cathode Material, Solid State Ionics, 2001, vol. 138, pp. 221–225.

    Article  CAS  Google Scholar 

  8. Kim, J. and Amine, K., A Comparative Study on the Substitution of Divalent, Trivalent, and Tetravalent Metal Ions in LiNi1−x MxO2 (M = Cu2+, Al3+, and Ti4+), J. Power Sources, 2002, vol. 104, pp. 33–39.

    Article  CAS  Google Scholar 

  9. Ohzuku, T. and Makimura, Y., Layered Lithium Insertion Material of LiNi1/2Mn1/2O2: A Possible Alternative to LiCoO2 for Advanced Lithium-Ion Batteries, Chem. Lett., 2001, vol. 30, pp. 744–745.

    Article  Google Scholar 

  10. Kang, S.-H. and Amine, K., Comparative Study of Li(Ni0.5−x Mn0.5−x M′2x )O2 (M′= Mg, Al, Co, Ni, Ti; x = 0, 0.025) Cathode Materials for Rechargeable Lithium Batteries, J. Power Sources, 2003, vols. 119–121, pp. 150–155.

    Article  Google Scholar 

  11. Makhonina, E.V., Pervov, V.S., and Dubasova, V.S., Oxide Materials for the Positive Electrode of Rechargeable Lithium Batteries, Usp. Khim., 2004, vol. 73, pp. 1075–1087.

    Google Scholar 

  12. Fey, G.T.K., Chen, J.G., and Subramanian, V., Electroanalytical and Thermal Stability Studies of Multi-Doped Lithium Nickel Cobalt Oxides, J. Power Sources, 2003, vols. 119–121, pp. 658–663.

    Article  Google Scholar 

  13. Shaju, K.M., Subba Rao, G.V., and Chowdari, B.V.R., X-ray Photoelectron Spectroscopy and Electrochemical Behaviour of 4 V Cathode, Li(Ni1/2Mn1/2)O2, Electrochim. Acta, 2003, vol. 48, pp. 1505–1514.

    Article  CAS  Google Scholar 

  14. Shaju, K.M., Subba Rao, G.V., and Chowdari, B.V.R., Performance of Layered Li(Ni1/3Co1/3Mn1/3)O2 as Cathode for Li-Ion Batteries, Electrochim. Acta, 2002, vol. 48, pp. 145–151.

    Article  CAS  Google Scholar 

  15. Chen Yao, Wang, G.X., Tian, J.P., et al., Preparation and Properties of Spherical LiNi0.75Co0.25O2 as a Cathode for Lithium-Ion Batteries, Electrochim. Acta, 2004, vol. 50, pp. 435–441.

    Article  CAS  Google Scholar 

  16. Kang, S.-H. and Amine, K., Synthesis and Electrochemical Properties of Layer-Structured 0.5Li(Ni0.5Mn0.5)O2-0.5Li(Li1/3Mn2/3)O2 Solid Mixture, J. Power Sources, 2003, vol. 124, pp. 533–537.

    Article  CAS  Google Scholar 

  17. Johnson, C.S., Kim, J.-S., Lefief, C., et al., The Significance of the Li2MnO3 Component in “Composite” xLi2MnO3 · (1 − x)LiMn0.5Ni0.5O2 Electrodes, Electrochem. Commun., 2004, vol. 6, pp. 1085–1091.

    Article  CAS  Google Scholar 

  18. Johnson, C.S., Li, N., Vaughey, J.T., et al., Lithium-Manganese Oxide Electrodes with Layered-Spinel Composite Structures xLi2MnO3 · (1 − x)Li1+y Mn2−y O4 (0 < x < 1, 0 ≤ y ≤ 0.33) for Lithium Batteries, Electrochem. Commun., 2005, vol. 7, pp. 528–536.

    Article  CAS  Google Scholar 

  19. Lin, C.H., Shen, C.H., Prince, A.A.M., et al., Electrochemical Studies on Mixtures of LiNi0.8Co0.17Al0.03O2 and LiCoO2 Cathode Materials for Lithium Ion Batteries, Solid State Commun., 2005, vol. 133, pp. 687–690.

    Article  CAS  Google Scholar 

  20. Zhang, L., Takada, K., Ohta, N., et al., Synthesis and Electrochemistry of Layered 0.6LiNi0.5Mn0.5O2 · xLi2MnO3 · yLiCoO2 (x + y = 0.4) Cathode Materials, Mater. Lett., 2004, vol. 58, pp. 3197–3200.

    Article  CAS  Google Scholar 

  21. Mayer, S.T., US Patent 6 379 842, 2002.

  22. Pervov, V.S., Mikheikin, I.D., Makhonina, E.V., and Butskii, V.D., Supramolecular Ensembles in Eutectic Alloys, Usp. Khim., 2003, vol. 72, pp. 852–863.

    Google Scholar 

  23. Chitra, S., Kalyani, P., Mohan, T., et al., Characterization and Electrochemical Studies of LiMn2O4 Cathode Materials Prepared by Combustion Method, J. Electroceram., 1999, vol. 3(4), pp. 433–441.

    Article  CAS  Google Scholar 

  24. Oku, M., X-ray Photoelectron Spectrum of Low-Spin Co(III) in LiCoO2, J. Solid State Chem., 1978, vol. 23, pp. 177–185.

    Article  CAS  Google Scholar 

  25. Gabrisch, H., Yazami, R., and Fultz, B., A Transmission Electron Microscopy Study of Cycled LiCoO2, J. Power Sources, 2003, vols. 119–121, pp. 674–679.

    Article  Google Scholar 

  26. Massarotti, V., Capsolini, D., and Bini, M., Stability of LiMn2O4 and New High Temperature Phases in Air, O2, and N2, Solid State Commun., 2002, vol. 122, pp. 317–322.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © Ya.V. Shatilo, E.V. Makhonina, V.S. Pervov, V.S. Dubasova, A.F. Nikolenko, Zh.V. Dobrokhotova, I.A. Kedrinskii, 2006, published in Neorganicheskie Materialy, 2006, Vol. 42, No. 7, pp. 863–868.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shatilo, Y.V., Makhonina, E.V., Pervov, V.S. et al. LiCoO2-and LiMn2O4-based composite cathode materials. Inorg Mater 42, 782–787 (2006). https://doi.org/10.1134/S0020168506070168

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168506070168

Keywords

Navigation