Abstract
Experimental thermophysical data for high-entropy carbide (HfTaTiNbZr)C are presented for the first time at high temperatures (2500–5500 K). A fast (10 μs) method of heating by a current pulse was used. Samples in the form of flat plates with a thickness of ∼100 μm were clamped between glass plates to fix the sample and prevent the occurrence of a shunt discharge. Solidus and liquidus temperatures and properties of carbide were measured—melting heat, input energy (enthalpy) and specific heat—depending on temperature. The temperature was measured using a high-speed pyrometer at a wavelength of 856 nm.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0018151X2205011X/MediaObjects/10740_2023_8513_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0018151X2205011X/MediaObjects/10740_2023_8513_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0018151X2205011X/MediaObjects/10740_2023_8513_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0018151X2205011X/MediaObjects/10740_2023_8513_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0018151X2205011X/MediaObjects/10740_2023_8513_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0018151X2205011X/MediaObjects/10740_2023_8513_Fig6_HTML.png)
REFERENCES
Potschke, J., Dahal, M., Herrmann, M., et al., J. Mater. Sci., 2021, vol. 56, p. 11237.
Yeh, J.-W., Chen, S.-K., Lin, S.-J., et al., Adv. Eng. Mater., 2004, vol. 6, p. 299.
Rogachev, A.S., Phys. Met. Metallogr., 2020, vol. 121, no. 8, p. 733.
Savchenko, A.M., At. Strategy, 2015, vol. 110, p. 14. http://www.proatom.ru/modules.php?name=News& file=print&sid=6440.
Savchenko, A., Energy Nature of Configurational Entropy: Generation of Entropy and Anti-entropy Flows, Saarbrucken: LAP, 2015.
Kovalev, D.Y., Kochetov, N.A., and Chuev, I.I., Ceram. Int., 2021, vol. 47, no. 23, p. 32626.
Istomin, P., Istomina, E., Nadutkin, A., Grass, V., Lysenkov, A., and Kudryavtsev, A., J. Eur. Ceram. Soc., 2021, vol. 41, no. 14, p. 6934.
Dusza, J., Csanadi, T., Medved, D., Sedlak, R., Vojtko, M., Ivor, M., Unsal, H., Tatarko, P., Tatarkova, M., and Sajgalik, P., J. Eur. Ceram. Soc., 2021, vol. 41, no. 11, p. 5417.
Pak, A.Y., Grinchuk, P.S., Mamontov, G.Y., Yakich, T.Y., and Gumovskaya, A.A., J. Eng. Phys. Thermophys., 2021, vol. 94, no. 1, p. 88.
Moskovskikh, D.O., Mukasyan, A.S., and Rogachev, A.S., Dokl. Phys. Chem., 2013, vol. 449, no. 1, p. 41.
Mukasyan, A.S., Shuck, C.T., Pauls, J.M., et al., Adv. Eng. Mater., 2018, vol. 20, p. 1701065.
Sedegov, A.S., Bobojanov, A.R., Vorotilo, S., et al., IOP Conf. Ser.: Mater. Sci. Eng., 2021, vol. 1014, p. 012049.
Savvatimskiy, A.I., Onufriev, S.V., Valyano, G.E., et al., Ceram. Int., 2022, vol. 48, no. 14, p. 19655.
Savvatimskii, A.I. and Onufriev, S.V., Yad. Fiz. Inzh., 2015, vol. 6, nos. 11–12, p. 622.
Liu, S.-Y., Zhang, S., Liu, S., Li, D.-J., Li, Y., and Wang, S., J. Eur. Ceram. Soc., 2021, vol. 41, no. 13, p. 6267.
Onufriev, S.V. and Savvatimskii, A.I., High Temp., 2018, vol. 56, no. 5, p. 678.
Savvatimskii, A.I., High Temp., 2022, vol. 60, Suppl. 2, p. S181.
ACKNOWLEDGMENTS
The authors of JIHT are grateful to the RSF grant no. 19-79-30086 in terms of measuring thermophysical properties, and the authors of NUST “MISIS” are grateful to the RSF grant no. 18-79-10215 in terms of synthesis and sintering of high-entropy compounds—for financial support of this study.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Rights and permissions
About this article
Cite this article
Savvatimskiy, A.I., Onufriev, S.V., Sedegov, A.S. et al. Thermophysical Properties of High-entropy Carbide (HfTaTiNbZr)C at Temperatures of 2500–5500 K. High Temp 60, 612–615 (2022). https://doi.org/10.1134/S0018151X2205011X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0018151X2205011X