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Thermodynamic Properties of Cerium Dioxide in the Condensed State

  • THERMOPHYSICAL PROPERTIES OF MATERIALS
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High Temperature Aims and scope

Abstract

As part of the further development of the IVTANTERMO information and reference system, the entire set of experimental data on the thermodynamic properties of cerium dioxide available in the literature was critically analyzed and processed. An equation was obtained that approximates the temperature dependence of the heat capacity of crystalline CeO2 in the interval 298.15–3083 K. There are no experimental data for liquid cerium dioxide in the literature. The missing thermodynamic quantities (enthalpy of melting, heat capacity of the liquid phase) are obtained by estimation. Particular attention is paid to the transition between the oxidized and reduced forms of cerium Ce4+ ⇄ Ce3+, as a result of which in the CeO2–CeO1.5 system, a number of intermediate oxides are formed.

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Funding

The study was carried out under an agreement between the Joint Institute for High Temperatures of the Russian Academy of Sciences and TRINITI JSC of July 31, 2020, no. 17706413348200001160/226/2872-D “Creation of Wide-Range Models and Development of Computer Codes to Obtain New Data on Mechanical, Thermodynamic, Structural Properties, as Well as Atomic Structures of Multielectron Ions for Various Nuclear Energy Materials at High Energy Concentrations”.

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  1. Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow, Russia

    N. M. Aristova

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Correspondence to N. M. Aristova.

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Aristova, N.M. Thermodynamic Properties of Cerium Dioxide in the Condensed State. High Temp 60, 756–760 (2022). https://doi.org/10.1134/S0018151X22040095

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