Skip to main content
SpringerLink
Log in

An Experimental Study of Phase Transformations of Aluminum Oxides in the Processes of Sub- and Supercritical Water Oxidation of Metallic Aluminum

  • THERMOPHYSICAL PROPERTIES OF MATERIALS
  • Published:
High Temperature Aims and scope

Abstract

In this work, samples of metallic aluminum are objects of sub- and supercritical water oxidation. Experimental studies have been carried out, and dependences of the effect of temperature, pressure, reaction time, and pH of the oxidizing agent on the phase composition of the oxidation products and their adsorption properties have been revealed. Experimental studies have been carried out in the temperature range of 275–380°C, reaction time from 3 to 12 h, and different water pH of 7–12. Maximum specific surface S = 120.2 m2/g samples obtained at temperature T = 380°C and reaction time τ = 3 h with pH 12. The phase composition of this sample included aluminum oxide γ-Al2O3 (92.3 wt %) and corundum α-Al2O3 (7.7 wt %).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Notes

  1. Powder diffraction data powder diffraction file.

REFERENCES

  1. Ivanova, A.S. and Mel’gunov, M.S., Promyshl. Katal. Lektsiyakh, 2009, no. 8, p. 7.

  2. Vostrikov, A.A., Fedyaeva, O.N., Fadeeva, I.I., and Sokol, M.Ya., Sverkhkrit. Fluidy: Teor. Prakt., 2010, vol. 5, no. 1, p. 12.

    Google Scholar 

  3. Vlaskin, M.S., Grigorenko, A.V., Zhuk, A.Z., Lisitsyn, A.V., Sheindlin, A.E., and Shkol’nikov, E.I., High Temp., 2016, vol. 54, no. 3, p. 322.

    Article  Google Scholar 

  4. Shkolnikov, E.I., Shaitura, N.S., and Vlaskin, M.S., J. Supercrit. Fluids, 2013, vol. 73, p. 10.

    Article  Google Scholar 

  5. Vostrikov, A.A., Shishkin, A.V., and Fedyaeva, O.N., Int. J. Hydrogen Energy, 2020, vol. 45, no. 1, p. 1061.

    Article  Google Scholar 

  6. Veriansyah, B., Susanti, R.F., Nugroho, A., Min, B.K., and Kim, J., Mater. Lett., 2011, vol. 65, no. 4, p. 772.

    Article  Google Scholar 

  7. Karimov, T.M., Mukhammadiev, A.D., Gil’mutdinov, I.I., Gil’mutdinov, I.M., Kuznetsova, I.V., and Sabirzyanov, A.N., Mater. 9-i Ross. stud. nauch.-tekhn. konf. “Vakuumnaya tekhnika i tekhnologiya” (Proc. 9th Russ. Student Conf. on Vacuum Technique and Technology), Kazan: Kazan. Nats. Issled. Tekhnol. Univ., 2019, p. 170.

Download references

Funding

The work was performed within the framework of the state order “Catalysis in Oil Refining and Petrochemicals” (agreement no. 075-00315-20-01 dated April 6, 2020) using the analytical equipment of the Center for Collective Use “Nanomaterials and Nanotechnologies.”

Author information

Authors and Affiliations

  1. Kazan National Research Technological University, 420000, Kazan, Russia

    I. I. Gilmutdinov, N. S. Sandugei, I. M. Gilmutdinov, I. V. Kuznetsova, Kh. E. Kharlampidi & A. N. Sabirzyanov

Authors
  1. I. I. Gilmutdinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. S. Sandugei
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. M. Gilmutdinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. V. Kuznetsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Kh. E. Kharlampidi
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. N. Sabirzyanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. S. Sandugei.

Ethics declarations

The authors declare that they have no conflicts of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gilmutdinov, I.I., Sandugei, N.S., Gilmutdinov, I.M. et al. An Experimental Study of Phase Transformations of Aluminum Oxides in the Processes of Sub- and Supercritical Water Oxidation of Metallic Aluminum. High Temp 60, 177–181 (2022). https://doi.org/10.1134/S0018151X22020183

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0018151X22020183

Search

Navigation