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Thermal Stability of C60 and C70 Fullerites

  • THERMOPHYSICAL PROPERTIES OF MATERIALS
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Abstract

The thermal properties of C60 and C70 fullerenes and fullerites have been studied by X-ray structural analysis and UV spectroscopy. It was shown that C70 fullerite is stabler than C60 fullerite (by ~150°C) due to the different geometry of the fullerenes and stronger intermolecular interactions. The experimental results are given a qualitative and quantitative interpretation based on the calculation of the interaction energy between two fullerene molecules.

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REFERENCES

  1. Eletskii, A.V. and Smirnov, B.M., Phys.—Usp., 1993, vol. 36, no. 2, p. 202.

    Article  ADS  Google Scholar 

  2. Eletskii, A.V. and Smirnov, B.M., Phys.—Usp., 1995, vol. 38, no. 9, p. 935.

    Article  ADS  Google Scholar 

  3. Diky, V.V. and Kabo, G.Ya., Russ. Chem. Rev., 2000, vol. 69, no. 2, p. 95.

    Article  ADS  Google Scholar 

  4. Leifer, S.D., Goodwin, D.G., Anderson, M.S., and Anderson, J.R., Phys. Rev. B: Condens. Matter Mater. Phys., 1995, vol. 51, no. 15, p. 9973.

    Article  ADS  Google Scholar 

  5. Mochida, I., Egashira, M., Koura, H., Dakeshita, K., Yoon, S.-H., and Korai, Y., Carbon, 1994, vol. 33, no. 8, p. 1186.

    Article  Google Scholar 

  6. Mochida, I., Egashira, M., Korai, Y., and Yokogawa, K., Carbon, 1997, vol. 35, no. 12, p. 1707.

    Article  Google Scholar 

  7. Eklund, P.S., Rao, A.M., Zhou, P., and Wang, Y., Thin Solid Films, 1995, vol. 257, p. 185.

    Article  ADS  Google Scholar 

  8. Vogel, W., Appl. Phys. A, 1996, vol. 62, p. 295.

    ADS  Google Scholar 

  9. Cuesta, A., Jamond, M., Martinez-Alonso, A., and Tascon, J.M.D., Carbon, 1996, vol. 34, no. 10, p. 1239.

    Article  Google Scholar 

  10. Stetzer, M.R., Heiney, P.A., Fischer, J.E., and McGhie, A.R., Phys. Rev. B: Condens. Matter Mater. Phys., 1997, vol. 55, no. 1, p. 127.

    Article  ADS  Google Scholar 

  11. Skokan, E.V., Arkhangelskii, I.V., Izotov, D.E., Chelovskaya, N.V., Nikulin, M.M., and Velikodnyi, Yu.A., Carbon, 2005, vol. 43, no. 4, p. 803.

    Article  Google Scholar 

  12. Zhang, B.L., Wang, C.Z., Chan, C.T., and Ho, K.M., Phys. Rev. B: Condens. Matter Mater. Phys., 1993, vol. 48, p. 11381.

    Article  ADS  Google Scholar 

  13. Sommer, T., Kruse, T., and Roth, P.J., J. Phys. B, 1996, vol. 29, no. 21, p. 4955.

    Article  ADS  Google Scholar 

  14. Borodin, V.I. and Trukhacheva, V.A., Tech. Phys. Lett., 2004, vol. 30, no. 14, p. 598.

    Article  ADS  Google Scholar 

  15. McKee, D.W., Carbon, 1991, vol. 29, no. 7, p. 1057.

    Article  Google Scholar 

  16. Sheka, E.F., J. Struct. Chem., 2006, vol. 47, no. 4, p. 593.

    Article  Google Scholar 

  17. Cicek, B., Kenar, A., and Nazir, H., Fulerene. Sci. Technol., 2001, vol. 9, no. 1, p. 103.

    Google Scholar 

  18. Rekhviashvili, S.Sh., Phys. Solid State, 2013, vol. 55, no. 7, p. 1525.

    Article  ADS  Google Scholar 

  19. Rekhviashvili, S.Sh., Phys. Solid State, 2017, vol. 59, no. 4, p. 835.

    Article  ADS  Google Scholar 

  20. Rekhviashvili, S.Sh., Tech. Phys. Lett., 2017, vol. 43, p. 745.

    Article  ADS  Google Scholar 

  21. Girifalco, L.A., J. Phys. Chem., 1992, vol. 96, no. 2, p. 858.

    Article  Google Scholar 

  22. Glukhova, O.E. and Zhbanov, A.I., Phys. Solid State, 2003, vol. 45, no. 1, p. 189.

    Article  ADS  Google Scholar 

  23. Kniaz, K., Girifalco, L.A., and Fischer, J.E., J. Phys. Chem., 1995, vol. 99, no. 45, p. 16804.

    Article  Google Scholar 

  24. Palucha, S., Gburski, Z., and Biesiada, J., J. Mol. Struct., 2004, vol. 704, nos. 1–3, p. 269.

    Article  ADS  Google Scholar 

  25. Magomedov, M.N., High Temp., 2005, vol. 43, no. 3, p. 379.

    Article  Google Scholar 

  26. Martinez-Herrera, M., Campos, M., Torres, L.A., and Rojas, A., Thermochim. Acta, 2015, vol. 622, p. 72.

    Article  Google Scholar 

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ACKNOWLEDGMENTS

The authors are grateful to Aksenova V.V. for obtaining UV spectroscopic data.

Funding

The work has state registration, no. АААА-А17-117022250039-4.

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Authors and Affiliations

  1. Scientific Center for Metallurgical Physics and Materials Science, Udmurt Federal Research Center, Ural Branch, Russian Academy of Sciences, Izhevsk, Russia

    R. M. Nikonova & V. I. Lad’yanov

  2. Institute of Applied Mathematics and Automation, Center, Russian Academy of Sciences, Nalchik, Russia

    S. Sh. Rekhviashvili & A. V. Pskhu

Authors
  1. R. M. Nikonova
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  2. V. I. Lad’yanov
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  3. S. Sh. Rekhviashvili
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  4. A. V. Pskhu
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Correspondence to R. M. Nikonova.

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Nikonova, R.M., Lad’yanov, V.I., Rekhviashvili, S.S. et al. Thermal Stability of C60 and C70 Fullerites. High Temp 59, 179–183 (2021). https://doi.org/10.1134/S0018151X21020103

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  • DOI: https://doi.org/10.1134/S0018151X21020103

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