Skip to main content
SpringerLink
Log in

Mechanisms of the Recombination of Oxygen and Nitrogen Atoms on Quartz

  • THERMOPHYSICAL PROPERTIES OF MATERIALS
  • Published:
High Temperature Aims and scope

Abstract

A heterogeneous recombination of nitrogen and oxygen atoms is considered. The installation and the method to determine the probability of heterogeneous recombination of oxygen and nitrogen atoms by resonance fluorescence spectroscopy under strictly controlled conditions are described. The variation of the recombination probability of nitrogen and oxygen atoms on the quartz surface is studied in the temperature range of 297–1000 K and pressures of 0.01–10 mbar. The regions of pressure and temperature in which recombination occurs predominantly according to the Langmuir–Hinshelwood mechanism or the Eley–Rideal mechanism are distinguished. Data on the recombination activation energy are presented. The recombination of nitrogen and oxygen atoms occurs mainly at various active centers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. Kovalev, V.L., Geterogennye kataliticheskie protsessy v aerotermodinamike (Heterogeneous Catalytic Processes in Aerothermodynamics), Moscow: Fizmatlit, 2002.

  2. Aleksandrov, E.N., Zhestkov, B.E., and Kozlov, S.N., High Temp., 2014, vol. 52, no. 1, p. 41.

    Article  Google Scholar 

  3. Aleksandrov, E.N., Egorov, I.V., Zhestkov, B.E., Kozlov, S.N., and Rusakov, S.V., in Rezul’taty fundamental’nykh issledovanii v prikladnykh zadachakh aviastroeniya (Results of Fundamental Research in Aircraft Engineering Applications), Moscow: Nauka, 2016, p. 150.

  4. Kholodkova, N.V., Kholodkov, I.V., and Brovikova, I.N., High Temp., 2009, vol. 47, no. 3, p. 448.

    Article  Google Scholar 

  5. Kholodkov, I.V., Kholodkova, N.V., and Smirnov, S.A., High Temp., 2016, vol. 54, no. 5, p. 639.

    Article  Google Scholar 

  6. Kablov, E.N., Zhestkov, B.E., Grashchenkov, D.V., Sorokin, O.Yu., Lebedeva, Yu.E., and Vaganova, M.L., High Temp., 2017, vol. 55, no. 6, p. 873.

    Article  Google Scholar 

  7. Kolesnikov, A.F., Gordeev, A.N., and Vasil’evskii, S.A., High Temp., 2016, vol. 54, no. 1, p. 29.

    Article  Google Scholar 

  8. Kozlov, S.N., Aleksandrov, E.N., Zhestkov, B.E., and Kislyuk, M.U., Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1987, vol. 36, no. 11, p. 2272.

  9. Kim, Y.C. and Boudart, M., Langmuir, 1991, vol. 7, no. 12, p. 2999.

    Article  Google Scholar 

  10. Jumper, E.J., Newman, M., Seward, W.A., and Kitchen, D.R., Recombination of nitrogen on silica-based, thermal-protection-tile-like surfaces, AIAA Paper, no. 93–0477, 1993.

  11. Jumper, E.J. and Seward, W.A., J. Thermophys. Heat Transfer, 1991, vol. 5, no. 3, p. 284.

    Article  Google Scholar 

  12. Nasuti, F., Barbato, M., and Bruno, C., J. Thermophys. Heat Transfer, 1996, vol. 10, no. 1, p. 131.

    Article  Google Scholar 

  13. Gerasimova, O.E. and Borisov, S.F., The study of the atomic oxygen recombination on silica by molecular dynamic method, Fiz.-Khim. Kin. Gaz. Din., 2007, no. 5. http://chemphys.edu.ru/issues/2007-5/articles/31/.

  14. Aleksandrov, E.N., Doctoral (Chem.) Dissertation, Moscow: Inst. Chem. Phys., Russ. Acad. Sci., 1986.

  15. Fünfer, E. and Neuert, H., Zählrohre und Szintillationszähler (Counter Tubes and Scintillation Counters), Karlsruhe: Braun, 1959.

  16. Samson, J.A.R., Techniques of Vacuum Ultraviolet Spectroscopy, New York: Wiley, 1967.

    Google Scholar 

  17. Zhestkov, B.E. and Grachev, N.N., Zh. Tekh. Fiz., 1984, vol. 54, no. 4, p. 716.

    Google Scholar 

  18. Kholodkova, N.V. and Kholodkov, I.V., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2014, vol. 57, no. 2, p. 3.

    Google Scholar 

  19. Brovikova, I.N. and Galiaskarov, E.G., High Temp., 2001, vol. 39, no. 6, p. 809.

    Article  Google Scholar 

  20. Brovikova, I.N., High Temp., 2004, vol. 42, no. 6, p. 879.

    Article  Google Scholar 

  21. Hirschfelder, J.O., Curtiss, C.F., and Bird, R.B., The Molecular Theory of Gases and Liquids, New York: Wiley, 1954.

    MATH  Google Scholar 

Download references

FUNDING

The work was supported within the program of joint fundamental research in the field of aerospace technologies of the Zhukovsky Central Aerohydrodynamic Institute and institutes of the Russian Academy of Sciences and by the Russian Foundation for Basic Research, project no. 18-08-00020-a.

Author information

Authors and Affiliations

  1. Zhukovsky Central Aerohydrodynamic Institute, 140181, Zhukovsky, Moscow oblast, Russia

    B. E. Zhestkov

  2. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334, Moscow, Russia

    S. N. Kozlov & E. N. Alexandrov

Authors
  1. B. E. Zhestkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. N. Kozlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. N. Alexandrov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to B. E. Zhestkov or S. N. Kozlov.

Additional information

Translated by O. Zhukova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhestkov, B.E., Kozlov, S.N. & Alexandrov, E.N. Mechanisms of the Recombination of Oxygen and Nitrogen Atoms on Quartz. High Temp 57, 329–334 (2019). https://doi.org/10.1134/S0018151X19030192

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0018151X19030192

Search

Navigation