Abstract
On the basis of analysis of the interaction between the defects of a crystal lattice of zirconium dioxide doped with inovalent cations, the conditions are found for which there are no relatively large single-charged anions of oxygen in interstitial sites of the lattice. Under the assumption that this is enough for the existence of cubic modification of the lattice, the position of the bottom phase boundary of its monophase existence (depending on doping level, temperature, and the partial pressure value of oxygen in ambient medium) is determined. It is demonstrated that such a description fits well with the experimental data and provides a physical explanation for detected phenomena of the existence of “low-temperature cubic modification” of zirconium dioxide. A qualitative description of the boundary positions of the existence domain of pure zirconium dioxide in cubic modification is proposed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Pakhomov, E.P., Teplofiz. Vys. Temp., 2005, vol. 43, no. 4, p. 556.
Pakhomov, E.P., Teplofiz. Vys. Temp., 2009, vol. 47, no. 6, p. 835.
Rauh, E.G. and Garg, S.P., High Temp. Sci., 1981, vol. 14, no. 2, p. 121.
Pakhomov, E.P., Teplofiz. Vys. Temp., 2006, vol. 44, no. 6, p. 861.
Stubican, V.S., Hilk, R.C., and Ray, S.P., J. Am. Ceram. Soc., 1978, vol. 61, nos. 1–2, p. 17.
Pascual, C. and Duran, P., J. Am. Ceram. Soc., 1983, vol. 66, no. 1, p. 23.
Srivastava, K.K., Patil, R.N., Choudhary, C.B., Gokhake, K.V.G., and Subbarao, E.C., Trans. J. Br. Ceram. Soc., 1974, vol. 73, no. 3, p. 85.
Scott, H.G., J. Mater. Sci., 1975, vol. 10, no. 9, p. 1527.
Gorelov, V.P., Tr. Inst. Elektrokhim., Ural. Nauchn. Tsentr, Akad. Nauk SSSR, 1978, no. 26, p. 69.
Steele, D. and Fender, B.F., J. Phys. C: Solid State Phys., 1974, vol. 7, no. 1, p. 1.
Tikhonov, P.A., Kuznetsov, A.K., Keler, E.K., and Krasil’nikov, M.D., Zh. Fiz. Khim., 1974, vol. 48, no. 3, p. 643.
Katz, G., J. Am. Ceram. Soc., 1971, vol. 51, no. 10, p. 531.
Boganov, A.G., Rudenko, V.S., and Makarov, L.P., Dokl. Akad. Nauk SSSR, 1965, vol. 160, no. 5, p. 1065.
Duwez, P., Odell, F., and Brown, F.Y., J. Am. Ceram. Soc., 1952, vol. 35, no. 5, p. 109.
Hund, F., Z. Phys. Chem., 1952, vol. 199, nos. 1–3, p. 142.
Tien, T.Y. and Subbarao, E.C., J. Chem. Phys., 1963, vol. 39, no. 4, p. 1041.
Strickler, D.W. and Carlson, W.G., J. Am. Ceram. Soc., 1964, vol. 47, no. 3, p. 122.
Noguchi, T. and Mizuno, M., Solar Energy, 1977, vol. 11, nos. 3–4, p. 145.
Stubican, V.S. and Ray, S.P., J. Am. Ceram. Soc., 1977, vol. 60, nos. 11–12, p. 534.
Stubican, V.S. and Hellmann, J.R., Adv. Ceram., 1981, vol. 3, p. 25.
Gorelov, V.P. and Pal’guev, S.F., Izv. Akad. Nauk SSSR, Neorg. Mater., 1977, vol. 13, no. 1, p. 181.
Kisi, E. and Yuxiang, M., J. Phys.: Condens. Matter, 1998, vol. 10, p. 3823.
Quensanga, A., Pialoux, A., and Dode, M., Rev. Int. Hautes Temp. Refract., 1974, vol. 11, no. 4, p. 289.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.P. Pakhomov, 2011, published in Teplofizika Vysokikh Temperatur, 2011, Vol. 49, No. 4, pp. 537–545.
Rights and permissions
About this article
Cite this article
Pakhomov, E.P. A general view of the lower boundary of existence of γ-Zr(M)O2 − x . High Temp 49, 520–527 (2011). https://doi.org/10.1134/S0018151X1104016X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0018151X1104016X