Abstract
The possibility is considered of increasing the concentration of singlet oxygen (SO), which is obtained in a discharge, by way of adding nitrogen dioxide to the starting gas. The presence of NO2 in the mixture must cause the removal of atomic oxygen formed in the discharge and, accordingly, a decrease in the loss of SO. The simulation of the kinetics of the products of dc discharge in a flow of oxygen is used for determining the values of expected increase in the concentration of SO, as well of the concentration of NO2, which are required for attaining the maximal effect. It is demonstrated that, at oxygen pressures of ∼6 torr and higher, the addition of NO2 may produce a double and higher increase in the concentration of SO in regions of post-discharge flow with transport times of ∼5–10 ms.
Similar content being viewed by others
References
Vasil’eva, A.N., Grishina, I.A., Klopovskii, K.S. et al., Fiz. Plazmy, 1985, vol. 11, no. 2, p. 221.
Klopovskii, K.S., Kovalev, A.S., Lopaev, D.V. et al., Fiz. Plazmy, 1992, vol. 18, no. 12, p. 1606.
Schmiedberger, J., Takahashi, S., and Fujii, H., Proc. SPIE, 1997, vol. 3092, p. 694.
Shepelenko, A.A., Mikheev, P.A., Kupryaev, N.V., and Voronov, A.I., Izv. Akad. Nauk Ser. Fiz., 2000, vol. 64, no. 7, p. 1259.
Ionin, A.A., Klimachev, Yu.M., Kotkov, A.A. et al., J. Phys. D, 2003, vol. 36, p. 982.
Laska, L., Masek, K., and Ruzicka, T., Czech. J. Phys., 1979, vol. 29, p. 498.
Bonnet, J., Fournier, G., Pigache, D., and Lecuiller, M., J. Phys. Paris Lett., 1980, vol. 41, p. 477.
Gousset, G., Touzeau, M., Vialle, M., and Ferreira, C.M., Chem. Plasma Process., 1989, vol. 9, no. 2, p. 189.
Rybkin, V.V., Bessarab, A.B., and Maksimov, A.I., Teplofiz. Vys. Temp., 1996, vol. 34, no. 2, p. 181 (High Temp. (Engl. transl.), vol. 34, no. 2, p. 175).
Atkinson, R., Baulch, D.L., Cox, R.A. et al., J. Phys. Chem. Ref. Data, 1997, vol. 26, p. 1329.
Vasiljeva, A.N., Klopovskiy, K.S., Kovalev, A.S. et al., J. Phys. D, 2004, vol. 37, p. 2455.
Braginsky, O.V., Kovalev, A.S., Lopaev, D.V. et al., J. Phys. D, 2006, vol. 39, p. 5183.
Shepelenko, A.A. and Fomin, E.V., On the Mechanisms of Production and Loss of Molecules O2(1Δ) in Oxygen Plasma of DC Discharge, in 3-i Mezhdunarodnyi simpozium po teoreticheskoi i prikladnoi plazmokhimii (The 3rd International Symposium on Theoretical and Applied Plasma Chemistry), 2002, Ivanovo: Ivanovo State Univ. of Chemical Technology, vol. 1, p. 199.
Shepelenko, A.A., Mikheev, P.A., Voronov, A.I., and Kupryaev, N.V., Singlet Delta Oxygen in Steady Discharge in Vortex Flow of Oxygen, in Materialy po fizike nizkotemperaturnoi plazmy. FNTP-2001 (Materials in Low-Temperature Plasma Physics. FNTP-2001), Petrozavodsk, Part 1, p. 216.
Azyazov, V.N., Kabir, H.M., and Heaven, M.C., Proc. SPIE, 2007, vol. 6454, p. 64540K.
Klopovskii, K.S., Kovalev, A.S., Lopaev, D.V. et al., Fiz. Plazmy, 1992, vol. 18, no. 12, p. 1606.
Klopovskiy, K.S., Lopaev, D.V., Popov, N.A. et al., J. Phys. D, 1999, vol. 32, p. 3004.
Kajita, S., Ushiroda, S., and Kondo, Y., J. Appl. Phys., 1999, vol. 67, no. 9, p. 4015.
Laher, R.R. and Gilmore, F.R., J. Phys. Chem. Ref. Data, 1990, vol. 19, no. 1, p. 277.
Kenner, R.D. and Ogryzlo, E.A., Can. J. Chem., 1983, vol. 61, p. 921.
Napartovich, A.P., Deryudin, A.A., and Kochetov, I.V., J. Phys. D, 2001, vol. 34, p. 1827.
Shepelenko, A.A., Teplofiz. Vys. Temp., 2007, vol. 45, no. 4, p. 492 (High Temp. (Engl. transl.), vol. 45, no. 4, p. 439).
Carroll, D.L., Verdeyen, J.T., King, D.M. et al., Appl. Phys. Lett., 2004, vol. 85, no. 8, p. 1320.
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.A. Shepelenko, E.V. Fomin, 2008, published in Teplofizika Vysokikh Temperatur, vol. 46, No. 6, 2008, pp. 831–835.
Rights and permissions
About this article
Cite this article
Shepelenko, A.A., Fomin, E.V. Increasing the concentration of singlet delta oxygen in discharge products by adding NO2 to oxygen. High Temp 46, 763–767 (2008). https://doi.org/10.1134/S0018151X08060059
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0018151X08060059