Skip to main content
SpringerLink
Log in

Methacrylate-Сontaining Para-Derivatives of N,N-Diethyl-4-(phenyldiazenyl)aniline as Initiators in Two-Photon Polymerization

  • PHOTOCHEMISTRY
  • Published:
High Energy Chemistry Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

The possibility of using a series of methacrylate-containing N,N-diethyl-4-(phenyldiazenyl)anilines with various para-substituents (–H, –Br, –NO2) relative to the azo group as photoinitiators of radical polymerization is considered. The electrochemical and photoluminescent properties of these compounds have been studied. In the presence of azo dyes, two-photon photopolymerization of pentaerythritol triacrylate was carried out using focused 780-nm radiation from a femtosecond laser. Structures with minimal dimensions of linear elements of 94 ± 5 nm were obtained by means of the DLW nanolithography technique, and 3D microstructures of complex architecture were fabricated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Jaiswal, A., Rastogi, C.K., Rani, S., Singh, G.P., Saxena, S., and Shukla, S., iScience, 2023, vol. 26, p. 106374.

  2. Zhiganshina, E.R., Arsenyev, M.V., and Chesnokov, S.A., Polym. Sci., Ser. B, 2023, vol. 65, p. 247.

    Article  CAS  Google Scholar 

  3. Zhiganshina, E.R., Arsenyev, M.V., Chubich, D.A., Kolymagin, D.A., Pisarenko, A.V., Burkatovsky, D.S., Baranov, E.V., Vitukhnovsky, A.G., Lobanov, A.N., Matital, R.P., Aleynik, D.Ya., and Chesnokov, S.A., Eur. Polym. J., 2021, vol. 162, p. 110917.

    Article  Google Scholar 

  4. Liu, Y.J., Yang, J.Y., Nie, Y.M., Lu, C.H., Huang, E.D., Shin, C.S., Baldeck, P., and Lin, C.L., Microfluid. Nanofluidics, 2015, vol. 18, p. 427.

    Article  CAS  Google Scholar 

  5. Sakellari, I., Yin, X., Nesterov, M.L., Terzaki, K., Xomalis, A., and Farsari, M., Adv. Opt. Mater., 2017, vol. 5, p. 1700200.

    Article  Google Scholar 

  6. Rakhymzhanov, A., Gueddida, A., Alonso-Redondo, E., Utegulov, Z., Perevoznik, D., Kurselis, K., Chichkov, B., El Boudouti, E., Djafari-Rouhani, B., and Fytas, G., Appl. Phys. Lett., 2016, vol. 108, p. 201901.

    Article  Google Scholar 

  7. Zheng, C., Jin, F., Zhao, Yu., Zheng, M., Liu, J., Dong, X., Xiong, Z., Xia, Y., and Duan, X., Sens. Actuators, 2020, vol. 304, p. 127345.

    Article  CAS  Google Scholar 

  8. Otuka, A.J.G., Torres, B.B.M., Dipold, J., Ba-logh, D.T., Tribuzi, V., De Boni, L., and Mendonca, C.R., Opt. Mater. Express, 2020, vol. 10, no. 8, p. 1792.

    Article  CAS  Google Scholar 

  9. Fominykh, O.D., Sharipova, A.V., and Balakina, M.Yu., Comput. Mater. Sci., 2019, vol. 168, p. 32.

    Article  CAS  Google Scholar 

  10. Lu, Y., Hasegawa, F., Goto, T., Ohkuma, S., Fukuhara, S., Kawazu, Y., Totani, K., Yamashita, T., and Watanabe, T., J. Mater. Chem., 2003, vol. 14, p. 75.

    Article  Google Scholar 

  11. Beharry, A.A., Sadovski, O., and Woolley, G.A., J. Am. Chem. Soc., 2011, vol. 133, p. 19684.

    Article  CAS  PubMed  Google Scholar 

  12. Vivas, M.G., Silva, D.L., De Boni, L., Bretonniere, Y., Andraud, C., Laibe-Darbour, F., Mulatier, J.-C., Zalesny, R., Bartkowiak, W., Canuto, S., and Mendonca, C.R., J. Phys. Chem. B, 2012, vol. 116, p. 14677.

    Article  CAS  PubMed  Google Scholar 

  13. Zhou, L., Mao, J., Ren, Y., Han, S.-T., Roy, V.A.L., and Zhou, Y., Small, 2018, vol. 14, p. 1703126.

    Article  Google Scholar 

  14. Ghanavatkar, C.W., Mishra, V.R., and Nagaiyan, S., Dyes Pigm., 2021, vol. 191, p. 109367.

    Article  CAS  Google Scholar 

  15. Xu, L., Zhang, J., Yin, L., Long, X., Zhang, W., and Zhang, Q., J. Mater. Chem. C, 2020, vol. 8, p. 6342.

    Article  CAS  Google Scholar 

  16. McKenzie, L.K., Bryant, H.E., and Weinstein, J.A., Coord. Chem. Rev., 2019, vol. 379, p. 2.

    Article  CAS  Google Scholar 

  17. Balakina, M.Yu., Shalin, N.I., Sharipova, A.V., and Fominykh, O.D., Mol. Phys., 2020, vol. 118, nos. 21−22, p. 1.

    Article  Google Scholar 

  18. Mendonca, C.R., Baldacchini, T., Tayalia, P., and Mazur, E., J. Appl. Phys., 2007, vol. 102, no. 1, p. 013109.

    Article  Google Scholar 

  19. Tribuzi, V., Fonseca, R.D., Correa, D.S., and Mendonca, C.R., Opt. Mater. Express, 2013, vol. 3, no. 1, p. 21.

    Article  CAS  Google Scholar 

  20. Turro, N.J., Modern Molecular Photochemistry, Sausalito, CA: University Science Books, 1991.

    Google Scholar 

  21. Vijayakumar, C., Balan, B., Kim, M.-J., and Takeuchi, M., J. Phys. Chem. C, 2011, vol. 115, p. 4533.

    Article  CAS  Google Scholar 

  22. Lim, S.L., Li, N.-J., Lu, J.-M., Ling, Q.-D., Zhu, C.X., Kang, E.-T., and Neoh, K.G., ACS Appl. Mater. Interfaces, 2009, vol. 1, no. 1, p. 60.

    Article  CAS  PubMed  Google Scholar 

  23. Qiu, F.X., Zhang, Q., and Yang, D.Y., Mater. Sci. Forum, 2010, vol. 663–665, p. 645.

    Article  Google Scholar 

  24. Armarego, W.L.F. and Chai, C.L.L., Purification of Laboratory Chemicals, Amsterdam: Butterworth–Heinemann (Elsevier Science), 2003, 5th ed.

  25. Eltaboni, F., Bader, N., El-Kailany, R., Elsharif, N., and Ahmida, A., J. Chem. Rev., 2022, vol. 4, no. 4, p. 313.

    CAS  Google Scholar 

Download references

Funding

The work was supported by the Russian Science Foundation, project no. 19-73-10173-P. The research was carried out using the equipment of the shared-use center “Analytical Center at the Institute of Organometallic Chemistry of the Russian Academy of Sciences” with the support of the grant “Ensuring the development of material and technical infrastructure of centers for shared use of scientific equipment” (Unique identifier RF—2296.61321X0017, agreement no. 075-15-2021-670).

Author information

Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia

    M. V. Arsenyev, E. R. Zhiganshina, V. A. Ilyichev, R. S. Kovylin & S. A. Chesnokov

  2. Moscow Institute of Physics and Technology (National Research University), 141700, Dolgoprudnyi, Moscow oblast, Russia

    D. A. Kolymagin & A. G. Vitukhnovsky

  3. Lebedev Physical Institute, Russian Academy of Sciences, 119991, Moscow, Russia

    A. G. Vitukhnovsky

Authors
  1. M. V. Arsenyev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. R. Zhiganshina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. A. Kolymagin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Ilyichev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. S. Kovylin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. G. Vitukhnovsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. S. A. Chesnokov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. R. Zhiganshina.

Ethics declarations

The authors declare no conflict of interest.

Additional information

Translated by S. Zatonsky

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Arsenyev, M.V., Zhiganshina, E.R., Kolymagin, D.A. et al. Methacrylate-Сontaining Para-Derivatives of N,N-Diethyl-4-(phenyldiazenyl)aniline as Initiators in Two-Photon Polymerization. High Energy Chem 58, 295–301 (2024). https://doi.org/10.1134/S0018143924700115

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0018143924700115

Keywords:

Search

Navigation