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Effects of Azomethine Derivatives of 4,6-Di-tert-Butyl-2,3-Dihydroxybezaldehyde on Radiation-Induced Reactions Involving Alkyl and Alpha-Hydroxyalkyl Radicals

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Abstract

The effects of azomethine derivatives of 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde on the formation of radiolysis products of deaerated n-hexane and ethanol have been studied. It was shown that the catechol moiety in the tested compounds did not significantly affect their reactions with carbon-centered radicals. The aldimine group exhibited high activity as an α-hydroxyalkyl radical scavenger and low activity as a scavenger of alkyl radicals. The introduction of additional radical-inhibiting groups –OH, –SH, –NO2, and =N–NH– into the side fragment of a molecule led to a significant increase in the antiradical activity with respect to various types of carbon-centered radicals.

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Funding

The results of this work were obtained in part within the framework of the state scientific research program Chemical Processes, Reagents, Technologies, Bioregulators, and Bioorganic Chemistry (project no. 2.2.01.05).

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Authors and Affiliations

  1. Research Institute of Physical and Chemical Problems, Belarussian State University, 220006, Minsk, Belarus

    G. A. Ksendzova, N. I. Ostrovskaya, R. L. Sverdlov & V. L. Sorokin

  2. Belarussian State University, 220030, Minsk, Belarus

    R. L. Sverdlov & V. L. Sorokin

Authors
  1. G. A. Ksendzova
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  2. N. I. Ostrovskaya
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  3. R. L. Sverdlov
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  4. V. L. Sorokin
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Corresponding author

Correspondence to G. A. Ksendzova.

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Translated by V. Makhlyarchuk

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Ksendzova, G.A., Ostrovskaya, N.I., Sverdlov, R.L. et al. Effects of Azomethine Derivatives of 4,6-Di-tert-Butyl-2,3-Dihydroxybezaldehyde on Radiation-Induced Reactions Involving Alkyl and Alpha-Hydroxyalkyl Radicals. High Energy Chem 57, 489–493 (2023). https://doi.org/10.1134/S0018143923060085

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