Abstract
The oxidative and nonoxidative conversion of ethylene in a dielectric barrier discharge in the presence of water with the formation of predominantly unsaturated compounds (acetylene, butene, butadiene) has been studied. The efficiency of ethylene conversion in argon is shown in comparison with its oxidation by air into oxygenates. A simple theoretical estimate of the energy loss of discharge electrons in the feed gas mixture and simple kinetic calculations make it possible to explain both the change in the degree of ethylene conversion and the direction of the process.
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Funding
The work was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the state assignment of the Institute of Petroleum Chemistry (Siberian Branch of the Russian Academy of Sciences), project no. FWRN-2021-0003.
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Translated by S. Zatonsky
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Ryabov, A.Y., Kudryashov, S.V. Oxidative and Nonoxidative Conversion of Ethylene in Dielectric Barrier Discharge. High Energy Chem 57, 364–368 (2023). https://doi.org/10.1134/S0018143923040124
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DOI: https://doi.org/10.1134/S0018143923040124