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Radiation-Initiated Dehalogenation of 1-Fluoro-2-Methoxyethane in Aqueous Solution

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Abstract

The γ-radiolysis of 0.001 M fluoromethoxyethane solutions has been studied in an inert atmosphere and in the presence of oxygen. The yield of fluoride ions decreases from 1.79 to 0.54 molecule/100 eV on going from an inert atmosphere to oxygen. It has been found that in an argon atmosphere, fluoride ions are formed from the F–•CHCH2OCH3 and FCH2–•CHOCH3 radicals by replacing fluoride ions with water molecules.

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Funding

This work was supported by the Ministry of Education of the Republic of Belarus in accordance with the state program of scientific research “Energy and Nuclear Processes and Technologies” (state registration no. 20211538 of May 24, 2021).

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Authors and Affiliations

  1. Belarusian State University, 220030, Minsk, Belarus

    V. S. Kosobutskii, O. V. Tugai, R. L. Sverdlov & S. D. Brinkevich

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  1. V. S. Kosobutskii
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  2. O. V. Tugai
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  3. R. L. Sverdlov
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  4. S. D. Brinkevich
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Corresponding author

Correspondence to V. S. Kosobutskii.

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The authors declare that they have no conflicts of interest.

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Translated by V. Makhlyarchuk

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Kosobutskii, V.S., Tugai, O.V., Sverdlov, R.L. et al. Radiation-Initiated Dehalogenation of 1-Fluoro-2-Methoxyethane in Aqueous Solution. High Energy Chem 56, 277–279 (2022). https://doi.org/10.1134/S0018143922040105

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  • DOI: https://doi.org/10.1134/S0018143922040105

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