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Degradation of Polyethersulfone in Homogeneous System by Gamma-Ray Irradiation

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Abstract

The gamma-ray irradiation-induced degradation of poly(ether sulfone) (PES) in a homogeneous system has been studied. By dissolving the polymer in different organic solvents, the degradation effect of gamma-ray irradiation on PES increases significantly except for dimethyl sulphoxide (DMSO). This phenomenon is supported by the experimental results of GPC. The enhancement effect of a homogeneous system is explained by increased gamma-ray irradiation energy harvesting capacity due to the presence of organic solvent molecules.

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REFERENCES

  1. Singh, B. and Sharma, N., Polym. Degrad. Stab., 2008, vol. 93, p. 561.

    Article  CAS  Google Scholar 

  2. Göpferich, A., Biomaterials, 1996, vol. 17, p. 103.

    Article  Google Scholar 

  3. Cao, J., Su, W., Wu, Z., Liu, J., Kitayama, T., and Hatada, K., Polymer, 1996, vol. 37, p. 4579.

    Article  CAS  Google Scholar 

  4. Shen, L., Bian, X., Lu, X., Shi, L., Liu, Z., Chen, L., Hou, Z., and Fan, K., Desalination, 2012, vol. 293, p. 21.

    Article  CAS  Google Scholar 

  5. Kai, F., Liu, E., Zhou, G., and Li, J., Polym. Sci., Ser. B, 2020, vol. 62, p. 550.

    Google Scholar 

  6. Brown, J.R. and O’Donnell, J.H., J. Appl. Polym. Sci., 1979, vol. 23, p. 2763.

    Article  CAS  Google Scholar 

  7. Brown, J.R. and O’Donnell, J.H., J. Appl. Polym. Sci., 1975, vol. 19, p. 405.

    Article  CAS  Google Scholar 

  8. Lu, S., Hu, H. Hu, G., and Liu, B., Radiat. Phys. Chem., 2015, vol. 108, p. 74.

    Article  CAS  Google Scholar 

  9. Singh, A., Radiat. Phys. Chem., 1999, vol. 56, p. 375.

    Article  CAS  Google Scholar 

  10. Qin, Q., Hou, Z., Lu, X., Bian, X., Chen, L., Shen, L., and Wang, S., J. Membr. Sci., 2013, vol. 427, p. 303.

    Article  CAS  Google Scholar 

  11. Hester, J.F., Banerjee, P., Won. Y.Y., Akthakul, A., Acar, M.H., and Mayes, A.M., Macromolecules, 2002, vol. 35, p. 7652.

    Article  CAS  Google Scholar 

  12. Karaduman, A., Energy Sources, 2002, vol. 24, p. 667.

    Article  CAS  Google Scholar 

  13. Fan, K., Li, L.F. and Li, J.J., High Energy Chem., 2021, vol. 55, p. 140.

    Article  CAS  Google Scholar 

  14. Fan, K., Liu, C., Su, J., and Li, J.H., High Energy Chem., 2021, vol. 55, p. 300.

    Article  CAS  Google Scholar 

  15. Gugumus, F., Polym. Degrad. Stab., 1993, vol. 39, p. 117.

    Article  CAS  Google Scholar 

  16. Coulter, D.R., Smith, M.V., Tsay, F.-D., Gupta, A., and Fornes, R.E., J. Appl. Polym. Sci., 1985, vol. 30, p. 1753.

    Article  CAS  Google Scholar 

  17. Serrano, D.P., Aguado, J., Vicente, G., and Sánchez N., J. Anal. Appl. Pyrolysis, 2007, vol. 78, p. 194.

    Article  CAS  Google Scholar 

  18. Madras, G. and Chattopadhyay, S., Polym. Degrad. Stab., 2001, vol. 71, p. 273.

    Article  CAS  Google Scholar 

  19. Sato, TS., Murakata, T., Baba, S., Saito, Y., and Watanabe, S., J. Appl. Polym. Sci., 1990, vol. 40, p. 2065.

    Article  CAS  Google Scholar 

  20. LeVan, H. and Moos, W.S., Experientia, 1967, vol. 23, p. 276.

    Article  CAS  Google Scholar 

  21. Santos, N.C., Figueira-Coelho, J., Martins-Silva, J., and Saldanha, C., Biochem. Pharmacol., 2003, vol. 65, p. 1035.

    Article  CAS  Google Scholar 

  22. Rosiak, J. and Schnabel, W., J. Radioanal. Nucl. Chem., 1986, vol. 101, p. 433.

    Article  CAS  Google Scholar 

  23. Nafisi-Movaghar, J., Birks, J.B., and Naqvi, K.R., Proc. Phys. Soc., 1967, vol. 91, p. 449.

    Article  CAS  Google Scholar 

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Funding

The authors acknowledge the financial support from the Natural Science Foundation of Gansu Province (Project no. 20JR10RA778), Science and Technology Research Project of Chongqing Education Commission (Project no. KJQN202003103), the Open Projects of CAS Key Laboratory of Interfacial Physics and Technology (Project no. CASKL-IPT2002), School Level Scientific Research Proj-ect of Chongqing College of Electronic Engineering (Project no. XJZK202107).

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Correspondence to Jihao Li.

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Fan, K., Huang, J., Wu, F. et al. Degradation of Polyethersulfone in Homogeneous System by Gamma-Ray Irradiation. High Energy Chem 56, 251–257 (2022). https://doi.org/10.1134/S0018143922040099

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  • DOI: https://doi.org/10.1134/S0018143922040099

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