Skip to main content
SpringerLink
Log in

Microporosity of Polynorbornenes by Positron Annihilation and Sorption Data

  • GENERAL ASPECTS
  • Published:
High Energy Chemistry Aims and scope Submit manuscript

Abstract

Based on positron annihilation and low-temperature gas (CO2) sorption data, we discuss the nature of size distribution of micropores in a number of polynorbornenes with various substituent groups in the side chain. The local stiffness of highly permeable glassy polymers suggests that they are microheterogeneous. In this case, distributions that are bimodal in nature seem quite possible, although unimodal cases cannot be excluded either. The positron annihilation data are consistent with these concepts and correlate with permeability. At the same time, the positron and sorption data on porosity are found to have discrepancies, which are explained either by limited mobility of the positronium atom or by inaccuracy of description of the sorption curve according to the density functional theory (NLDFT) and the Monte Carlo method (GCMC).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. Rudel, M., Krause, J., Ratzke, K., Faupel, M., Yampolskii, Yu., Shantarovich, V., and Dlubek, G., Macromolecules, 2008, vol. 41, p. 788.

    Article  CAS  Google Scholar 

  2. Shantarovich, V.P., J. Polym. Sci., Part B: Polym. Phys., 2008, vol. 46, p. 2485.

    Article  CAS  Google Scholar 

  3. Weber, M.H. and Lynn, K.G., Principles and Applications of Positron and Positronium Chemistry, Jean, Y.C., Mallon, P.E., and Schrader, D.M., Eds., Singapore: World Scientific, 2003, p. 167.

    Google Scholar 

  4. Shantarovich, V.P., Bekeshev, V.G., Kevdina, I.B., Yampol’skii, Yu.P., Bermeshev, M.V., and Belov, N.A., High Energy Chem., 2018, vol. 52, no. 4, p. 275.

    Article  CAS  Google Scholar 

  5. Horwath, G. and Kawazoe, R., J. Chem. Eng. Jpn., 1983, vol. 16, no. 6, p. 373.

    Google Scholar 

  6. NOVAWIN2 Version 2. 1: Operating Manual, Boynton Beach, FL: Quantachrome Instruments, 2004.

  7. Saito, A. and Foley, H.C., AlChE J., 1991, vol. 37, no. 3, p. 429.

    Article  CAS  Google Scholar 

  8. Barrett, E.P., Joyner, L.G., and Halenda, P.P., J. Am. Chem. Soc., 1951, vol. 73, p. 373.

    Article  CAS  Google Scholar 

  9. Vyacheslavov, A.S. and Efremova, M., Opredelenie ploshchadi poverkhnosti i poristosti materialov metodom sorbtsii gazov. Metodicheskaya razrabotka (A Tutorial on Determination of Surface Area and Porosity of Materials by Gas Sorption), Moscow: MGU, 2011.

  10. Starodubov, S.S., Nechaev, I.V., and Vvedenskii, A.V., Sorbts. Khromatogr. Protsessy, 2014, vol. 14, no. 2, p. 296.

    CAS  Google Scholar 

  11. Shantarovich, V.P., Bekeshev, V.G., Bermeshev, M.V., Alentiev, D.A., Gustov, V.W, Belousova, E.V., Kevdina, I.B., and Novikov, Yu.A., High Energy Chem., 2019, vol. 53, no. 4, p. 276.

    Article  CAS  Google Scholar 

  12. Wozniak, A.I., Bermesheva, E.V., Borisov, I.L., Petukhov, D.I., Bermeshev, M.V., Volkov, A.V., and Finkelshtein, E.S., Macromol. Rapid Commun., 2019, vol. 40, no. 20, p. 1900206.

    Article  CAS  Google Scholar 

  13. Bermesheva, E.V., Wozniak, A.I., Borisov, I.L., Yevlampieva, N.P., Vezo, O.S., Karpov, G.O., Bermeshev, M.V., Asachenko, A.F., Topchiy, M.A., Gribanov, P.S., Nechaev, M.S., Volkov, V.V., and Finkelshtein, E.S., Polym. Sci., Ser. C, 2019, vol. 61, no. 1, p. 86.

    Article  CAS  Google Scholar 

  14. Bermesheva, E.V., Wozniak, A.I., Andreyanov, F.A., Karpov, G.O., Nechaev, M.S., Asachenko, A.F., Topchiy, M.A., Melnikova, E.K., Nelyubina, Y.V., Gribanov, P.S., and Bermeshev, M.V., ACS Catal., 2020, vol. 10, no. 3, p. 1663.

    Article  CAS  Google Scholar 

  15. Wozniak, A.I., Bermesheva, E.V., Andreyanov, F.A., Borisov, I.L., Zarezin, D.P., Bakhtin, D.S., Gavrilova, N.N., Ilyasov, I.R., Nechaev, M.S., Asachenko, A.F., Topchiy, M.A., Volkov, A.V., Finkelshtein, E.S., and Ren, X.-K., M, React. Funct. Polym., 2020, p. 104513.

  16. Garrido, J., Linares-Solano, A., Martin-Martinez, J.M., Molina-Sabio, M., Rodriguez-Reinozo, F., and Torregroza, R., Langmuir, 1987, vol. 3, no. 1, pp. 76–81.

    Article  CAS  Google Scholar 

  17. Gun’ko, V.M., Leboda, R., Skubishevska-Zieba, J., Gawdzik, B., and Charmas, B., Appl. Surf. Sci., 2005, vol. 252, p. 612.

    Article  Google Scholar 

  18. Garcia-Martinez, J., Cazorla-Amoros, D., and Linares-Solano, A., Characterization of Porous Solids V, Unger, K.K., Kreysa, G., and Baselt, J.P., Eds., Amsterdam: Elsevier, 2000, p. 485.

    Google Scholar 

  19. Zhu, Y., Murali, S., Stoller, M.D., Ganesh, K.J., et al., Science, 2011, vol. 332, p. 1537.

    Article  CAS  Google Scholar 

  20. Thommes, M., Cychosz, K.A., and Neimark, A.V., Novel Carbon Adsorbents, Tascon, J.M.D., Ed., Amsterdam: Elsevier, 2012, ch. 4, p. 107.

    Google Scholar 

  21. Weber, J., Najying, Du., and Guiver, M.D., Macromolecules, 2011, vol. 44, p. 1763.

    Article  CAS  Google Scholar 

  22. Elmehalmey, W.A., Azzam, R.A., Hassan, Y.S., Alkordi, M.H., and Madkour, T.M., ACS Omega, 2018, vol. 3, p. 2757.

    Article  CAS  Google Scholar 

  23. Dlubek, G. and Eichler, S., Phys. Status Solidi A, 1998, vol. 168, p. 333.

    Article  CAS  Google Scholar 

  24. Zaleski, R., Stefanniak, W., Maciejewska, M., and Goworek, J., J. Porous Matter, 2009, vol. 16, p. 91.

    Article  Google Scholar 

  25. Alentiev, D.A., Bermeshev, M.V., Starannikova, L.E., Bermesheva, E.V., Shantarovich, V.P., Bekeshev, V.G., Yampolskii, Yu.P., and Finkelshtein, E.S., J. Polym. Sci., Part A: Polym. Chem., 2018, vol. 56, p. 1234.

    Article  CAS  Google Scholar 

  26. Tokarev, A.V., Bondarenko, G.N., and Yampol’skii, Yu.P., Polym Sci., Ser. A., 2007, vol. 49, no. 8, p. 909.

    Article  Google Scholar 

  27. Budd, P.M., McKeown N.B., Fritsch D., Yampolskii Yu., and Shantarovich V., Membrane Gas Separation, Yampolskii, Yu. and Freeman, B., Eds., Chichester: Wiley, 2010, p. 29.

    Google Scholar 

  28. Dlubek, G., Eichler, S., Hubner, Ch., and Nagel, Ch., Phys. Status Solidi A, 1999, vol. 174, p. 313.

    Article  CAS  Google Scholar 

  29. Rudel, M., Krauze, J., Ratzke, K., Faupel, F., Yampolskii, Yu.P., and Shantarovich, V.P., Macromolecules, 2008, vol. 41, p. 788.

    Article  CAS  Google Scholar 

  30. Hofmann, D., Entrialgo-Castano, M., Lebret, A., Heuchel, M., and Yampolskii, Yu.P., Macromolecules, 2003, vol. 36, p. 8528.

    Article  CAS  Google Scholar 

  31. Mazo, M., Balabaev, N., Alentiev, A., and Yampolskii, Yu., Macromolecules, 2018, vol. 51, no. 4, p. 1398.

    Article  CAS  Google Scholar 

  32. Shantarovich, V.P., Gustov, V.V., Belousova, E.V., Polyakova, A.V., Bekeshev, V.G., and Kevdina, I.B., Russ. J. Phys. Chem. B, 2014, vol. 8, no. 4, p. 559.

    Article  CAS  Google Scholar 

  33. Badd, P.M., Msaib, K.J., Tattershall, C.S., et al., J. Membr. Sci., 2005, vol. 251, p. 263.

    Article  Google Scholar 

  34. Shantarovich, V.P., Suzuki, T., He, C., Davankov, V.A., Pastukhov, A.V., Tsurupa, M.P., et al., Macromolecules, 2002, vol. 35, p. 9723.

    Article  CAS  Google Scholar 

  35. Shantarovich, V.P., Bekeshev, V.G., Pastukhov, A.V., Davankov, V.A., Krasil’nikova, O.K., et al., J. Phys., Conf. Ser., 2015, vol. 618, p. 92.

    Article  Google Scholar 

  36. Shantarovich, V.P., Novikov, Yu.A., Suptel, Z.K., Kevdina, I.B., Khotimskii, V.S., and Yampolskii, Yu.P., Radiat. Phys. Chem., 2000, vol. 58, p. 513.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Semenov Research Center for Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    V. P. Shantarovich, V. G. Bekeshev & I. B. Kevdina

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    M. V. Bermeshev & A. I. Wozniak

Authors
  1. V. P. Shantarovich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. G. Bekeshev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. B. Kevdina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. V. Bermeshev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. I. Wozniak
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. P. Shantarovich.

Additional information

Translated by S. Zatonsky

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shantarovich, V.P., Bekeshev, V.G., Kevdina, I.B. et al. Microporosity of Polynorbornenes by Positron Annihilation and Sorption Data. High Energy Chem 55, 80–87 (2021). https://doi.org/10.1134/S0018143921010112

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0018143921010112

Keywords:

Search

Navigation