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Use of Radiation-Synthesized Tetrafluoroethylene Telomers with Silane End Groups for Hydrophobization of Polyester Fabric

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Abstract

The optimal parameters of radiation-initiated synthesis in trimethylchlorosilane of tetrafluoroethylene telomers intended for hydrophobization of polyester fabrics have been determined. The efficiency of using tetrafluoroethylene telomers with silane end groups as water repellents has been evaluated. It has been shown that treatment of polyester fabric with tetrafluoroethylene telomer solutions makes it possible to form a highly hydrophobic coating characterized by a contact angle of water of about 120° and high resistance to factors affecting the performance. The hydrophobized fabric possesses uniquely low water absorption and good hygienic properties.

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ACKNOWLEDGMENTS

This work was carried out using the Gammatok-100 unique research facility at the Institute of Problems of Chemical Physics, equipment of the Analytical Center for Shared Use at the same Institute, and the Center for Shared Use of Scientific Equipment “Upper Volga Regional Center for Physicochemical Research.”

Funding

This work was supported by the Russian Foundation for Basic Research and the Ivanovo oblast administration, project no. r_tsentr_a 18-48-370005; the Russian Academy of Sciences under Presidium basic research program no. 55 “The Arctic—Scientific Principles of New Technologies for Exploration, Conservation and Development”; and State Assignment, theme no. 0089-2020-0008.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    G. A. Kichigina, P. P. Kushch & D. P. Kiryukhin

  2. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045, Ivanovo, Russia

    N. P. Prorokova & T. Yu. Kumeeva

Authors
  1. G. A. Kichigina
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  2. P. P. Kushch
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  3. D. P. Kiryukhin
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  4. N. P. Prorokova
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  5. T. Yu. Kumeeva
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Corresponding authors

Correspondence to G. A. Kichigina or D. P. Kiryukhin.

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Translated by S. Zatonsky

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Kichigina, G.A., Kushch, P.P., Kiryukhin, D.P. et al. Use of Radiation-Synthesized Tetrafluoroethylene Telomers with Silane End Groups for Hydrophobization of Polyester Fabric. High Energy Chem 54, 123–129 (2020). https://doi.org/10.1134/S0018143920020095

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  • DOI: https://doi.org/10.1134/S0018143920020095

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