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Dissipative Processes in Irradiated Latex Polymers

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Abstract

The dissipative processes of α-, β-, and μ-relaxation in irradiated acrylic latex polymers have been studied by means of dynamic mechanical relaxation spectroscopy. Radiation-induced changes in the temperature position of maxima and intensity of dissipative processes in the internal friction spectra of the polymers have been revealed. The manifestation of the effects depends on the rubber elasticity of the polymer and the presence of functional groups.

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ACKNOWLEDGMENTS

The authors are grateful to E.I. Saunin, a research associate at the Frumkin Institute for assistance in the irradiation of polymer samples.

Funding

The study of the physicochemical properties and structure of latex polymers was supported by the Russian Academy of Sciences under the Presidium program “Physicochemical Principles of Highly Efficient Processes for Fabricating Multilayer Nanoparticles and Film Nanocomposites with Pronounced Functionalities (Including Protective, Mechanical, etc. Properties).”

Investigation of the effect of ionization radiation on the relaxation structure and elastic properties of polyacrylates was carried out in the framework of the government assignment on the topic “Relaxation, deformation and strength properties of binary or multicomponent polymer systems and the influence on their structural and physicochemical characteristics of electromagnetic radiation, including UV, microwave, gamma, neutron, and cosmic radiation.”

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    T. R. Aslamazova, V. A. Kotenev, N. Yu. Lomovskaya, V. A. Lomovskoy & A. Yu. Tsivadze

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  1. T. R. Aslamazova
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  2. V. A. Kotenev
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  3. N. Yu. Lomovskaya
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  4. V. A. Lomovskoy
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  5. A. Yu. Tsivadze
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Corresponding author

Correspondence to T. R. Aslamazova.

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Translated by S. Zatonsky

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Aslamazova, T.R., Kotenev, V.A., Lomovskaya, N.Y. et al. Dissipative Processes in Irradiated Latex Polymers. High Energy Chem 53, 371–375 (2019). https://doi.org/10.1134/S0018143919050023

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  • DOI: https://doi.org/10.1134/S0018143919050023

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