Skip to main content
Log in

EPR and fluorescence study of molecular dynamics of lipids in bilayers adsorbed on porous silica gel

  • Photonics
  • Published:
High Energy Chemistry Aims and scope Submit manuscript

Abstract

Lipid bilayers immobilized on highly porous silica gel monoliths (SLBs) have been proposed as templates for chemosensors. Procedures for preparation and characterization of SLBs have been developed and applied. Rotational dynamics and orientational ordering at different depths in a SLB membrane and, for comparison, in bilayer liposomes have been studied for the first time using n-PC phospholipid spin labels.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Sackmann, E., Science, 1996, vol. 271, p. 43.

    Article  CAS  Google Scholar 

  2. Hardy, G., Nayak, R., and Zausher, S., Curr. Opin. Coll. Interface Sci., 2013, vol. 18, p. 448.

    Article  CAS  Google Scholar 

  3. Castellana, E.T. and Cremer, P.S., Surf. Sci. Rep., 2006, vol. T. 61, p. C. 429.

    Google Scholar 

  4. Ionova, I.V., Voronina, L.V., Meshkov, B.B., Alfimov, M.V., and Livshits, V.A., Nanotechnol. Russ., 2013, vol. 8, no. 9/10, p. 592.

    Article  Google Scholar 

  5. Voronina, L.V., Alfimov, M.V., and Livshits, V.A., Nanotechnol. Russ., 2011, vol. 6, no. 7/8, p. 444.

    Article  Google Scholar 

  6. Spin Labeling: Theory and Applications, Berliner, L.J., Ed., New York Academic, 1976.

  7. Biological Magnetic Resonance, vol. 8: Spin Labeling: Theory and Applications, Berliner, L.J. and Reuben, J., Eds., New York, Springer, 1989.

  8. Cremer, P.S. and Boxer, G., J. Phys. Chem. B, 1999, vol. 103, p. 2554.

    Article  CAS  Google Scholar 

  9. Tero, R., Materials, 2012, vol. 5, p. 2658.

    Article  CAS  Google Scholar 

  10. Bayerl, T.M. and Bloom, M., Biophys. J., 1990, vol. 58, p. 357.

    Article  CAS  Google Scholar 

  11. Mashaghi, S. and Van Oijen, A.M., Biotechnol. Bioeng., 2014, vol. 111, p. 2076.

    Article  CAS  Google Scholar 

  12. Tabaei, S.R., Choi, J.-Y., Zan, G.H., and Zhdanov, V.P., Langmuir, 2014, vol. 30, p. 10363.

    Article  CAS  Google Scholar 

  13. GuoXing-Zhong Li, Wen-Yan Zhu, Yang Nakanishi Kazuki, Kanamori Kazuyoshi, and Yang Hu, Acta Phys. Chim. Sin., 2013, vol. 29, no. 3, p. 646.

    Google Scholar 

  14. Fajer, P. and Marsh, D., J. Magn. Reson., 1982, vol. 49, p. 212.

    CAS  Google Scholar 

  15. Schneider, D.J. and Freed, J.H., Biological Magnetic Resonance, vol. 8: Spin Labeling: Theory and Applications, Berliner, L.J. and Reuben, J., Eds., New York: Springer, 1989, ch. 1, p. 1.

    CAS  Google Scholar 

  16. Budil, D.E., Lee, S., Saxena, S., and Freed, J.H., J. Magn. Reson., Ser. A, 1996, vol. 120, p. 155.

    Article  CAS  Google Scholar 

  17. McIntyre, J. and Sleight, R.G., Biochemistry, 1991, vol. 30, p. 11819.

    Article  CAS  Google Scholar 

  18. Petrache, H.I., Gouliaev, N., Tristam-Nagle, S., Zhang, R., Suter, R.M., and Nagle, J.F., Phys. Rev. E, 1998, vol. 57, p. 7014.

    Article  CAS  Google Scholar 

  19. Brian, A.A. and McConnell, H.M., Proc. Natl. Acad. Sci. USA, 1984, vol. 81, p. 6159.

    Article  CAS  Google Scholar 

  20. Anderson, T., Min, Y., Zeng, H., Feigenson, D., and Israelishvili, J.N., Langmuir, 2009, vol. 25, p. 6997.

    Article  CAS  Google Scholar 

  21. Livshits, V.A., Kurad, D., and Marsh, D., J. Phys. Chem. B, 2004, vol. 108, p. 9403.

    Article  CAS  Google Scholar 

  22. Dzikovski, B.G., Livshits, V.A., and Freed, J.H., J. Phys. Chem. B, 2015, vol. 119, p. 13330.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. A. Livshits.

Additional information

Original Russian Text © V.A. Livshits, B.B. Meshkov, A.V. Koshkin, B.G. Dzikovskii, M.V. Alfimov, 2017, published in Khimiya Vysokikh Energii, 2017, Vol. 51, No. 4, pp. 271–277.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Livshits, V.A., Meshkov, B.B., Koshkin, A.V. et al. EPR and fluorescence study of molecular dynamics of lipids in bilayers adsorbed on porous silica gel. High Energy Chem 51, 256–262 (2017). https://doi.org/10.1134/S0018143917040099

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0018143917040099

Keywords

Navigation