Abstract
The kinetics of photoreduction under the action of visible light of the 3,6-di-tert-butyl-o-benzoquinone moiety in methacrylic monomer, polymer, and in the graft layer on the surface of pores in the presence of different N,N-dimethylanilines has been studied. The reaction is accelerated with the increasing electron-donating ability of the amine. In the presence of N,N-dimethylaniline at 50-fold molar excess of the amine, the photoreduction in the porous polymer occurs three and four times faster than in the monomer and the polymer, respectively.
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Urban, J. and Jandera, P., Anal. Bioanal. Chem., 2013, vol. 405, p. 2123.
Tetala, K.K.R. and van Beek, T.A., J. Sep. Sci., 2010, vol. 33, p. 422.
Namera, A. and Saito, T., Trends Anal. Chem., 2013, vol. 45, p. 185.
Wang, Y. and Tao, S., Any, J. Mater. Chem. A, 2013, vol. 1, p. 1701.
Eslava, S., Zhang, L., Esconjauregui, S., Yang, J., Vanstreels, K., Baklanov, M., and Saiz, E., Chem. Mater., 2013, vol. 25, p. 27.
Kang, Q.-S., Shen, X.-F., Hu, N.-N., Hu, M.-J., Liao, H., Wang, H.-Z., He, Z.-K., and Huang, W.-H., Analyst, 2013, vol. 138, p. 2613.
Svec, F. and Frechet, J.M.J., Science, 1996, vol. 273, p. 205.
Zhang, P., Weng, Z., Guo, J., and Wang, C., Chem. Mater., 2011, vol. 23, p. 5243.
Han, W., Xin, Y., Hasegawa, U., and Uyama, H., Polym. Degrad. Stab., 2014, vol. 109, p. 362.
Shurygina, M.P., Poddel’sky, A.I., Druzhkov, N.O., Chesnokov, S.A., Fukin, G.K., Cherkasov, V.K., and Abakumov, G.A., J. Polym. Res., 2013, vol. 20, p. 98.
Shushunova, N.Yu., Arsenyev, M.V., Glukhova, T.A., Zaitsev, S.D., and Chesnokov, S.A., Polym Sci., Ser. B, 2015, vol. 57, no. 3, p. 207.
Baten’kin, M.A., Konev, A.N., Mensov, S.N., and Chesnokov, S.A., Polym Sci., Ser. A, 2011, vol. 53, no. 7, p. 558.
Chesnokov, S.A., Lenshina, N.A., Arsenyev, M.V., Kovylin, R.S., Baten’kin, M.A., Poddel’sky, A.I., and Abakumov, G.A., Appl. Organomet. Chem., 2016. doi doi 10.1002/aoc.3553
Shurygina, M.P., Kurskii, Yu.A., Druzhkov, N.O., Chesnokov, S.A., and Abakumov, G.A., High Energy Chem., 2010, vol. 44, no. 3, p. 234.
Abakumov, G.A., Chesnokov, S.A., Cherkasov, V.K., and Razuvaev, G.A., Izv. Akad. Nauk SSSR, Ser. Khim., 1985, no. 3, p. 773.
Gordon, A.J. and Ford, R.A., The Chemist’s Companion, New York Wiley–Interscience, 1972.
Shurygina, M.P., Kurskii, Yu.A., Druzkov, N.O., Chesnokov, S.A., Abakumova, L.G., Fukin, G.K., and Abakumov, G.A., Tetrahedron, 2008, vol. 64, p. 9784.
Klement’eva, S.V., Fukin, G.K., Baranov, E.V., Cherkasov, V.K., and Abakumov, G.A., High Energy Chem., 2011, vol. 45, no. 5, p. 423.
Shurygina, M.P., Lenshina, N.A., Arsenyev, M.V., Poddel’sky, A.I., Zaitsev, S.D., Chesnokov, S.A., and Abakumov, G. A, J. Coord. Chem., 2015, vol. 68, p. 4159.
Chesnokov, S.A., Cherkasov, V.K., Chechet, Yu.V., Nevodchikov, V.I., Abakumov, G.A., and Mamysheva, O.N., Izv. Akad. Nauk, Ser. Khim., 2000, no. 9, p. 1515.
Schönberg, A., Präparative organische Photochemie, Berlin Springer, 1968.
Chesnokov, S.A., Shurygina, M.P., and Abakumov, G.A., High Energy Chem., 2011, vol. 45, no. 4, p. 287.
Shurygina, M.P., Chesnokov, S.A., and Abakumov, G.A., High Energy Chem., 2016, vol. 3, p. 196.
Peters, K.S., Cashin, A., and Timbers, P., J. Am. Chem. Soc., 2000, vol. 122, p. 107.
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Original Russian Text © N.A. Len’shina, M.V. Arsenyev, M.P. Shurygina, S.A. Chesnokov, G.A. Abakumov, 2017, published in Khimiya Vysokikh Energii, 2017, Vol. 51, No. 3, pp. 224–229.
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Len’shina, N.A., Arsenyev, M.V., Shurygina, M.P. et al. Photoreduction of o-benzoquinone moiety in mono- and poly(quinone methacrylate) and on the surface of polymer matrix pores. High Energy Chem 51, 209–214 (2017). https://doi.org/10.1134/S0018143917030080
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DOI: https://doi.org/10.1134/S0018143917030080