Abstract
It has been shown that the addition of molecular bromine to the monomer acrylamide (AA) results in the spontaneous formation of radicals. During heating the AA + Br2 mixture, the radicals initiate polymerization and bromination reactions. Beginning well below the melting point of bromine, both the reactions proceed at a noticeable rate at its melting temperature.
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Original Russian Text © D.A. Gordon, G.A. Kichigina, A.I. Mikhailov, 2016, published in Khimiya Vysokikh Energii, 2016, Vol. 50, No. 5, pp. 353—357.
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Gordon, D.A., Kichigina, G.A. & Mikhailov, A.I. Processes occurring during the interaction of molecular bromine with acrylamide at low temperatures and upon heating the mixture. High Energy Chem 50, 334–338 (2016). https://doi.org/10.1134/S001814391605009X
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DOI: https://doi.org/10.1134/S001814391605009X