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Fabrication of microstructured materials based on chitosan and D,L-lactide copolymers using laser-induced microstereolithography

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Abstract

The graft copolymers of chitosan and oligo(D,L-lactide) obtained by solid-phase synthesis have been used as the basis of photosensitive compositions for the fabrication of three-dimensional microstructures by laser-induced stereolithography. The electronic absorption spectra of the copolymers are close to the sum of the spectra of native chitosan and polylactide, which has been chosen as a model of grafted oligolactide chains. The fundamental absorption bands of the copolymers lie in a range to 500 nm, and their contribution to the absorption intensity of a photosensitive composition based on the copolymers at second harmonic laser frequency is insignificant. Depending on the macromolecular characteristics of the copolymers, the three-dimensional crosslinking of photosensitive compositions on their basis in the course of microstructuring occurs with different efficiency.

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Authors and Affiliations

  1. Sechenov First Moscow State Medical University, Ministry of Health of the Russian Federation, ul. Bol’shaya Pirogovskaya 2-4, Moscow, 119991, Russia

    T. S. Demina & D. V. Butnaru

  2. Institute of Laser and Information Technologies, Russian Academy of Sciences, ul. Pionerskaya 2, Troitsk, Moscow, 142092, Russia

    K. N. Bardakova, N. V. Minaev, G. I. Pudovkina, M. M. Novikov, V. N. Bagratashvili & P. S. Timashev

  3. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, ul. Profsoyuznaya 70, Moscow, 117393, Russia

    E. A. Svidchenko, N. M. Surin, T. A. Akopova & A. N. Zelenetskii

Authors
  1. T. S. Demina
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  2. K. N. Bardakova
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  3. E. A. Svidchenko
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  4. N. V. Minaev
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  5. G. I. Pudovkina
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  6. M. M. Novikov
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  7. D. V. Butnaru
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  8. N. M. Surin
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  9. T. A. Akopova
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  10. V. N. Bagratashvili
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  11. A. N. Zelenetskii
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  12. P. S. Timashev
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Corresponding author

Correspondence to T. S. Demina.

Additional information

Original Russian Text © T.S. Demina, K.N. Bardakova, E.A. Svidchenko, N.V. Minaev, G.I. Pudovkina, M.M. Novikov, D.V. Butnaru, N.M. Surin, T.A. Akopova, V.N. Bagratashvili, A.N. Zelenetskii, P.S. Timashev, 2016, published in Khimiya Vysokikh Energii, 2016, Vol. 50, No. 5, pp. 411—416.

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Demina, T.S., Bardakova, K.N., Svidchenko, E.A. et al. Fabrication of microstructured materials based on chitosan and D,L-lactide copolymers using laser-induced microstereolithography. High Energy Chem 50, 389–394 (2016). https://doi.org/10.1134/S0018143916050088

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  • DOI: https://doi.org/10.1134/S0018143916050088

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