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EPR study of spin interactions in the poly(3-dodecylthiophene): Fullerene/polyaniline: p-toluenesulfonic acid composite

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Abstract

Magnetic, relaxation, and dynamic parameters of polarons P1 ·+, trapped in p-toluenesulfonic aciddoped polyaniline, polarons P2 ·+, and fullerene radical anions photoinduced in the poly(3-dodecylthiophene)/methanofullerene composite and in mixtures of these composites have been investigated using the EPR technique. It has been shown that spin charge carriers P2 ·+ during diffusion along poly(3-dodecylthiophene) chains interact with P1 ·+ trapped on adjacent polymer chains of polyaniline. The exchange interaction and spin relaxation in the ternary composites is determined by the activated hopping mobility of polarons P2 ·+ and depends on the composition of the material.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    E. I. Yudanova, V. R. Bogatyrenko & V. I. Krinichnyi

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  1. E. I. Yudanova
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  2. V. R. Bogatyrenko
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  3. V. I. Krinichnyi
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Correspondence to E. I. Yudanova.

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Original Russian Text © E.I. Yudanova, V.R. Bogatyrenko, V.I. Krinichnyi, 2016, published in Khimiya Vysokikh Energii, 2016, Vol. 50, No. 2, pp. 132–138.

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Yudanova, E.I., Bogatyrenko, V.R. & Krinichnyi, V.I. EPR study of spin interactions in the poly(3-dodecylthiophene): Fullerene/polyaniline: p-toluenesulfonic acid composite. High Energy Chem 50, 127–133 (2016). https://doi.org/10.1134/S0018143916010112

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  • DOI: https://doi.org/10.1134/S0018143916010112

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