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Role of chemiexcited particles in permanganate reduction by citric acid: Investigation with spectrophotometric and chemiluminescence methods

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Abstract

Potassium permanganate reduction by citric acid in the presence of sulfuric acid includes stages of chemigeneration of electronically excited Mn(II) and emission of photons by it. The electronic absorption, reactant concentration, and chemiluminescence kinetics have been investigated. It has been shown that the chemiexcited species Mn(II) (chemiluminescence emitter) acts as a permanganate reduction catalyst.

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References

  1. Adam, W., Kazakov, D.V., and Kazakov, V.P., Chem. Rev., 2005, vol. 105, no. 9, p. 3371.

    Article  CAS  Google Scholar 

  2. Ciscato, L.F.M.L., Weiss, D., Beckert, R., Bastos, E.L., Bartoloni, F.H., and Baader, W.J., New J. Chem., 2011, vol. 35, no. 4, p. 773.

    Article  CAS  Google Scholar 

  3. Tsaplev, Yu.B., Vasil’ev, R.F., and Trofimov, A.V., High Energy Chem., 2014, vol. 48, no. 3, p. 191.

    Article  CAS  Google Scholar 

  4. Karavaev, A.D., Voloshin, A.I., and Kazakov, V.P., Teor. Eksp. Khim., 1989, vol. 25, no. 2, p. 191.

    CAS  Google Scholar 

  5. Tsaplev, Yu.B., Zh. Fiz. Khim., 1991, vol. 65, no. 3, p. 799.

    CAS  Google Scholar 

  6. Hindson, C.M., Francis, P.S., Hanson, G.R., Adcock, J.L., and Barnett, N.W., Anal. Chem., 2010, vol. 82, no. 10, p. 4174.

    Article  CAS  Google Scholar 

  7. Berka, A., Barek, J., and Hladikova, A., Microchem. J., 1979, vol. 24, no. 4, p. 431.

    Article  CAS  Google Scholar 

  8. Tronov, B.V. and Zharikov, I.I., Izv. SKhTI, 1931, no. 2, p. 1.

    Google Scholar 

  9. Ladbury, J.W. and Cullis, C.F., Chem. Rev., 1958, vol. 58, no. 2, p. 403.

    Article  CAS  Google Scholar 

  10. Selim, R.G. and Lingane, J.J., Anal. Chim. Acta, 1959, vol. 21, p. 536.

    Article  CAS  Google Scholar 

  11. Morrow, J.I. and Perlman, S., Inorg. Chem., 1973, vol. 12, no. 10, p. 2453.

    Article  CAS  Google Scholar 

  12. Bailey, N., Carrington, A., Lott, K.A.K., and Symons, M.C.R., J. Chem. Soc. (Resumed), 1960, p. 290.

    Google Scholar 

  13. Chai, X.S. and Zhu, J.Y., J. Pulp Paper Sci., 1999, vol. 25, no. 11, p. 387.

    CAS  Google Scholar 

  14. Zakhedi, M. and Bakhrami, Kh., Kinet. Katal., 2004, vol. 45, no. 3, p. 377.

    Google Scholar 

  15. Hindson, C.M., Smith, Z.M., Barnett, N.W., Hanson, G.R., Lim, K.F., and Francis, P.S., J. Phys. Chem. A, 2013, vol. 117, p. 3918.

    Article  CAS  Google Scholar 

  16. Sveshnikova, E.B. and Ermolaev, V.L., Opt. Spektrosk., 2011, vol. 111, no. 1, p. 38.

    Article  Google Scholar 

  17. White, E.H., Wiecko, J., and Roswell, D.F., J. Am. Chem. Soc., 1969, vol. 91, no. 18, p. 5194.

    Article  CAS  Google Scholar 

  18. Ambartzumian, R.V., Chem. Phys. Lett., 2004, vol. 400, no. 4, p. 531.

    Google Scholar 

  19. Kalnin’sh, K.K., Elektronnoe vozbuzhdenie v khimii (Electronic Excitation in Chemistry), St. Petersburg: IPTs SPGUTD, 1998.

    Google Scholar 

  20. Kalnin’sh, K.K. and Panarin, E.F., Vozbuzhdennye sostoyaniya v khimii polimerov (Excited States in Polymer Chemistry), St. Petersburg: IPTs SPGUTD, 2007.

    Google Scholar 

  21. Lechtken, P., Yekta, A., and Turro, N.J., J. Am. Chem. Soc., 1973, vol. 98, no. 9, p. 3027.

    Article  Google Scholar 

  22. Kazakov, V.P., Voloshin, A.I., and Shavaleev, N.M., J. Photochem. Photobiol. A, 1998, vol. 119, no. 3, p. 177.

    Article  CAS  Google Scholar 

  23. Nazarov, A.M., Khursan, S.L., and Yamilova, G.A., React. Kinet. Catal. Lett., 1999, vol. 68, no. 2, p. 299.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119334, Russia

    Yu. B. Tsaplev, R. F. Vasil’ev & A. V. Trofimov

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  1. Yu. B. Tsaplev
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  2. R. F. Vasil’ev
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  3. A. V. Trofimov
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Correspondence to Yu. B. Tsaplev.

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Original Russian Text © Yu.B. Tsaplev, R.F. Vasil’ev, A.V. Trofimov, 2014, published in Khimiya Vysokikh Energii, 2014, Vol. 48, No. 6, pp. 467–471.

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Tsaplev, Y.B., Vasil’ev, R.F. & Trofimov, A.V. Role of chemiexcited particles in permanganate reduction by citric acid: Investigation with spectrophotometric and chemiluminescence methods. High Energy Chem 48, 371–375 (2014). https://doi.org/10.1134/S0018143914060083

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  • DOI: https://doi.org/10.1134/S0018143914060083

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