Skip to main content
SpringerLink
Log in

Chemical transformations in sodium chloride aqueous solutions under the action of low-temperature contact glow-discharge plasma

  • Plasma Chemistry
  • Published:
High Energy Chemistry Aims and scope Submit manuscript

Abstract

Changes in the composition of aqueous NaCl solutions during the course of their treatment with glow-discharge plasma in a gas-liquid plasma-chemical reactor have been studied. A mathematical model involving the steps of oxidation of water molecules and chloride ions and the steps of reduction of their chemical conversion products has been developed. For the first time, it has been found that the hydrogen peroxide content of the solution monotonically decreases with the concentration of NaCl and a change in chlorite, chlorate, and perchlorate concentrations has the appearance of an undulating curve with a maximum at c(NaCl) = 3 g/L. The predominant accumulation of hypochlorite ions in the solution has been detected only in the case of the plasma treatment of the NaCl solutions with concentrations higher than 5 g/L.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Zakharov, A.G., Maksimov, A.I., and Titova, Yu.V., Usp. Khim., 2007, vol. 76, no. 3, p. 260.

    Article  Google Scholar 

  2. Pivovarov, A.A. and Tishchenko, A.P., Neravnovesnaya plazma: protsessy aktivatsii vody i vodnykh rastvorov (Nonequilibrium Plasma: Activation of Water and Aqueous Solutions), Dnepropetrovsk: Grek, 2006.

    Google Scholar 

  3. Bugaenko, L.T., Kuzmin, M.G., and Polak, L.S., High Energy Chemistry, New York: Ellis Horwood and Prentice Hall, 1993.

    Google Scholar 

  4. Pivovarov, A.A., Nikolenko, N.V., Zakharov, R.I., Tishchenko, A.P., and Kravchenko, A.V., Vopr. Khim. Khim. Tekhnol., 2012, no. 3, p. 127.

    Google Scholar 

  5. Frumina, N.S., Lisenko, N.F., and Chernova, M.A., Khlor (Chlorine), Moscow: Nauka, 1983.

    Google Scholar 

  6. Williams, W.J., Handbook of Anion Determination, London: Butterworths, 1979.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ukrainian State University of Chemical Technology, pr. Gagarina 8, Dnepropetrovsk, 49005, Ukraine

    N. V. Nikolenko, A. A. Pivovarov, R. I. Zakharov & A. N. Kalashnikova

Authors
  1. N. V. Nikolenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Pivovarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. I. Zakharov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. N. Kalashnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. V. Nikolenko.

Additional information

Original Russian Text © N.V. Nikolenko, A.A. Pivovarov, R.I. Zakharov, A.N. Kalashnikova, 2013, published in Khimiya Vysokikh Energii, 2013, Vol. 47, No. 5, pp. 394–399.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nikolenko, N.V., Pivovarov, A.A., Zakharov, R.I. et al. Chemical transformations in sodium chloride aqueous solutions under the action of low-temperature contact glow-discharge plasma. High Energy Chem 47, 262–267 (2013). https://doi.org/10.1134/S001814391305007X

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S001814391305007X

Keywords

Search

Navigation