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Photochemical modification of polyethylene surface with aryl azides

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Abstract

It has been shown that the formation of a covalently grafted modifying layer takes place during the photolysis of polycrystalline layers of 2-azidoanthraquinone and 4-azidobenzoyl azide on the surface of polyethylene. Its thickness is determined by the amount of the azide applied, and phenyl isocyanate groups formed by the photolysis of 4-azidobenzoyl azide are prone to further functionalization of the modified surface with primary amines.

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Authors and Affiliations

  1. Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia

    A. V. Budruev & D. Yu. Sinjagina

Authors
  1. A. V. Budruev
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  2. D. Yu. Sinjagina
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Correspondence to A. V. Budruev.

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Original Russian Text © A.V. Budruev, D.Yu. Sinjagina, 2013, published in Khimiya Vysokikh Energii, 2013, Vol. 47, No. 5, pp. 365–369.

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Budruev, A.V., Sinjagina, D.Y. Photochemical modification of polyethylene surface with aryl azides. High Energy Chem 47, 237–241 (2013). https://doi.org/10.1134/S0018143913050020

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  • DOI: https://doi.org/10.1134/S0018143913050020

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