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Photochromic processes in solutions of di(mercaptoquinolinato)nickel(II) and perfluoro-2,2′-dinaphthyl disulfide

  • Photochemistry
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Abstract

Reactions of transient species for a new photochromic system composed of perfluoro-2.2′-dinaphthyl disulfide ((SC10F7)2 = (SNF)2) and the planar complex di(mercaptoquinolinato)nickel(II) (Ni(SC9H6)2 = Ni(SR)2) in benzene solutions have been studied. Under UV irradiation, the disulfide dissociates yielding two sulfur-centered radicals (·SC10F7 ≡ ·SNF), which rapidly enter into the coordination sphere of the Ni(II) ion to give the radical complex (·SNF)Ni(SR)2. This species disappears in a second-order reaction yielding the dimer (RS)2Ni(RSSR)Ni(SR)2. The photochromic system returns to the initial state via dissociation of the dimer to the parent disulfide and two Ni(SR)2 molecules.

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Authors and Affiliations

  1. Institute of Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, ul. Institutskaya 3, Novosibirsk, 630090, Russia

    A. V. Kolomeets, V. F. Plyusnin & V. P. Grivin

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  1. A. V. Kolomeets
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  2. V. F. Plyusnin
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  3. V. P. Grivin
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Correspondence to V. F. Plyusnin.

Additional information

Original Russian Text © A.V. Kolomeets, V.F. Plyusnin, V.P. Grivin, 2012, published in Khimiya Vysokikh Energii, 2012, Vol. 46, No. 3, pp. 240–245.

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Kolomeets, A.V., Plyusnin, V.F. & Grivin, V.P. Photochromic processes in solutions of di(mercaptoquinolinato)nickel(II) and perfluoro-2,2′-dinaphthyl disulfide. High Energy Chem 46, 194–199 (2012). https://doi.org/10.1134/S0018143912030034

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