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The specifics of radiation telomerization of tetrafluoroethylene in chlorinated solvents and telomer properties

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Abstract

Radiation telomerization of tetrafluoroethylene in butyl chloride, chloroform, and carbon tetrachloride has been investigated. The chain length of telomers and their solubility and thermal stability depend on the initial monomer concentration and telogen properties. In the case of telomerization in chloroform and carbon tetrachloride, the yield, the chain length, and the thermal stability of the telomers are significantly higher than those in butyl chloride, in which the process is less efficient but soluble telomers having a short chain length and exhibiting quite high thermal resistance are produced. The molecular structure of the telomers has been studied by IR spectroscopy.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    G. A. Kichigina, P. P. Kushch, A. M. Kolesnikova & D. P. Kiryukhin

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  1. G. A. Kichigina
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  2. P. P. Kushch
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  3. A. M. Kolesnikova
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  4. D. P. Kiryukhin
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Correspondence to D. P. Kiryukhin.

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Original Russian Text © G.A. Kichigina, P.P. Kushch, A.M. Kolesnikova, D.P. Kiryukhin, 2011, published in Khimiya Vysokikh Energii, 2011, Vol. 45, No. 5, pp. 431–436.

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Kichigina, G.A., Kushch, P.P., Kolesnikova, A.M. et al. The specifics of radiation telomerization of tetrafluoroethylene in chlorinated solvents and telomer properties. High Energy Chem 45, 397–402 (2011). https://doi.org/10.1134/S0018143911050067

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  • DOI: https://doi.org/10.1134/S0018143911050067

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