Skip to main content
SpringerLink
Log in

The study of polymerization initiated by gamma-irradiated perfluoroacids and their derivatives

  • Radiation Chemistry
  • Published:
High Energy Chemistry Aims and scope Submit manuscript

Abstract

Polymerization of tetrafluoroethylene and methyl methacrylate has been initiated by active sites arising upon γ-radiolysis of perfluorinated organic acids and their derivatives. In the low-temperature radiolysis, two types of active sites are formed. The active sites of the first type (supposedly, -ĊF-COO−), which provide the most efficient polymerization at low temperatures, are accumulated during radiolysis of NaPFNA both at 77 and 300 K. The active sites of the second type, supposedly, of the radical type, are accumulated during radiolysis at 77 K and annealed during heating the sample to room temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Panshin, Yu.A., Malkevich, S.G., and Dunaevskaya, Ts.S., Ftoroplasty (Fluoroplastics), Leningrad: Khimiya, 1978.

    Google Scholar 

  2. Rakhimov, A.I., Khimiya i tekhnologiya ftororganicheskikh soedinenii (Chemistry and Technology of Fluoroorganic Compounds), Moscow: Khimiya, 1986.

    Google Scholar 

  3. Dzhagatspanyan, R.V. and Filippov, M.T., Radiatsionnaya khimiya galogensoderzhashchikh organicheskikh soedinenii (Radiation Chemistry of Halogen-containing Organic Compounds), Moscow: Atomizdat, 1973.

    Google Scholar 

  4. Pshzhetskii, S.Ya., Kotov, A.G., Milinchuk, V.K., Roginskii, V.A., and Tupikov, V.M., EPR svobodnykh radikalov v radiatsionnoi khimii (ESR of Free Radicals in Radiation Chemistry), Moscow: Khimiya, 1972.

    Google Scholar 

  5. Ayscough, P.B., Machov, A.J., and Mach, K., J. Chem. Soc., Faraday II, 1973, vol. 69, p. 750.

    Article  CAS  Google Scholar 

  6. Hori, H., Takano, Y., Koine, K., Kutsuna, S., Einaga, H., and Ibusuki, T., Appl. Catal. B: Environ, 2003, vol. 46, p. 333.

    Article  CAS  Google Scholar 

  7. Hori, H., Hayakawa, E., Koine, K., Einaga, H., and Ibusuki, T., J. Mol. Catal. A: Chem., 2004, vol. 211, p. 35.

    Article  CAS  Google Scholar 

  8. Kalyadin, V.G. and Sirliboev, T.S., Abstract of Papers, IV Vsesoyuznaya konferentsiya po khimii ftororganicheskikh soedinenii., (IV All-Union Conf. on Chemistry of Fluoroorganic Compounds0, Tashkent, 1982, pp. 142.

  9. Barkalov, I.M. and Kiryukhin, D.P., Vysokomol. Soedin., Ser. A, 1980, vol. 22, p. 723.

    CAS  Google Scholar 

  10. Barkalov, I.M., Usp. Khim., 1980, vol. 49, p. 362.

    CAS  Google Scholar 

  11. Kim, I.P., Allayarov, S.R., Barkalov, I.M., and Gol’danskii, V.I., Dokl. Akad. Nauk SSSR, 1988, vol. 300, p. 648.

    CAS  Google Scholar 

  12. Mach, K., Coll. Chechoslov. Chem. Commun., 1972, vol. 37, p. 663.

    CAS  Google Scholar 

  13. Tarutina, L.I. and Pozdnyakova, F.O., Spektral’nyi analiz polimerov (Spectral Analysis of Polymers), Leningrad: Khimiya, 1986.

    Google Scholar 

  14. Allayarov, S.R. and Konovalikhin, S.V., Izv. Akad. Nauk, Ser. Khim., 2000, p. 1038.

  15. Allayarov, S.R., Konovalikhin, S.V., Gordon, D.A., Chernysheva, T.E., and Barkalov, I.M., Khim. Vys. Energ., 2002, vol. 36, p. 445 [High Energy Chem., 2002, vol. 36, p. 405].

    Google Scholar 

  16. Ol’khov, Yu.A., Allayarov, S.R., Chernysheva, T.E., Barkalov, I.M., Kispert, L.D., Tresher, Zh.S., Fernandes, R.E., and Nikels, D.E., Khim. Vys. Energ., 2006, vol. 40, p. 355 [High Energy Chem., 2006, vol. 40, p. 310].

    Google Scholar 

  17. Allayarov, S.R., Konovalikhin, S.V., Olkhov, Yu.A., Jackson, V.E., Kispert, L.D., Dixon, D.A., Ila, D., and Lappan, U., J. Fluorine Chem., 2007, vol. 128, p. 575.

    Article  CAS  Google Scholar 

  18. Shamonina, N.F. and Kotov, A.G., Vysokomol. Soedin., Ser. B, 1974, vol. 16, p. 342.

    CAS  Google Scholar 

  19. Kuzina, S.I., Muidinov, M.R., and Mikhailov, A.I., Zh. Fiz. Khim., 2001, vol. 75, p. 1486.

    CAS  Google Scholar 

  20. Muidinov, M.R., Mashinostroitel’, 1996, p. 23.

  21. Kuzina, S.I., Kim, I.P., Kiryukhin, D.P., Mikhailov, A.I., and Buznik, V.M., Khim. Vys. Energ., 2008, vol. 42, p. 476 [High Energy Chem., 2008, vol. 42, p. 426].

    Google Scholar 

  22. Saika, A., Ohya-Nishiguichi, H., Satokava, T., and Ohmori, A., J. Polym. Sci., 1977, vol. 15, p. 1073.

    CAS  Google Scholar 

  23. Allayarov, S.R., Sumina, I.V., Mikhailov, A.I., and Barkalov, I.M., Izv. Akad. Nauk SSSR, Ser. Khim., 1987, p. 2693.

  24. Allayarov, S.R., Sumina, I.V., Barkalov, I.M., and Mikhailov, A.I., Izv. Akad. Nauk SSSR, Ser. Khim., 1987, p. 2698.

  25. Muromtsev, V.I., Asaturyan, R.A., and Akhvlediani, I.G., Usp. Khim., 1971, vol. 40, p. 312.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    S. R. Allayarov & I. P. Kim

  2. Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    S. V. Konovalikhin

  3. Department of Chemistry, University of Alabama, Tuscaloosa, AL, 35487-0336, USA

    D. A. Dixon

Authors
  1. S. R. Allayarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. P. Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Konovalikhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. A. Dixon
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. R. Allayarov.

Additional information

Original Russian Text © S.R. Allayarov, I.P. Kima, S.V. Konovalikhin, D.A. Dixon, 2011, published in Khimiya Vysokikh Energii, 2011, Vol. 45, No. 1, pp. 32–39.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Allayarov, S.R., Kim, I.P., Konovalikhin, S.V. et al. The study of polymerization initiated by gamma-irradiated perfluoroacids and their derivatives. High Energy Chem 45, 29–36 (2011). https://doi.org/10.1134/S0018143911010024

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0018143911010024

Keywords

Search

Navigation