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Transfer coefficients of cations and anions upon glow discharge-induced nonequilibrium vaporization of solutions of alkaline earth metal salts

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Abstract

Firing of atmospheric-pressure, electrolytic-cathode glow discharge leads to an effect that is similar to well-known cathode sputtering. This process can be called nonequilibrium vaporization of the solution. Unlike quasi-equilibrium vaporization, the nonequilibrium process entails the transfer of nonvolatile components of the solution to the gas phase. Previously, studying glow discharge with calcium and barium chloride solutions as the cathode, we have shown that the transfer of cations and anions via the nonequilibrium vaporization of the nonvolatile solutes is not necessarily stoichiometric [1].

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References

  1. Maksimov, A.I., Naumova, I.K., and Khlyustova, A.V., Khim. Vys. Energ., 2008, vol. 42, no. 6, p. 540 [High Energy Chem., 2008, vol. 42, no. 6, p. 488].

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  2. Alekseev, V.N., Kurs kachestvennogo khimicheskogo polumikroanaliza (Textbook of Qualitative Chemical Semi-Microanalysis), Moscow: Khimiya, 1973.

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Authors and Affiliations

  1. Institute of Chemistry of Solutions, Russian Academy of Sciences, Akademicheskaya ul. 1, Ivanovo, 153045, Russia

    A. V. Khlyustova & A. I. Maksimov

  2. Ivanovo State University for Chemistry and Technology, pr. F. Engel’sa 7, Ivanovo, 153000, Russia

    N. A. Sirotkin

Authors
  1. A. V. Khlyustova
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  2. N. A. Sirotkin
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  3. A. I. Maksimov
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Corresponding author

Correspondence to A. I. Maksimov.

Additional information

Original Russian Text © A.V. Khlyustova, N.A. Sirotkin, A.I. Maksimov, 2010, published in Khimiya Vysokikh Energii, 2010, Vol. 44, No. 1, pp. 77–78.

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Khlyustova, A.V., Sirotkin, N.A. & Maksimov, A.I. Transfer coefficients of cations and anions upon glow discharge-induced nonequilibrium vaporization of solutions of alkaline earth metal salts. High Energy Chem 44, 75–76 (2010). https://doi.org/10.1134/S001814391001011X

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  • DOI: https://doi.org/10.1134/S001814391001011X

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