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Manifestation of the loading effect in polypropylene oxidative plasma degradation processes

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Abstract

Changes in the surface composition of polypropylene films depending on the type of surface subjected to oxygen plasma treatment in a cylindrical reactor were studied by means of Fourier-transform attenuated total reflectance IR spectroscopy. It was found that an increase in the surface area of the film mounted as a cylinder on the reactor wall leads to a decrease in the etching rate and to an inhomogeneous concentration distribution of oxygen-containing functional groups and double bonds over the specimen length. It was shown that the concentrations of newly formed functional groups increase with an increase in the area of the treated surface.

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References

  1. Moreau, W.M., Semiconductor Lithography Principles: Practices and Materials, New York: Plenum, 1988, vol. 2.

    Google Scholar 

  2. Ivanovskii, G.F. and Petrov, V.I., Ionno-plazmennaya obrabotka materialov (Ion Bombardment and Plasma Treatment of Materials), Moscow: Radio i Svyaz’, 1986.

    Google Scholar 

  3. Lamontegne B., Wrobel A.M., Jelbert G., Wertheimer M.P., J. Phys. D: Appl. Phys., 1987, vol. 20, no. 7, p. 844.

    Article  Google Scholar 

  4. Economau, D., Aydit, E.S., and Barno, G., Solid State Technol., 1991, vol. 34, no. 4, p. 107.

    Google Scholar 

  5. Lerner, N.R. and Wydeven, T., J. Electrochem. Soc., 1989, vol. 136, no. 5, p. 1426.

    Article  CAS  Google Scholar 

  6. Entsiklopediya nizkotemperaturnoi plazmy. Vvodnyi tom IV (Encyclopedia of Low-Temperature Plasma: Introductory Volume IV) Fortov, V.E., Ed., Moscow: Nauka, 2000, p. 374.

    Google Scholar 

  7. Maksimov, A.I., Rybkin, V.V., and Kuvaldina, E.V., Khim, Vys. Energ., 1995, vol. 25, no. 1, p. 60 [High Energy Chem., 1995, vol. 25, no. 1, p. 56].

    Google Scholar 

  8. Kuvaldina, E.V., Maksimov, A.I., Rybkin, V.V., and Lyubimov, V.K., Khim. Vys. Energ., 1990, vol. 24, no. 5, p. 422.

    Google Scholar 

  9. Dechant, J., Danz, R., Kimmer, W., and Schmolke, R., Ultrarotspektroskopische Untersuchungen an Polymeren, Berlin: Akademie, 1972.

    Google Scholar 

  10. Kuvaldina, E.V., Rybkin, V.V., Titov, V.A., Shikova, T.G., and Shutov, D.A., Khim. Vys. Energ., 2004, vol. 38, no. 6, p. 461 [High Energy Chem., 2004, vol. 38, no. 6, p. 411].

    Google Scholar 

  11. Rybkin, V.V., Bessarab, A.B., and Maksimov, A.I., Teplofiz. Vys. Temp., 1996, vol. 34, no. 2, p. 181.

    Google Scholar 

  12. Fizicheskie velichiny. Spravochnik (Handbook of Physical Quantities) Grigor’ev, I.S. and Meilikhov, M.Z., Eds., Moscow: Energoatomizdat, 1991.

    Google Scholar 

  13. Vargaftik, N.B., Spravochnik po teplofizicheskim svoistvam gazov i zhidkostei (Handbook on Thermophysical Properties of Gases and Liquids), Moscow: Izd. Fizikomatematicheskoi Literatury, 1963.

    Google Scholar 

  14. Bulan’kov, N.I., Kuvaldina, E.V., Lyubimov, V.K., and Rybkin, V.V., Zh. Prikl. Spectrosk., 1991, vol. 54, no. 3, p. 851.

    CAS  Google Scholar 

  15. Shikova, T.G., Rybkin, V.V., Titov, V.A., and Choi, Kh.S., Khim. Vys. Energ., 2006, vol. 40, no. 5, p. 396 [High Energy Chem., 2006, vol. 40, no. 5, p. 337].

    Google Scholar 

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Authors and Affiliations

  1. Ivanovo State University for Chemistry and Technology, pr. F. Engel’sa 7, Ivanovo, 153000, Russia

    E. V. Kuvaldina & V. V. Rybkin

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  1. E. V. Kuvaldina
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  2. V. V. Rybkin
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Original Russian Text © E.V. Kuvaldina, V.V. Rybkin, 2007, published in Khimiya Vysokikh Energii, 2007, Vol. 41, No. 2, pp. 155–158.

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Kuvaldina, E.V., Rybkin, V.V. Manifestation of the loading effect in polypropylene oxidative plasma degradation processes. High Energy Chem 41, 122–125 (2007). https://doi.org/10.1134/S0018143907020129

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  • DOI: https://doi.org/10.1134/S0018143907020129

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