Abstract
The irradiation of gaseous alkane mixtures under circulation conditions was used for the synthesis of liquid branched hydrocarbons. It was found that the synthesized liquid product was a mixture of alkanes with the average molecular weight higher than the molecular weight of the parent gas by a factor of 3–4. The resulting liquids were characterized by boiling range from 35 to 200°C in atmospheric distillation. The average degree of molecular branching in the synthesized liquids was evaluated on the basis of their knock resistance. The octane ratings of liquid mixtures were above 95 (motor octane number) or 103 (research octane number). The fractional composition and detonation properties of the synthesized liquids suggested the prevalence of C5–C11 isomers with highly branched structures in these liquids. Depending on irradiation conditions, 2,3-dimethylbutane, 2-methylpentane, or 3-methylpentane was predominant among hexanes. As a rule, 2,2,3-trimethylbutane and 2,3-dimethylpentane prevailed among heptanes.
Similar content being viewed by others
References
Leffler, W.L., Petroleum Refining, Tulsa: Penn Well, 1979.
Akhmetov, S.A., Tekhnologiya glubokoi pererabotki nefti i gaza (Technology of Deep Oil and Gas Refining), Ufa: Gilem, 2002.
Ivanov, A.S., Maznev, V.P., Nikonov, O.F., Ovchinnikov, V.P., Svinin, M.P., Makarov, I.E., and Ponomarev, A.V., Proc. 10th Int. Meeting on Application of Charged Particle Accelerators in Industry and Medicine, St. Petersburg, 2001, p. 20.
Bugaenko, L.T., Kuz’min, M.G., and Polak, L.S., High-Energy Chemistry, New York: Ellis Horwood and Prentice Hall, 1993.
Pikaev, A.K., Sovremennaya radiatsionnaya khimiya: radioliz gazov i zhidkostei (Modern Radiation Chemistry: Radiolysis of Gases and Liquids), Moscow: Nauka, 1986.
Radiation Chemistry of Hydrocarbons, Feldiak, G., Ed., Budapest: Akademiai Kiado, 1981.
Ponomarev, A.V., Makarov, I.E., Pikaev, A.K., Saifullin, N.R., and Syrtlanov, A.Sh., Dokl. Akad. Nauk, 2001, vol. 381, no. 2, p. 267.
Ponomarev, A.V., Syrtlanov, A.Sh., and Pikaev, A.K., Dokl. Akad. Nauk, 2000, vol. 372, no. 2, p. 195.
Ponomarev, A.V., Makarov, I.E., Saifullin, N.R., Syrtlanov, A.Sh., and Pikaev, A.K., Radiat. Phys. Chem., 2002, vol. 65, no. 1, p. 71.
Saraeva, V.V., Radioliz uglevodorodov v zhidkoi faze (Radiolysis of Hydrocarbons in the Liquid Phase), Moscow: Mosk. Gos. Univ., 1986.
Spravochnik neftepererabotchika (Petroleum Refinery Engineer Handbook) Lastovkin, G.A., Radchenko, E.D., and Rudin, M.G., Eds., Leningrad: Khimiya, 1986.
Fiziko-khimicheskie svoistva individual’nykh uglevodorodov. Spravochnik (Physicochemical Properties of Individual Hydrocarbons) Tilicheev, M.D., Ed., Moscow: Gostoptekhizdat, 1945.
Cooks, R.G., J. Chem. Phys., 1966, vol. 44, p. 2046.
Lias, S.G., Rebbert, R.E., and Ausloos, P., J. Am. Chem. Soc., 1970, vol. 92, p. 6430.
Matsuoka, S., Tamura, T., Oshima, K., and Oshima, A., Can. J. Chem., 1975, vol. 92, p. 92.
Nonhebel, D. and Walton, J., Free-Radical Chemistry: Structure and Mechanism, Cambridge: Cambridge Univ. Press, 1974.
Baldwin, R.R. and Walker, R.W., J. Chem. Soc., Perkin Trans., 1973, vol. 2, p. 361.
Pancini, E., Santoro, V., and Spadaccini, G., Int. J. Radiat. Phys. Chem., 1970, vol. 2, p. 147.
Praktikum po radiatsionnoi khimii (Laboratory Works on Radiation Chemistry), Moscow: Izd. Mosk. Univ., 1982.
Partridge, R.H., J. Chem. Phys., 1970, vol. 52, p. 2485.
Gavlowski, J., Niedzielski, J., and Herman, J.A., Can. J. Chem., 1977, vol. 55, p. 463.
Author information
Authors and Affiliations
Additional information
Original Russian Text © I.E. Makarov, A.V. Ponomarev, B.G. Ershov, 2007, published in Khimiya Vysokikh Energii, 2007, Vol. 41, No. 2, pp. 83–89.
Rights and permissions
About this article
Cite this article
Makarov, I.E., Ponomarev, A.V. & Ershov, B.G. Radiation-induced synthesis of branched liquid alkanes. High Energy Chem 41, 55–60 (2007). https://doi.org/10.1134/S0018143907020014
Received:
Issue Date:
DOI: https://doi.org/10.1134/S0018143907020014