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Postradiation copolymerization of N-vinylpyrrolidone with triethylene glycol dimethacrylate

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Abstract

The kinetics of low-temperature postradiation copolymerization of N-vinylpyrrolidone (N-VP) with triethylene glycol dimethacrylate (TGM-3) were studied using reactant mixtures with different compositions and different pre-irradiation doses, and the characteristics of the obtained copolymers were determined. The copolymerization process is most effective in glassy systems (at an N-VP concentration in solution below 80 mol %). It was shown that a poly-N-vinylpyrrolidone homopolymer is formed along with a crosslinked N-VP-TGM-3 copolymer.

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References

  1. Zubakova, L.B., Nikiforova, L.Ya., Galitskaya, N.B., Vydra, V.L., Kreinina, S.L., Yamnikov, V.A., Zaikanova, G.I., Burachevskii, I.I., Vorob’eva, E.V., and Lutskaya, B.P., USSR Inventor’s Certificate no. 1634671, Byull. Izobret., 1991, no. 10, p. 80.

  2. Pilina, I.Yu., Akhnazarova, S.L., Zubakova, L.B., and Ileneva, E.V., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1998, vol. 41, no. 3, p. 90.

    CAS  Google Scholar 

  3. Kiryukhin, D.P., Kichigina, G.A., Zubakova, L.B., and Pilina, I.Yu., Zh. Prikl. Khim., 2005, vol. 78, no. 5, p. 814.

    Google Scholar 

  4. Barkalov, I.M. and Kiryukhin, D.P., Int. Rev. Phys. Chem., 1994, vol. 13, no. 2, p. 337.

    Article  CAS  Google Scholar 

  5. Ushakova, V.N., Panarin, E.F., Kiryukhin, D.P., Munikhes, V.M., Lelyukh, A.I., Ul’yanova, N.N., Baranovskaya, I.A., and Klenin, S.I., Vysokomol. Soedin., Ser. A, 1991, vol. 33, no. 10, p. 2151.

    CAS  Google Scholar 

  6. Munikhes, V.M., Berezin, M.P., Kiryukhin, D.P., Barkalov, I.M., and Korolev, G.V., Vysokomol. Soedin., Ser. A, 1986, vol. 28, no. 2, p. 358.

    CAS  Google Scholar 

  7. Bol’shakov, A.I. and Kiryukhin, D.P., Vysokomol. Soedin., Ser. A, 2005, vol. 47, no. 5, p. 909.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    G. A. Kichigina & D. P. Kiryukhin

Authors
  1. G. A. Kichigina
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  2. D. P. Kiryukhin
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Original Russian Text © G.A. Kichigina, D.P. Kiryukhin, 2006, published in Khimiya Vysokikh Energii, 2006, Vol. 40, No. 6, pp. 433–437.

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Kichigina, G.A., Kiryukhin, D.P. Postradiation copolymerization of N-vinylpyrrolidone with triethylene glycol dimethacrylate. High Energy Chem 40, 387–390 (2006). https://doi.org/10.1134/S0018143906060051

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  • DOI: https://doi.org/10.1134/S0018143906060051

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