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Surface properties of plasma-modified polypropylene and propylene-hexene-1 copolymer films

  • Plasma Chemistry
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Abstract

The surface properties of polypropylene and propylene and hexene-1 copolymers synthesized on the rac-Me2SiInd2ZrCl2-polymethylalumoxane isocpecific metallocene system and the Ph2C(Cp)(Flu)ZrCl2-polymethylalumoxane syndiospecific system were studied. It was found that syndiotactic polypropylene films were less hydrophobic than isotactic polypropylene films, whereas the films of propylene and hexene-1 copolymers were less hydrophobic than the films of corresponding homopolymers. The hydrophobicity of samples decreased with the hexene-1 content of the copolymer. Treatment in a dc discharge resulted in noticeable surface hydrophilization in all of the test polymer samples. There is a correlation between the surface parameters and the density of surface charge induced in the polymers by dc discharge treatment.

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Authors and Affiliations

  1. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, ul. Profsoyuznaya 70, Moscow, 117393, Russia

    A. B. Gil’man & A. I. Drachev

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    L. A. Rishina

Authors
  1. A. B. Gil’man
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  2. A. I. Drachev
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  3. L. A. Rishina
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Original Russian Text © A.B. Gil’man, A.I. Drachev, L.A. Rishina, 2006, published in Khimiya Vysokikh Energii, 2006, Vol. 40, No. 4, pp. 317–320.

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Gil’man, A.B., Drachev, A.I. & Rishina, L.A. Surface properties of plasma-modified polypropylene and propylene-hexene-1 copolymer films. High Energy Chem 40, 273–275 (2006). https://doi.org/10.1134/S0018143906040126

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  • DOI: https://doi.org/10.1134/S0018143906040126

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