Abstract
The γ-radiolysis of the α-and β-anomers of D-glucose was studied. The kinetic parameters of mutarotation of irradiated glucoses were determined by polarimetry. The reaction rate constants are independent of the radiation history of samples. The yields of hydrogen from irradiated glucoses were determined by chromatography. The radiation stability of the powdered anomers was the same.
Similar content being viewed by others
References
Kohla, G., Stockfleth, E., and Schauer, R., Neurochem. Res., 2002, vol. 27, nos. 7–8, p. 583.
Dodd, R.B. and Drickamer, K., Glycobiology, 2001, vol. 11, no. 5, p. 71R.
Paulsen, H. and Brockhausen, I., Glycoconj. J., 2001, vol. 18, p. 867.
Shostenko, A.G., Trushkovskii, S., Bukhal’skii, A., Churkin, A.A., and Dobrov, V.I., Khim. Vys. Energ., 2003, vol. 37, no. 4, p. 243 [High Energy Chem., 2003, vol. 37, no. 4, p. 205].
Dizdaroglu, M., Hennenberg, D., Neuwald, K., Schomburg, G., and Sonntag, C., Z. Naturforsch., B: Chem. Sci., 1977, vol. 32, p. 213.
Abagyan, G.V. and Apresyan, A.S., Khim. Vys. Energ., 2002, vol. 36, no. 4, p. 263 [High Energy Chem., 2002, vol. 36, no. 4, p. 229].
Yamabe, S., J. Org. Chem., 1999, vol. 64, no. 12, p. 4519.
Andersen, B. and Gronlund, F., Acta Chem. Scand., 1979, vol. A33, no. 4, p. 275.
O’Connor, C.J., Odell, A.L., and Bailey, A.A.T., Aust. J. Chem., 1982, vol. 35, p. 951.
Ikeda, T. and Senda, U., Bull. Chem. Soc. Jpn., 1973, vol. 46, no. 7, p. 2107.
Sharpatyi, V.A., Khim. Fiz., 1995, vol. 14, no. 10, p. 113.
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.G. Shostenko, S. Truszkowski, A. Bukhal’skii, A.A. Churkin, 2006, published in Khimiya Vysokikh Energii, 2006, Vol. 40, No. 4, pp. 243–245.
Rights and permissions
About this article
Cite this article
Shostenko, A.G., Truszkowski, S., Bukhal’skii, A. et al. Radiolysis of α-D-glucose and β-D-glucose anomers. High Energy Chem 40, 203–205 (2006). https://doi.org/10.1134/S0018143906040011
Received:
Issue Date:
DOI: https://doi.org/10.1134/S0018143906040011