Skip to main content
Log in

Platinum Group Element Geochemistry in the Ocean

  • Published:
Geochemistry International Aims and scope Submit manuscript

Abstract

The paper considers the current state of Platinum Group Elements (PGEs) geochemistry in the ocean. The behavior of PGEs in the aquatic environment is defined by their oxidation state, the ability to change it, and complexation. The difference in chemical properties leads to PGEs fractionation in the ocean. This is their characteristic feature, along with their ultra-low contents. The paper describes the sources of PGEs supply to the ocean, PGEs behavior in the river–sea mixing zone, and their distribution in seawater. The processes of PGE accumulation in sediments, seafloor sulfides, and ferromanganese deposits of the ocean are reviewed. Possible mechanisms of PGE accumulation on ferromanganese oxyhydroxides are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.

REFERENCES

  1. M. Abdou, J. Schäfer, R. Hu, T. Gil-Díaz, C. Garnier, C. Brach-Papa, and G. Blanc, “Platinum in sediments and mussels from the northwestern Mediterranean coast Temporal and spatial aspects,” Chemosphere 215, 783–792 (2019).

    Article  CAS  Google Scholar 

  2. A. D. Anbar, G. J. Wasserburg, D. A. Papanastassiou, and P. S. Andersson, “Iridium in natural waters,” Science 273 (5281), 1524–1528 (1996).

    Article  CAS  Google Scholar 

  3. A. D. Anbar, D. A. Papanastassiou, and G. J. Wasserburg, “Determination of iridium in natural waters by clean chemical extraction and negative thermal ionization mass spectrometry,” Analyt. Chem. 69 (13), 2444–2450 (1997).

    Article  CAS  Google Scholar 

  4. E. Anders and N. Grevesse, “Abundances of the elements: meteoritic and solar,” Geochim. Cosmochim. Acta 5 (1), 197–214 (1989).

    Article  Google Scholar 

  5. N. V. Astakhova, “Noble metals in ferromanganese crusts from marginal seas of the Northwest Pacific,” Oceanology 57, 558–567 (2017).

    Article  CAS  Google Scholar 

  6. V. K. Banakar, J. R. Hein, R. P. Rajani, and A. R. Chodankar, “Platinum group elements and gold in ferromanganese crusts from Afanasiy–Nikitin seamount, equatorial Indian Ocean sources and fractionation,” J. Earth Syst. Sci. 116, 3–13 (2007).

    Article  CAS  Google Scholar 

  7. G. N. Baturin, E. V. Konopleva, V. T. Dubinchuk, and M. E. Melnikov, “Platinum and gold in the ferromanganese crusts of the Pacific Ocean,” Okeanology 45 (2), 269–276 (2005).

    Google Scholar 

  8. G. I. Bekov, V. S. Letokhov, V. N. Radaev, G. N. Baturin, A. S. Egorov, A. N. Kursky, and V. A. Narseyev, “Ruthenium in the ocean,” Nature 312 (5996), 748–750 (1984).

    Article  Google Scholar 

  9. G. B. B. Berbel, M. A. Hortellani, J. E. de Souza Sarkis, V. G. Chiozzini, D. I. T. Fávaro, B. O. Sutti, and E. de Santis Braga, “Emerging contaminants (Rh, Pd, and Pt) in surface sediments from a Brazilian subtropical estuary influenced by anthropogenic activities,” Mar. Pollut. Bull. 163, 111929 (2021).

    Article  CAS  Google Scholar 

  10. E. D. Berezhnaya, A. V. Dubinin, E. N. Zologina, and E. V. Mikhailik, “platinum group element geochemistry in ferromanganese crust of the Detroit Guyot, Pacific Ocean,” Oceanology 61, 94–103 (2021a).

    Article  CAS  Google Scholar 

  11. E. D. Berezhnaya, A. V. Dubinin, and E. V. Mikhailik, “Platinum group elements in ferromanganese crusts of the Atlantic Ocean: forms and sources of matter,” Oceanology 61, 390–403 (2021b).

    Article  CAS  Google Scholar 

  12. K. K. Bertine, M. Koide, and E. D. Goldberg, “Aspects of rhodium marine chemistry,” Mar. Chem. 42, 199–210 (1993).

    Article  CAS  Google Scholar 

  13. Yu. A. Bogdanov, N. S. Bortnikov, I. V. Vikentyev, et al., “Mineralogical–geochemical peculiarities of hydrothermal sulfide ores and fluids in the Rainbow field associated with serpentinites, Mid-Atlantic Ridge (36°14' N),” Geol. Ore Deposits 44 (6), 444–473 (2002).

    Google Scholar 

  14. A. R. Cabral, C. D. Sattler, B. Lehmann, and H. Tsikos, “Geochemistry of some marine Fe–Mn nodules and crusts with respect to Pt contents,” Resour. Geol. 59, 400–406 (2009).

    Article  CAS  Google Scholar 

  15. R. R. Cave, G. E. Ravizza, C. R. German, J. Thomson, and R. W. Nesbitt, “Deposition of osmium and other platinum-group elements beneath the ultramafic-hosted Rainbow hydrothermal plume,” Earth Planet. Sci. Lett. 210, 65–79 (2003).

    Article  CAS  Google Scholar 

  16. C. Chen and M. Sharma, “High precision and high sensitivity measurements of osmium in seawater,” Analyt. Chem. 81 (13), 5400–5406 (2009).

    Article  CAS  Google Scholar 

  17. K. Chen, R. J. Walker, R. L. Rudnick, S. Gao, R. M. Gaschnig, I. S. Puchtel, M. Tang, and Z.-C. Hu, “Platinum–group element abundances and Re–Os isotopic systematics of the upper continental crust through time Evidence from glacial diamictites,” Geochim. Cosmochim. Acta 191, 1–16 (2016).

    Article  CAS  Google Scholar 

  18. A. Cobelo-Garcia, A. Turner, and G. E. Millward, “Fractionation and Reactivity of Platinum Group Elements During Estuarine Mixing,” Environ. Sci. Technol. 42, 1096–1101 (2008).

    Article  CAS  Google Scholar 

  19. A. Cobelo-García, D. E. López-Sánchez, C. Almécija, and J. Santos-Echeandía, “Behavior of platinum during estuarine mixing (Pontevedra Ria, NW Iberian Peninsula),” Mar. Chem. 150, 11–18 (2013).

    Article  Google Scholar 

  20. A. Cobelo-García, D. E. López-Sánchez, J. Schäfer, J. C. Petit, G. Blanc, and A. Turner, “Behavior and fluxes of Pt in the macrotidal Gironde Estuary (SW France),” Mar. Chem. 167, 93–101 (2014).

    Article  Google Scholar 

  21. A. Cobelo-García, M. E. Mulyani, and J. Schäfer, “Ultra-trace interference-free analysis of palladium in natural waters by ICP-MS after on-line matrix separation and pre–concentration,” Talanta 232, 122289 (2021).

    Article  Google Scholar 

  22. D. Colodner, The Marine Geochemistry of Rhenium, Iridium and Platinum (Massachusetts Institute of Technology, 1991).

    Google Scholar 

  23. D. C. Colodner, E. A. Boyle, and J. M. Edmond, “Determination of rhenium and platinum in natural waters and sediments, and iridium in sediments by flow injection isotope dilution inductively coupled plasma mass spectrometry,” Analyt. Chem. 65, 1419–1425 (1993).

    Article  CAS  Google Scholar 

  24. D. C. Colodner, E. A. Boyle, J. M. Edmond, and J. Thomson, “Post–depositional mobility of platinum, iridium and rhenium in marine sediments,” Nature 358, 402–404 (1992).

    Article  CAS  Google Scholar 

  25. C. Colombo, C. J. Oates, A. J. Monhemius, and J. A. Plant, “Complexation of platinum, palladium and rhodium with inorganic ligands in the environment,” Geochem. Explor. Environ. Anal. 8 (1), 91–101 (2008).

    Article  CAS  Google Scholar 

  26. T. Conrad, J. R. Hein, A. Paytan, and D. A. Clague, “Formation of Fe–Mn crusts within a continental margin environment,” Ore Geol. Rev. 87, 25–40 (2017).

    Article  Google Scholar 

  27. T. M. Conway, T. J. Horner, Y. Plancherel, and A. G. González, “A decade of progress in understanding cycles of trace elements and their isotopes in the oceans,” Chem. Geol. 580, 120381 (2021).

    Article  CAS  Google Scholar 

  28. J. M. Cosden and R. H. Byrne, “Comparative geochemistries of PdII and PtII Formation of mixed hydroxychloro and chlorocarbonato-complexes in seawater,” Geochim. Cosmochim. Acta. 67 (7), 1331–1338 (2003).

    Article  CAS  Google Scholar 

  29. J. H. Crocket, “Noble metals in seafloor hydrothermal mineralization from the Juan de Fuca and Mid–Atlantic ridges; a fractionation of gold from platinum metals in hydrothermal fields,” Can. Mineral. 28, 639–648 (1990).

    CAS  Google Scholar 

  30. J. H. Crocket, “PGE in fresh basalt, hydrothermal alteration products, and volcanic incrustations of Kilauea volcano, Hawaii,” Geochim. Cosmochim. Acta 64 (10), 1791–1807 (2000)

    Article  CAS  Google Scholar 

  31. J. H. Crocket, “Platinum-group element geochemistry of mafic and ultramafic rocks. The geology, geochemistry, mineralogy, and mineral beneficiation of platinum-group elements,” CIM Special. 54, 177–210 (2002).

    Google Scholar 

  32. T. K. Dalai and G. Ravizza, “Evaluation of osmium isotopes and iridium as paleoflux tracers in pelagic carbonates,” Geochim. Cosmochim. Acta. 70, 3928–3942 (2006).

    Article  CAS  Google Scholar 

  33. D. H. Dang, D. Omanović, A. Mucci, W. Wang, A. Sikma, and A. Chatzis, “The winter estuarine geochemistry of platinum in the Estuary and Gulf of St. Lawrence,” Mar. Chem. 242,104123 (2022).

    Article  CAS  Google Scholar 

  34. V. M. Dekov, O. Rouxel, B. Guéguen, A. V. Wegorzewski, A. Khripounoff, and L. Menot, “Mn-micronodules from the sediments of the Clarion–Clipperton zone (Pacific Ocean): Origin, elemental source, and Fe–Cu–Zn-isotope composition,” Chem. Geol. 580, 120388 (2021).

    Article  CAS  Google Scholar 

  35. A. C. Dinesh, N. V. Nisha, S. Varghese, R. Pillai, D. Prasad, S. Baraik, R. P. Ramesh, R. K. Joshi, S. I. Meitei, and B. K. Jishnu, “Extensive occurrence of Fe–Mn crusts and nodules on seamounts in the southern Andaman Sea, India,” Curr. Sci. 119, 704 (2020).

    Article  Google Scholar 

  36. J. R. Donat and K. W. Bruland, “Trace metals in the oceans,” Trace Elements in Natural Waters (CRC Press, Boca Raton, 1995), pp. 247–281.

    Google Scholar 

  37. A. V. Dubinin and E. D. Berezhnaya, “Layered distribution of platinum group elements in ferromanganese nodules from the Cape Basin, Atlantic Ocean,” Geochem. Int. 59 (1), 39–55 (2021).

    Article  CAS  Google Scholar 

  38. A. V. Dubinin and Yu. T. Uspenskaya, “Geochemistry and specific features of manganese ore formation in sediments of oceanic bioproductive zones,” Lithol. Miner. Resour. 41 (1), 1–14 (2006).

    Article  CAS  Google Scholar 

  39. A. V. Dubinin, M. N. Rimskaya-Korsakova, E. D. Berezhnaya, T. Y. Uspenskaya, and O. M. Dara, “Ferromanganese crusts in the South Atlantic Ocean compositional evolution and specific features of ore formation,” Geochem. Int. 56 (11), 1093–1108 (2018).

    Article  CAS  Google Scholar 

  40. L. Fischer, G. Smith, S. Hann, and K. W. Bruland, “Ultra-trace analysis of silver and platinum in seawater by ICP-SFMS after off-line matrix separation and pre-concentration,” Mar. Chem. 199, 44–52 (2018).

    Article  CAS  Google Scholar 

  41. A. Gannoun and K. W. Burton, “High precision osmium elemental and isotope measurements of North Atlantic seawater,” J. Analyt. At. Spectrom. 29, 2330–2342 (2014).

    Article  CAS  Google Scholar 

  42. S. Gao, T.-C. Luo, B. -R. Zhang, H.-F. Zhang, Y. Han, Z.‑D. Zhao, and Y.-K. Hu, “Chemical composition of the continental crust as revealed by studies in East China,” Geochim. Cosmochim. Acta 62 (11), 1959–1975 (1998).

    Article  CAS  Google Scholar 

  43. G. P. Glasby, “Incorporation of transition and Platinum Group Elements (PGE) in Co-rich Mn crusts at Afanasiy–Nikitin Seamount (AFS) in the Equatorial S Indian Ocean,” Resour. Geol. 60, 212–215 (2010).

    Article  CAS  Google Scholar 

  44. E. D. Goldberg, V. Hodge, P. Kay, M. Stallard, and M. Koide, “Some comparative marine chemistries of platinum and iridium,” Appl. Geochem. 1 (2), 227–232 (1986).

    Article  CAS  Google Scholar 

  45. O. N. Grebneva-Balyuk and I. V. Kubrakova, “Determination of platinum group elements in geological samples by inductively coupled plasma mass spectrometry: possibilities and limitations,” J. Analyt. Chem. 75 (3), 275–285 (2020).

    Article  CAS  Google Scholar 

  46. Y. Guan, X. Sun, Y. Ren, and X. Jiang, “Mineralogy, geochemistry, and genesis of the polymetallic crusts and nodules from the South China Sea,” Ore Geol. Rev. 89, 206–227 (2017).

    Article  Google Scholar 

  47. P. E. Halbach, A. Jahn, and G. Cherkashov, “Marine Co-rich ferromanganese crust deposits description and formation, occurrences and distribution, estimated world-wide resources,” in Deep–Sea Mining (Springer, 2017), pp. 65–141.

    Google Scholar 

  48. J. R. Hein, B. Mcintyre, and A. Koschinsky, “The global enrichment of platinum group elements in marine ferromanganese crusts, Extend. Abstr. 10, 98–101 (2005).

    Google Scholar 

  49. J. R. Hein, K. Mizell, A. Koschinsky, and T. A. Conrad, “Deep-ocean mineral deposits as a source of critical metals for high-and green-technology applications Comparison with land-based resources,” Ore Geol. Rev. 51, 1–14 (2013).

    Article  Google Scholar 

  50. J. R. Hein, T. Conrad, K. Mizell, V. K. Banakar, F. A. Frey, and W. W. Sager, “Controls on ferromanganese crust composition and reconnaissance resource potential, Ninetyeast Ridge, Indian Ocean,” Deep–Sea Res. Part I 110, 1–19 (2016).

    Article  CAS  Google Scholar 

  51. V. F. Hodge, M. Stallard, M. Koide, and E. D. Goldberg, “Platinum and the platinum anomaly in the marine environment,” Earth Planet. Sci. Lett. 72 (2–3), 158–162 (1985).

    Article  CAS  Google Scholar 

  52. G. S. Jacinto and C. M. G. Van den Berg, “Different behaviour of platinum in the Indian and Pacific oceans,” Nature 338 (6213), 332–334 (1989).

    Article  CAS  Google Scholar 

  53. P. Josso, P. Lusty, S. Chenery, and B. Murton, “Controls on metal enrichment in ferromanganese crusts Temporal changes in oceanic metal flux or phosphatisation,” Geochim. Cosmochim. Acta 308, 60–74 (2021).

    Article  CAS  Google Scholar 

  54. M. Koide, M. Stallard, V. Hodge, and E. D. Goldberg, “Preliminary studies on the marine chemistry of ruthenium,” Netherl. J. Sea Res. 20 (2–3), 163–166 (1986).

    Article  CAS  Google Scholar 

  55. M. Koide, E. D. Goldberg, S. Niemeyer, D. Gerlach, V. Hodge, K. K. Bertine, and A. Padova, “Osmium in marine sediments,” Geochim. Cosmochim. Acta 55 (6), 1641–1648 (1991).

    Article  CAS  Google Scholar 

  56. R. Komendova, “Recent advances in the preconcentration and determination of platinum group metals in environmental and biological samples,” TrAC Trends Anal. Chem. 122, 115708 (2020).

    Article  CAS  Google Scholar 

  57. A. Koschinsky, “The enrichment of platinum and the fractionation of Pt from Pd in marine ferromanganese crusts,” In Extended Abstracts-10th Int. Platinum Symp., pp. 429–432 (2005).

  58. A. Koschinsky, J. R. Hein, D. Kraemer, A. L. Foster, T. Kuh, and P. Halbach, “Platinum enrichment and phase associations in marine ferromanganese crusts and nodules based on a multi–method approach,” Chem. Geol. 539, 119426 (2020).

    Article  CAS  Google Scholar 

  59. I. V. Kubrakova, G. M. Varshal, Yu. F. Pogrebnyak, and T. F. Kudinova, Forms of Platinum and Palladium Migratio in Natural Waters (Nauka, Moscow, 1988) [in Russian].

    Google Scholar 

  60. I. V. Kubrakova, I. Y. Koshcheeva, O. A. Tyutyunnik, and A. M. Asavin, “Role of organic matter in the accumulation of platinum in oceanic ferromanganese deposits,” Geochem. Int. 48 (7), 655–663 (2010).

    Article  Google Scholar 

  61. I. V. Kubrakova, O. A. Tyutyunnik, I. Y. Koshcheeva, A. Y. Sadagov, and S. N. Nabiullina, “Migration behavior of platinum group elements in natural and technogeneous systems,” Geochem. Int. 55 (1), 108–124 (2017).

    Article  CAS  Google Scholar 

  62. C. T. A. Lee, G. J. Wasserburg, and F. T. Kyte, “Platinum-group elements (PGE) and rhenium in marine sediments across the Cretaceous–Tertiary boundary constraints on Re–PGE transport in the marine environment,” Geochim. Cosmochim. Acta 67 (4), 655–670 (2003).

    Article  CAS  Google Scholar 

  63. D. S. Lee, “Palladium and nickel in north-east Pacific waters,” Nature 305 (5929), 47–48 (1983).

    Article  CAS  Google Scholar 

  64. A. Y. Lein, N. V. Ul’yanova, A. M. Sagalevich, Y. A. Bogdanov, E. G. Gurvich, G. A. Cherkashev, T. V. Stepanova, M. P. Torokhov, and A. A. Ul’yanov, “Mineralogy and geochemistry of sulfide ores from the Logachev-2 and Rainbow fields Similar and distinctive features,” Geochem. Int. 41 (3), 271–294 (2003).

    Google Scholar 

  65. S. Levasseur, J. L. Birck, and C. J. Allègre, “Direct measurement of femtomoles of osmium and the 187Os–186Os ratio in seawater,” Science 282 (5387), 272–274 (1998).

    Article  CAS  Google Scholar 

  66. S. Li, Z. Chai, and X. Mao, “Iridium in the Bering Sea and Arctic Ocean studied by neutron activation analysis, J. Radioanal. Nucl. Chem. 271, 125–128 (2007).

    Article  CAS  Google Scholar 

  67. Z. Li, X. Sun, D. Li, Y. Liang, S. Li, and J. Peng, “Platinum enrichment in marine ferromanganese oxides Constraints from surface adsorption behavior on synthetic feroxyhyte (δ-FeOOH),” Chem. Geol. 615, 121204 (2023).

    Article  CAS  Google Scholar 

  68. D. E. López-Sánchez, A. Cobelo-García, M. J. A. Rijkenberg, L. J. A. Gerringa, and H. J. W. de Baar, “New insights on the dissolved platinum behavior in the Atlantic Ocean,” Chem. Geol. 511, 204–211 (2019).

    Article  Google Scholar 

  69. M. Y. Maeno, H. Ohashi, K. Yonezu, A. Miyazaki, Y. Okaue, K. Watanabe, T. Ishida, M. Tokunaga, and T. Yokoyama, “Sorption behavior of the Pt(II) complex anion on manganese dioxide (δ-MnO2) a model reaction to elucidate the mechanism by which Pt is concentrated into a marine ferromanganese crust,” Mineral. Deposita 51, 211–218 (2016).

    Article  CAS  Google Scholar 

  70. E. Marino, F. J. González, L. Somoza, R. Lunar, L. Ortega, J. T. Vázquez, J. Reyes, and E. Bellido, “Strategic and rare elements in Cretaceous–Cenozoic cobalt–rich ferromanganese crusts from seamounts in the Canary Island Seamount Province (northeastern tropical Atlantic),” Ore Geol. Rev. 87, 41–61 (2017).

    Article  Google Scholar 

  71. A. S. Mashio, H. Obata, and T. Gamo, “Dissolved platinum concentrations in coastal seawater Boso to Sanriku areas, Japan,” Arch. Environ. Contam. Toxicol. 73, 240–246 (2017).

    Article  CAS  Google Scholar 

  72. A. S. Mashio, A. Ichimura, H. Yamagishi, K. H. Wong, H. Obata, and H. Hasegawa, “Determination of the sub–picomolar concentration of dissolved palladium in open ocean seawater,” Mar. Chem. 243, 104124 (2022).

    Article  CAS  Google Scholar 

  73. W. F. McDonough and S.-S. Sun, “The composition of the Earth,” Chem. Geol. 120, 223–253 (1995).

    Article  CAS  Google Scholar 

  74. M. A. McKibben, A. E. Williams, and G. E. Hall, “Solubility and transport of plantinum-group elements and Au in saline hydrothermal fluids; constraints from geothermal brine data,” Econ. Geol. 85 (8), 1926–1934 (1990).

    Article  CAS  Google Scholar 

  75. O. B. Mokhodoeva, G. V. Myasoedova, and I. V. Kubrakova, “Sorption preconcentration in combined methods for the determination of noble metals,” J. Analyt. Chem. 62 (7), 607–622 (2007).

    Article  CAS  Google Scholar 

  76. C. E. Monteiro, dos Santos M. Correia, A. Cobelo-García, P. Brito, and M. Caetano, “Platinum and rhodium in Tagus estuary, SW Europe sources and spatial distribution,” Environ. Monitor. Assess. 191, 1–16 (2019).

    Article  Google Scholar 

  77. C. E. Monteiro, A. Cobelo-García, dos Santos M. M. Correia, and M. Caetano, “Drivers of Rh and Pt variability in the water column of a hydrodynamic estuary Effects of contrasting environments,” Sci. Total Environ. 760, 143909 (2021).

    Article  CAS  Google Scholar 

  78. Y. Morishita and A. Usui, “Microanalysis of platinum in hydrogenetic ferromanganese crust using SIMS,” Geochem. J. 49, e21–e26 (2015).

    Article  CAS  Google Scholar 

  79. N. N. Mozgova, Yu. S. Borodaev, and T. V. Stepanova, “Noble metals in sulfide assemblages from deep sectors of the active TAG Mound (Mid-Atlantic Ridge, 26o08′ N),” Lithol. Miner. Resour. 35 (1), 1–18 (2000).

    Article  Google Scholar 

  80. S. B. Muiños, J. R. Hein, M. Frank, J. H. Monteiro, L. Gaspar, T. Conrad, H. G. Pereira, and F. Abrantes, “Deep-sea Fe–Mn crusts from the northeast Atlantic Ocean composition and resource considerations,” Mar. Geores. Geotechnol. 31 (1), 40–70 (2013).

    Article  Google Scholar 

  81. H. Obata, T. Yoshida, and H. Ogawa, “Determination of picomolar levels of platinum in estuarine waters: a comparison of cathodic stripping voltammetry and isotope dilution-inductively coupled plasma mass spectrometry,” Anal. Chim. Acta. 580 (1), 32–38 (2006).

    Article  CAS  Google Scholar 

  82. J. Pađan, S. Marcinek, A.-M. Cindrić, N. Layglon, C. Garnier, P. Salaün, A. Cobelo-García, and D. Omanović, “Determination of sub–picomolar levels of platinum in the pristine Krka River estuary (Croatia) using improved voltammetric methodology,” Environ. Chem. 17, 77–84 (2019).

    Article  Google Scholar 

  83. S. V. Palesskii, I. V. Nikolaeva, O. A. Kozmenko, and G. N. Anoshin, “Determination of platinum-group elements and rhenium in standard geological samples by isotope dilution with mass-spectrometric ending,” J. Analyt. Chem. 64 (3), 272–276 (2009).

    Article  CAS  Google Scholar 

  84. J.-W. Park, Z. Hu, S. Gao, I. H. Campbell, and H. Gong, “Platinum group element abundances in the upper continental crust revisited–New constraints from analyses of Chinese loess,” Geochim. Cosmochim. Acta 93, 63–76 (2012).

    Article  CAS  Google Scholar 

  85. J. Pašava, A. Vymazalová, S. Petersen, and P. Herzig, “PGE distribution in massive sulfides from the PACMANUS hydrothermal field, eastern Manus basin, Papua New Guinea Implications for PGE enrichment in some ancient volcanogenic massive sulfide deposits,” Mineral. Deposita 39, 784–792 (2004).

    Article  Google Scholar 

  86. J. Pašava, A. Vymazalová, and S. Petersen, “PGE fractionation in seafloor hydrothermal systems Examples from mafic- and ultramafic-hosted hydrothermal fields at the slow-spreading Mid–Atlantic Ridge,” Mineral. Deposita 42, 423–431 (2007).

    Article  Google Scholar 

  87. D. G. Pearson and S. J. Woodland, “Solvent extractionanion exchange separation and determination of PGEs (Os, Ir, Pt, Pd, Ru) and Re–Os isotopes in geological samples by isotope dilution ICP-MS,” Chem. Geol. 165 (1–2), 87–107 (2000).

    Article  CAS  Google Scholar 

  88. B. Peucker-Ehrenbrink and B. M. Jahn, “Rhenium-osmium isotope systematics and platinum group element concentrations Loess and the upper continental crust,” Geochem. Geophys. Geosyst. 2 (10), 2001GC000172 (2001).

  89. B. Peucker–Ehrenbrink and G. Ravizza, “The effects of sampling artifacts on cosmic dust flux estimates A reevaluation of nonvolatile tracers (Os, Ir),” Geochim. Cosmochim. Acta. 64, 1965–1970 (2000).

    Article  Google Scholar 

  90. B. Peucker-Ehrenbrink, W. Bach, S. R. Hart, J. S. Blusztajn, and T. Abbruzzese, “Rhenium-osmium isotope systematics and platinum group element concentrations in oceanic crust from DSDPODP Sites 504 and 417/418,” Geochem. Geophys. Geosyst. 4 (7), (2003).

  91. F. Reith, S. G. Campbell, A. S. Ball, A. Pring, and G. Southam, “Platinum in Earth surface environments,” Earth Sci. Rev. 131, 1–21 (2014).

    Article  CAS  Google Scholar 

  92. N. S. Rudashevskii, Yu. L. Kretser, L. I. Anikeeva, S. I. Andreev, M. P. Torokhov, and V. E. Kazakova, “Platinum minerals in oceanic ferromanganese crusts,” Dokl. Earth Sci. 378 (4), 464–467 (2001).

    Google Scholar 

  93. D. P. Savelyev, A. I. Khanchuk, O. L. Saveleva, S. V. Moskaleva, and P. E. Mikhailik, “First find of platinum in cosmogenic spherules of ferromanganese crusts (Fedorov Guyot, Magellan Seamounts, Pacific Ocean),” Dokhl Earth Sci. 491 (2), 199–203 (2020).

    CAS  Google Scholar 

  94. O. L. Savel’eva and D. P. Saveleyv, “Origin of iridium and other PGE anomalies at different stratigraphic levels,” Vestn. KRAUNTs. Ser. Nauki Zemle, No. 4, 73–87 (2016).

    Google Scholar 

  95. G. Schmidt, H. Palme, and Kratz K. L. &, “Highly siderophile elements (Re, Os, Ir, Ru, Rh, Pd, Au) in impact melts from three European impact craters (Sääksjärvi, Mien, and Dellen) clues to the nature of the impacting bodiesm” Geochim. Cosmochim. Acta 61 (14), 2977–2987 (1997).

    Article  CAS  Google Scholar 

  96. I. S. Sen and B. Peucker-Ehrenbrink, “Anthropogenic Disturbance of Element Cycles at the Earth’s Surface,” Environ. Sci. Technol. 46, 8601–8609 (2012).

    Article  CAS  Google Scholar 

  97. M. Sharma, “Applications of osmium and iridium as biogeochemical tracers in the environment, in Handbook of Environmental Isotope Geochemistry Vol. I, Advances in Isotope Geochemistry, Ed. by M. Baskaran (Springer, Berlin–Heidelberg, 2012), pp. 205–227.

  98. M. Sharma, “Platinum group elements and their isotopes in the ocean,” in Encyclopedia of Ocean Sciences, 3rd Edition, Ed. by J. K.Cochran, H. J. Bokuniewicz, and P. L. Yager (Academic Press, Oxford, 2019), pp. 174–180.

    Google Scholar 

  99. M. Sharma, E. J. Rosenberg, and D. A. Butterfield, “Search for the proverbial mantle osmium sources to the oceans: hydrothermal alteration of mid–ocean ridge basalt,” Geochim. Cosmochim. Acta. 71, 4655–4667 (2007).

    Article  CAS  Google Scholar 

  100. N. S. Skornyakova, Local variations of ferromanganese nodule fields,” Ferromanganese Nodules from the central Pacific Ocean (Nauka, Moscow, 1986), pp. 109–185 [in Russian].

    Google Scholar 

  101. T. O. Soyol-Erdene, Y. Huh, S. Hong, and S. D. Hur, “A 50-year record of platinum, iridium, and rhodium in Antarctic snow volcanic and anthropogenic sources,” Environ. Sci. Technol. 45 (14), 5929–5935 (2011).

    Article  CAS  Google Scholar 

  102. T. O. Soyol-Erdene and Y. Huh, “Dissolved platinum in major rivers of East Asia Implications for the oceanic budget,” Geochem. Geophys. Geosyst. 13, 1–13 (2012).

    Article  Google Scholar 

  103. D. Stueben, G. P. Glasby, J. -D. Eckhardt, Z. Berner, B. W. Mountain, and A. Usui, “Enrichments of platinum–group elements in hydrogenous, diagenetic and hydrothermal marine manganese and iron deposits,” Explor. Mining Geol. 8, 233–250 (1999).

    Google Scholar 

  104. A. Suzuki, H. Obata, A. Okubo, and T. Gamo, “Precise determination of dissolved platinum in seawater of the Japan Sea, Sea of Okhotsk and western North Pacific Ocean,” Mar. Chem. 166, 114–121 (2014).

    Article  CAS  Google Scholar 

  105. B. R. Tagirov, N. N. Baranova, A. V. Zotov, N. N. Akinfiev, N. A. Polotnyanko, N. D. Shikina, L. A. Koroleva, Y. V. Shvarov, and E. N. Bastrakov, “The speciation and transport of palladium in hydrothermal fluids experimental modeling and thermodynamic constraints,” Geochim. Cosmochim. Acta. 117, 348–373 (2013).

    Article  CAS  Google Scholar 

  106. B. R. Tagirov, N. N. Baranova, and Y. V. Bychkova, “Thermodynamic properties of platinum chloride complexes in aqueous solutions derivation of consistent parameters from literature data and experiments on Pt (cr) solubility at 400–475°C and 1 kbar,” Geochem. Int. 53 (4), 327–340 (2015).

    Article  CAS  Google Scholar 

  107. S. Terashima, H. Katayama, and S. Itoh, “Geochemical behavior of Pt and Pd in coastal marine sediments, southeastern margin of the Japan Sea,” Appl. Geochem. 8, 265–271 (1993).

    Article  CAS  Google Scholar 

  108. S. Terashima, N. Mita, S. Nakao, and S. Ishihara, “Platinum and palladium abundances in marine sediments and their geochemical behavior in marine environments,” Bull. Geol. Surv. Japan 53, 725–747 (2002).

    Article  CAS  Google Scholar 

  109. M. P. Torokhov and M. E. Melnikov, “Accessory minerals in hydrogenic ferromanganese crusts of the Pacific Ocean: placer accumulation mechanism,” Dokl. Earth Sci. 405 (9), 1288–1290 (2005).

    Google Scholar 

  110. C. B. Tuit, G. E. Bothner, and M. H. Ravizza, “Anthropogenic platinum and palladium in the sediments of Boston Harbor,” Environ. Sci. Technol. 34 (6), 927–932 (2000).

    Article  CAS  Google Scholar 

  111. D. L. VonderHaar, G. M. McMurtry, D. Garbe-Schönberg, D. Stüben, and B. K. Esser, “Platinum and other related element enrichments in Pacific ferromanganese crust deposits, Spec. Publ.-Soc. Sediment. Geol. 66, 287–308 (2000).

    Google Scholar 

  112. K. H. Wedepohl, The composition of the continental crust,” Geochim. Cosmochim. Acta. 59 (7), 1217–1232 (1995).

    Article  CAS  Google Scholar 

  113. S. A. Wood and L. J. Cabri, “The aqueous geochemistry of the platinum-group elements with applications to ore deposits,” The Geology, Geochemistry, Mineralogy and Mineral Beneficiation of Platinum–Group Elements, Ed. by L. J. Cabri, Can, Inst. Mining Metallurg. 54, 211–249 (2002).

  114. Y. Yamashita, Y. Takahashi, H. Haba, S. Enomoto, and H. Shimizu, “Comparison of reductive accumulation of Re and Os in seawater–sediment systems,” Geochim. Cosmochim. Acta 71, 3458–3475 (2007).

    Article  CAS  Google Scholar 

  115. M. A. Yudovskaya, S. Tessalina, V. V. Distler, I. V. Chaplygin, A. V. Chugaev, and Y. P. Dikov, “Behavior of highly-siderophile elements during magma degassing A case study at the Kudryavy volcano,” Chem. Geol. 248 (3–4), 318–341 (2008).

    Article  CAS  Google Scholar 

  116. F. Zereini, L. S. Clare, and C. L.S. Wiseman, Platinum Metals in the Environment (Springer–Verlag, Heidelberg–Berlin, 2015).

    Book  Google Scholar 

  117. S. M. Zhmodik, D. K. Belyanin, A. G. Mironov, V. S. Parkhomenko, A. T. Titov, T. V. Teplyakova, V. G. Tsimbalist, and A. V. Tatarinov, “Role of the biogenic factor in platinum accumulation by oceanic ferromanganese nodules, Dokl. Earth Sci. 427 (5), 777–782 (2009).

    Article  CAS  Google Scholar 

  118. Yu. A. Zolotov, G. V. Varshal, and V. M. Ivanov, Analytical Chemistry of Platinum Group Metals. A Collection of Papers (Editorial URSS, Moscow, 2003) [in Russian].

    Google Scholar 

Download references

ACKNOWLEDGMENTS

We are grateful to I.V. Kubrakova, reviewers, and scientific editor for the attention to the paper and valuable comments.

Funding

This work was made in the framework of the government-financed task (project no. FMWE-2021-0004).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. D. Berezhnaya.

Ethics declarations

The authors of this work declare that they have no conflicts of interest.

Additional information

Translated by M. Bogina

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Berezhnaya, E.D., Dubinin, A.V. Platinum Group Element Geochemistry in the Ocean. Geochem. Int. 62, 327–343 (2024). https://doi.org/10.1134/S0016702923700106

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0016702923700106

Keywords:

Navigation