Abstract
The paper considers the formation of carbon nanoparticles under hydrodynamic cavitation in natural and laboratory conditions. The sizes and structures of particles synthesized from carbon-bearing liquids of different composition are compared. Such carbon nanoforms as nanodiamonds, complex fullerenes, and FCC-carbon have been separated and studied using electron diffraction and Raman spectroscopy. The possibility of doping of synthesized nanodiamonds with small amounts of nitrogen and silicon was studied using photoluminescence spectra. The obtained results can be applied to the processes of mineral formation during the migration of mantle fluids.
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REFERENCES
D. S. Bethune, “The vibrational Raman spectra of purified solid films of C60 and C70,” Chem. Phys. Let. 174, 219–222 (1990).
R. Kh. Bolotnova, “Extension of the equation of state of benzene,” Tr. Inst. Mekhaniki (UNTs RAN, Ufa, 2007), pp. 113–120 (2007).
A. Yu. Dnestrovskii, S. A. Voropaev, and E. A. Ponomareva, “Modeling of diamond formation conditions during cavitation in benzene,” Dokl. Physics 56 (2), 78–81 (2011).
A. Yu. Dnestrovskii, S. A. Voropaev and E. A. Zabrodina, “Modeling of cavitation-bubble compression in benzene,” Dokl. Physics 61 (8), 389–393 (2016).
A. Yu. Dnestrovskij, N. V. Dushenko, and S. A. Voropaev, “Two-phase flow in setup for obtaining cavitation diamonds,” Inzh.-Fiz. Zh. 91 (6), 32–37 (2018).
A. Yu. Dnestrovskij, S. A. Voropaev, N. V. Dushenko, S. G. Naimushin and E. M. Galimov, “Conditions of the formation of a shock wave under cavitation in hydrocarbon solutions,” Dokl. Physics 65 (1), 8–11 (2020).
N. V. Dushenko, S. A. Voropaev, E. A. Ponomareva, A. Yu. Dnestrovskii, V. M. Shkinev, A. S. Aronin, and E. M. Galimov, “Cavitation synthesis of carbon nanoforms by hydroshock,” Izv. Vyssh. Ucheb. Zaved. Seriya Khim. Khim. Tekhnol. 59 (9), 80–85 (2016).
D. V. Fedoseev, E. M. Galimov, V. P. Varnin, V. S. Prokhorov, and B. V. Deryagin, “Carbon isotope fractionation during physicochemical synthesis of diamond from gas,” Dokl. Akad. Nauk SSSR 201 (5), 1149–1158 (1971).
E. M. Galimov, “Possibility of natural diamond synthesis under conditions of cavitation, occurring in a fast–moving magnetic melt,” Nature 243, 389–391 (1973).
E. M. Galimov, “Cavitation as mechanism of synthesis of natural diamonds,” Izv. Akad. Nauk SSSR. Ser. Geol., 1, 22–37 (1974).
E. M. Galimov, “Isotope fractionation related to kimberlite magmatism and diamond formation,” Geochim. Cosmochim. Acta. 55, 1697–1708 (2001).
E. M. Galimov, “Some evidence for plausibility of cavitation synthesis of diamond in nature,” Geokhimiya, No. 4, 456–471 (1985).
E. M. Galimov, “Variations of diamond isotope composition and their relation with conditions of diamond formation,” Geokhimiya, No. 8, 1091–1118 (1984).
E. M. Galimov, V. S. Prokhorov, D. V. Fedoseev, and V. P. Varnin, “Heterogeneous isotope effects on carbon during diamond and graphite synthesis from gas,” Geokhimiya, No. 3, 416–425 (1973).
E. M. Galimov, A. M. Kudin, V. N. Skorobogatski, V. G. Plotnichenko, O. L. Bondarev, B. G. Zarubin, V. V. Strazdovski, A. S. Aronin, A. V. Fisenko, I. V. Bykov, and A. Yu. Barinov, “Experimental Corroboration of the Synthesis of Diamond in the Cavitation Process,” Dokl. Physics 49 (3), 150–153 (2004).
H. Hirai and K. Kondo, “A new crystalline form of carbon under shock compression,” Proc. Japan Acad. 67 (Ser. B), 22–26 (1991).
F. Jelezko, “Single defect centres in diamond,” Phys. Stat. Solid. A. 203, 3207 (2006).
O. A. Lukanin, T. I. Tsekhonya, V. V. Koltashev and N. N. Kononkova “Influence of C–O–H volatiles on Ni, Co, and P partition between silicate melt and liquid metal Fe alloy at 4 GPa, 1550°C, ” Geochem. Int. 58 (6), 670–686 (2020).
R. I. Nigmatulin, A. A. Aganin, D. Yu. Toporkov, and M. A. Il’gamov, “Formation of convergent shock waves in a bubble upon its collapse,” Dokl. Physics 59 (9), 431–436 (2014).
S. A. Voropaev, A. Yu. Dnestrovskii, V. N. Skorobogatskii, A. S. Aronin, V. M. Shkinev, O. L. Bondarev, V. V. Strazdovskii, A. A. Eliseev, E. A. Zevakin, E. A. Ponomareva, and E. M. Galimov, “Face-centered cubic carbon synthesis under cavitation compression,” 56 (9), 463–466 (2011).
S. A. Voropaev, V. M. Shkinev, A. Yu. Dnestrovskii, E. A. Ponomareva, A. S. Aronin, O. L. Bondarev, V. V. Strazdovskii, V. N. Skorobogatskii, A. A. Eliseev, B. Ya. Spivakov, and E. M. Galimov, “Synthesis of diamondlike nanoparticles under cavitation in toluene,” Dokl. Physics 446 (4–6), 373–377 (2012).
S. A. Voropaev, A. Yu. Dnestrovskii, V. N. Skorobogatskii, A. S. Aronin, V. M. Shkinev,O. L. Bondarev, V. V. Strazdovskii, A. A. Eliseev, E. A. Ponomareva, N. V. Dushenko, and E. M. Galimov, Experimental study into the formation of nanodiamonds and fullerenes during cavitation in an ethanol–aniline mixture,” Dokl. Physics 59 (11), 503–506 (2014).
S. A. Voropaev, N. V. Dushenko, V. N. Skorobogatskii, A. S. Aronin, V. M. Shkinev, O. L. Bondarev, V. V. Strazdovskii, A. A. Eliseev, E. A. Ponomareva, and E. M. Galimov, “Photoluminescence of nitrogen-doped nanodiamonds of cavitation synthesis,” Dokl. Phys. 59 (12), 564–567 (2014).
S. A. Voropaev, N. V. Dushenko, A. S. Aronin, V. M. Shkinev, and E. M. Galimov, “Study of possibility of nitrogen and silica doping of cavitaion nanodiamonds,” Fiz-khim aspekty izucheniya klasterov, nanostruktur, i nanomaterialov 7, 158–164 (2015).
V. N. Zharkov, Physics of Earth’s Interior (Nauka i Obrazovanie, Moscow, 2012) [in Russian].
N. E. Zhukovskii, On Hydraulic Impact in the Water-Supply Pipe (MSU, Moscow, 1898) [in Russian].
ACKNOWLEDGMENTS
We are grateful to the Corresponding Member of the RAS, F.N. Kaminsky for the careful reviewing of the manuscript and critical comments, which significantly improved the formulation of our results.
Funding
This work was supported by the Russian Foundation for Basic Research (project no. 19-05-00554).
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Translated by M Bogina
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Voropaev, S.A., Dushenko, N.V., Dnestrovskiy, A.Y. et al. Hydrodynamic Cavitation as a Natural Mechanism for Diamond Nucleation. Geochem. Int. 59, 1052–1062 (2021). https://doi.org/10.1134/S0016702921110112
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DOI: https://doi.org/10.1134/S0016702921110112