Skip to main content
Log in

The Role of Garnetization of Olivine in the Olivine–Diopside–Jadeite System in the Ultramafic–Mafic Evolution of Upper-Mantle Magmatism (Experiment at 6 GPa)

  • Published:
Geochemistry International Aims and scope Submit manuscript

Abstract

The peritectic mechanisms controlling the ultramafic–mafic evolution of magmatism during fractional crystallization and the genesis of peridotite–pyroxenite–eclogite rock series of the garnet–peridotite facies of the upper mantle were substantiated experimentally. The melting phase relations of differentiated mantle material in the olivine–clinopyroxene/omphacite–corundum–coesite multicomponent system were studied by the polythermal sections method; their boundary phases reproduced the compositions of peridotitic and eclogitic minerals. The peritectic reaction between orthopyroxene and melt with the formation of clinopyroxene proceeds at the liquidus of the olivine–orthopyroxene–clinopyroxene–garnet system as the mechanism for “clinopyroxenization of orthopyroxene,” which yields the regressive olivine + clinopyroxene + garnet + melt monovariant cotectic reaction. The further evolution of magmatism was studied experimentally at 6 GPa in the ultramafic–mafic olivine–diopside–jadeite–garnet system with a variable composition of the diopside–jadeite solid solutions (clinopyroxene ↔ omphacite). The peritectic reaction between olivine and melt with the formation of garnet was detected on the liquidus of the triple system olivine–diopside–jadeite as the of olivine garnetization mechanism yielding the omphacite + garnet + melt cotectic reaction with the formation of bimineral eclogite. The structure of the liquidus of the olivine–diopside–jadeite–garnet system was defined, as well as its critical role as the “physicochemical bridge” between the ultramafic olivine-bearing peridotite–pyroxenite composition and mafic silica-saturated eclogitic composition of matter within the garnet–peridotite facies. The experimental physicochemical results illustrate the genetic links between ultramafic and mafic rocks and the mechanisms of continuous fractional magmatic evolution and petrogenesis from olivine-bearing peridotite–pyroxenite rocks to silica-saturated eclogite–grospydite rocks. This explains the complete petrochemical trends for the rock-forming components in clinopyroxenes and garnets from differentiated rocks of the garnet–peridotite facies.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.
Fig. 10.

Similar content being viewed by others

REFERENCES

  1. P. M. Bell and B. T. C. Davis, “Melting relations in the system jadeite–diopside at 30 and 40 kb,” Am. J. Sci. A-267, 17–32 (1969).

    Google Scholar 

  2. A. V. Bobrov, A. M. Dymshits, and Litvin, Yu. A. “Conditions of magmatic crystallization of Na-bearing majoritic garnets in the Earth mantle: evidence from experimental and natural data,” Geochem. Int. 47(10), 951–965 (2009).

    Article  Google Scholar 

  3. F. R. Boyd and R. V. Danchin, “Lherzolites, eclogites, and megacrysts from some kimberlites of Angola,” Am. J. Sci. 280 (2), 528–549 (1980).

    Google Scholar 

  4. V. Butvina and Yu. Litvin, “Phase relations in the forsterite–diopside–jadeite system,” Geophys. Res. Abstr. 11, EGU2009-3328 (2009).

    Google Scholar 

  5. B. T. C. Davis, “The system enstatite-diopside at 30 kilobars pressure,” Carnegie Institution Washington Yearbook 62, 103–107 (1963).

    Google Scholar 

  6. B. T. C. Davis, “The system diopside–forsterite–pyrope at 40 kilobars,” Carnegie Inst. Washington Yearbook 63, 165–171 (1964).

    Google Scholar 

  7. B. T. C. Davis and J. F. Schairer, “Melting relations in the diopside-forsterite-pyrope at 40 kilobars and one atmosphere,” Carnegie Inst. Washington Yearbook 64, 123–126 (1965).

    Google Scholar 

  8. J. B. Dawson, Kimberlites and Their Xenoliths (Springer-Verlag, 1980).

    Book  Google Scholar 

  9. A. M. Dymshits, A. V. Bobrov, and Yu. A. Litvin, “Phase relations in the system (Mg,Ca)3Al2Si3O12–Na2MgSi5O12 at 7.0 and 8.5 GPa and 1400–1900oC,” Geochem. Int. 53 (1), 9–18 (2015).

    Article  Google Scholar 

  10. T. Gasparik and Yu. A. Litvin, “Stability of Na2Mg2Si2O7 and melting relations on the forsterite–jadeite join at pressures up to 22 GPa,” Eur. J. Mineral., no. 9, 311–326 (1997).

  11. V. Yu. Litvin, T. Gasparik, and Yu. A. Litvin, “The system enstatite–nepheline in experiments at 6.5–13.5 GPa: the importance of Na2Mg2Si2O7 for the melting of nefeline-normative mantle,” Geochem. Int. 38 (Suppl. 1), S100–S107 (2000).

    Google Scholar 

  12. Yu. A. Litvin, Physicochemical Study of Melting Deep-Seated Material, (Nauka, Moscow, 1991). [in Russian].

    Google Scholar 

  13. Yu. A. Litvin, Genesis of Diamond and Associated Phases (Springer, 2017).

    Book  Google Scholar 

  14. Yu. A. Litvin, A. V. Spivak, and A. V. Kuzyura, “Fundamentals of mantle carbonatite concept of diamond genesis,” Geochem. Int. 54 (10), 839–857 (2016).

    Article  Google Scholar 

  15. S. Maaloe, Principles of Igneous Petrology (Springer, 1985).

    Book  Google Scholar 

  16. I. D. MacGregor and J. L. Carter, “The chemistry of clinopyroxenes and garnets of eclogite and peridotite xenoliths from Roberts Victor Mine, South Africa,” Phys. Earth Planet. Inter., No. 3, 391–397 (1970).

    Article  Google Scholar 

  17. B. I. Malyuk and A. A. Sivoronov, “On the problem of systematics of komatiites,” Geol. Geofiz., no. 1, 62–69 (1984).

  18. A. A. Marakushev, “Nodules of peridotites in the kimberlites as indicators of the deep-seated structure of lithosphere,” Reports of Russian Geologists on the 27th Session of the International Geological Congress. Petrology (Nauka, Moscow, 1985), Vol. 13, pp. 5–13.

  19. M. Mathias, I. C. Siebert, and P. C. Rickwood, “Some aspects of the mineralogy and petrology in ultramafic xenoliths in kimberlite,” Contrib. Mineral. Petrol. 26, 75–123 (1970).

    Article  Google Scholar 

  20. H. O. A. Meyer and F. R. Boyd, “Composition and origin of crystalline inclusions in natural diamonds,” Geochim. Cosmochim. Acta 36, 1255–1274 (1972).

    Article  Google Scholar 

  21. M. J. O’Hara and H. S. Yoder, “Partial melting of the mantle,” Carnegie Inst. Washington Yearbook 62, 67–71 (1963).

    Google Scholar 

  22. M. J. O’Hara and H. S. Yoder, “Formation and fractionation of basic magmas at high pressures,” Scott. J. Geol., no. 3, 67–117 (1967).

    Article  Google Scholar 

  23. M. J. O’Hara, “The bearing of phase equilibria studies in synthetic and natural systems on the origin and evolution of basic and ultrabasic rocks,” Earth Sci. Rev., no. 4, 69–133 (1968).

    Article  Google Scholar 

  24. L. S. Palatkik and A. I. Landau, Phase Equilibria in the Multicomponent Systems (KhGU. Khar’kiv, 1961) [in Russian].

  25. M. Prinz, D. V. Manson, P. F. Hlava, and K. Keil, “Inclusions in diamonds: garnet lherzolite and eclogite assemblages,” Phys. Chem. Earth 9, 797–815 (1975).

    Article  Google Scholar 

  26. F. N. Rhines, Phase Diagrams in Metallurgy: Their Development and Application (McGraw-Hill Book Company, New York–Toronto–London, 1956).

    Google Scholar 

  27. A. E. Ringwood, Composition and Petrology of the Earth’s Mantle (McGraw-Hill Book Company, New York–Toronto, 1975).

    Google Scholar 

  28. N. V. Sobolev, Deep-Seated Inclusions in Kimberlites and the Problem of Mantle Composition (Nauka, Navosibirsk, 1974) [in Russian].

  29. S. V. Sobolev and N. V. Sobolev, “Xenoloiths in kimberlites of South Yakutia and problems of mantle structure,” Dokl. Akad. Nauk SSSR 158 (1), 143–145.

  30. W. Wang, “Formation of diamond with mineral inclusions of mixed eclogite and peridotite paragenesis,” Earth Planet. Sci. Lett. 160, 831–843 (1998).

    Article  Google Scholar 

  31. K. E. Windom and A. L. Boettcher, “Phase relations for the join jadeite-enstatite and jadeite-forsterite at 28 kb and their role in basalt genesis,” Am. J. Sci. 281, 335–331 (1981).

    Article  Google Scholar 

  32. H. J. Yoder, Generation of Basaltic Magma (Nat. Acad. Sci., Washington, 1976)

    Google Scholar 

  33. H. J. Yoder and C. E. Tilley, “Origin of basalt magmas: an experimental study of natural and synthetic rock systems,” J. Petrol. 3 (3), 342–532 (1962).

    Article  Google Scholar 

  34. A. M. Zakharov, Phase Diagrams of Quaternary Systems (Metallurgiya, Moscow, 1964) [in Russian].

    Google Scholar 

  35. V. A. Zharikov and Yu. A. Litvin, “Phase equilibria of multicomponent mineral systems at high pressures and high temperatures,” High Pressure Res., No. 1, 387–393 (1989).

    Article  Google Scholar 

Download references

Funding

This study was supported by the Presidium of the Russian Academy of Sciences, program no. I.08.P.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yu. A. Litvin.

Additional information

Translated by A. Bobrov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Litvin, Y.A., Kuzyura, A.V. & Limanov, E.V. The Role of Garnetization of Olivine in the Olivine–Diopside–Jadeite System in the Ultramafic–Mafic Evolution of Upper-Mantle Magmatism (Experiment at 6 GPa). Geochem. Int. 57, 1045–1065 (2019). https://doi.org/10.1134/S0016702919100070

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0016702919100070

Keywords:

Navigation