Abstract—
The paper presents pioneering data on the isotopic composition and elemental ratios of nitrogen, carbon (carbon dioxide), helium, and argon in the fluid phase of quenched tholeiitic glasses from different segments of the Bouvet Triple Junction area (BTJ). The data reflect a complicated geodynamic and tectonic history of the area evolution and indicate that the variations in the elemental ratios of the volatile components of the fluid–gas phase were controlled by a number of various factors: elemental fractionation during melt degassing, mixing of gases from different sources, postmagmatic diffusion-controlled helium loss. The nitrogen–argon and noble gas isotope systematics suggest a significant contribution of the atmospheric component to the mantle source of fluids for the samples from the Spiess Ridge and the segment of the Southwest Indian Ridge (SWIR) and a smaller contribution for the Mid-Atlantic Ridge (MAR) samples. For the Spiess Ridge and SWIR, the most probable contaminating agent was water fluid with dissolved gases of atmospheric composition. This fluid may have been brought to the mantle with ancient crustal rocks involved in magma generation. These crustal rocks may represent small fragments of the Gondwana continent with which sedimentary organic matter could be brought into the magma source.
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REFERENCES
C. J. Ballentine and D. Barfod, “The origin of air-like noble gases in MORB and OIB,” Earth Planet. Sci. Lett. 180, 39–48 (2000).
Z. C. Ben-Avraham, J. H. Hartnady, and J. A. Malan, “Early tectonic extension between the Agulhas Bank and the Falkland Plateau due to the rotation of the Lafonia microplate,” Earth Planet. Sci. Lett. 117, 43–58 (1993).
A. I. Buikin, M. Trieloff, E. V. Korochantseva, J. Hopp, M. Kaliwoda, H.-P. Meyer, and R. Altherr, “Distribution of mantle and atmospheric argon in mantle xenoliths from the Western Arabian Peninsula: constraints on timing and composition of metasomatizing agents in the lithospheric mantle,” J. Petrol. 51, 2547–2570 (2010).
A. I. Buikin, A. B. Verchovsky, V. A. Grinenko, S. A. Silantyev, V. S. Sevast’yanov, Yu. A. Nevinnyi, and E. P. Smirnova, “C, N, He, and Ar isotope and element ratios in fluid inclusions from MORB chilled glasses: stepwise crushing data,” Geochem. Int. 51 (4), 338–343 (2013).
A. I. Buikin, I. P. Solovova, A. B. Verchovsky, L. N. Kogarko, and A. A. Averin, “PVT parameters of fluid inclusions and the C, O, N, and Ar isotopic composition in a garnet lherzolite xenolith from the Oasis Jetty, East Antarctica,” Geochem. Int. 52 (10) 805–821 (2014).
A. I. Buikin, N. A. Migdisova, J. Hopp, E. V. Korochantseva, and M. Trieloff, “He, Ne, Ar stepwise crushing data on basalt glasses from different segments of Bouvet Triple Junction,” Geochem. Int. 55 (11), 977–987 (2017).
P. G. Burnard, D. Graham, and G. Turner, “Vesicle-specific noble gas analyses of „popping rock“: Implications for primordial noble gases in Earth,” Science 276, 568–571 (1997).
P. Cartigny, N. Jendrzejewski, F. Pineau, E. Petit, and M. Javoy, “Volatile (C, N, Ar) variability in MORB and the respective roles of mantle source heterogeneity and degassing: the case of the Southwest Indian Ridge,” Earth Planet. Sci. Lett. 194, 241–257 (2001).
J. S. Dickey, E. A. Frey, S. R. Hart, E. B. Watson, and G. Thompson, “Geochemistry and petrology of dredged basalts from the Bouvet triple junction, South Atlantic,” Geochim. Cosmochim. Acta 41, 1105–1118 (1977).
E. P. Dubinin, N. M. Sushchevskaya, and A. L. Grokholskii, “The evolution of spreading ridges of the South Atlantic and spatiotemporal position of the Bouvet Triple Junction,” Russ. J. Earth Sci. 1 (5), 423–435 (1999).
T. P. Fisher, P. Burnard, B. Marty, D. R. Hilton, E. F?ri, F. Palhol, Z. D. Sharp, and F. Mangasini, “Upper-mantle volatile chemistry at Oldoinyo Lengai volcano and the origin of carbonatites,” Nature 459, 77–80 (2009).
A. Jambon, H. Weber, and O. Braun, “Solubilities of He, Ne, Ar, Kr and Xe in a basalt melt in the range 1250–1600°C: geochemical implications,” Geochim. Cosmochim. Acta 50, 401–408 (1986).
M. C. Kleinrock and J. Ph. Morgan, “Triple junction reorganization,” J. Geophys. Res. 93, 2981–2996 (1988).
R. Sh. Krymsky, N. M. Sushchevskaya, B. V. Belyatsky, and N. A. Migdisova, “Peculiarities of the osmium isotopic composition of basaltic glass from the western termination of the Southwest Indian Ridge,” Dokl. Earth Sci. 428 (7) 1126–1130 (2009).
M. D. Kurz, A. P. le Roex, and H. J. B. Dick, “Isotope heterogeneity near the Bouvet triple junction,” Geochim. Cosmochim. Acta. 62, 841–852 (1998).
L. A. Lawver, J. G. Sclater, and L. Meinke, ”Mesozoic and Cenozoic reconstructions of the South Atlantic,” Tectonophysics 114, 233–254 (1985).
A. P. Le Roex, H. J. B. Dick, A. M. Reid, F. A. Frey, and S. R. Hart, “Geochemistry, mineralogy and petrogenesis of lavas erupted along the Southwest Indian Ridge between the Bouvet Triple Junction and 11 degrees East,” J. Petrol. 24 (3) 267–318 (1983).
A. P. Le Roex, H. J. B. Dick, A. M. Reid, and A. J. Erlank, “Ferrobasalts from the Spiess Ridge segment of the southwest Indian Ridge,” Earth Planet. Sci. Lett. 60, 437–451 (1982).
A. P. Le Roex, H. J. B. Dick, A. M. Reid, F. A. Frey, and A. J. Erlank, “Petrology and geochemistry of basalts from the American-Antarctic Ridge, Southern Ocean: implications for the westward influence of the Bouvet mantle plume,” Contrib. Mineral. Petrol. 90, 367–380 (1985).
A. P. Le Roex, H. J. B. Dick, and R. T. Watkins, “Petrogenesis of anomalous K-enriched MORB from the Southwest Indian Ridge: 11°53′ E to 14°38′ E,” Contrib. Mineral. Petrol. 110, 253–268 (1992).
M. Ligi, E. Bonatti, G. Bortoluzzi, G. Carrara, P. Fabretti, D. Penitenti, D. Gilod, A. Peyve, S. Skolotnev, and N. Turko, “Death and transfiguration of a triple junction in the South Atlantic,” Science 276, 243–245 (1997).
M. Ligi, E. Bonatti, G. Bortoluzzi, G. Carrara, and Pl. Fabretti, “Bouvet triple junction in the South Atlantic: geology and evolution,” J. Geophys. Res. 104 (12), 29365–29385 (1999).
D. P. Mattey, R. A. Exley, and C. T. Pillinger, “Isotopic composition of CO2 and dissolved carbon species in basalt glass,” Geochim. Cosmochim. Acta 53, 2377–2386 (1989).
N. A. Migdisova, N. M. Sushchevskaya, A. V. Lattenen, and E. M. Mikhalsky, Variations in the composition of clinopyroxene from the basalts of various geodynamic settings of the Antarctic Region,” Petrology 12 (2), 206–224 (2004).
N. A. Migdisova, A. V. Sobolev, N. M. Sushchevskaya, E. P. Dubinin, and D.V. Kuzmin, Mantle heterogeneity at the Bouvet triple junction based on the composition of olivine phenocrysts,” Russ. Geol. Geophys. 58 (11) 1289–1304 (2017).
Y. Nishio, T. Ishii, T. Gamo, and Y. Sano, Volatile element isotopic systematic of the Rodrigues Triple Junction Indian Ocean MORB: implications for mantle heterogeneity,” Earth Planet. Sci. Lett. 170, 241–253 (1999).
A. A. Peyve, A. S. Perfil’ev, Yu. M. Pushcharovskii, V. A. Simonov, N. N. Turko, and Yu. N. Raznitsin, “The Structure of the southern end of Mid-Atlantic Ridge (the Bouvet Triple Junction),” Geotektonika 1, 40–57 (1995).
F. Pineau and M. Javoy, “Carbon isotopes and concentrations in mid-oceanic ridge basalts,” Earth Planet. Sci. Lett. 62, 239–257 (1983).
F. Pineau, M. Javoy, and Y. Bottinga, “13C/12C ratios of rocks and inclusions in the popping rocks of the Mid-Atlantic ridge and their bearing on the problems of isotopic composition of deep seated carbon,” Earth Planet. Sci. Lett. 29, 413–421 (1976).
J. G. Shilling, G. Thompson, R. Kinzley, and S. E. Humphris, “Hotspot-migrating ridge interaction in South Atlantic: geochemical evidence,” Nature 313, 187–191 (1985).
V. A. Simonov, A. A. Peyve, V. Yu. Kolobov, A. A. Milosnov, and S. V. Kovyazin, “Magmatic and hydrothermal processes in the Bouvet triple junction region (South Atlantic),” Terra Nova. 8, 45–424 (1996).
N. M. Sushchevskaya, E. V. Koptev-Dvornikov, N. A. Migdisova, and D. M. Khvorov, “Crystallization and geochemistry of tholeiitic magma at the Bouvet Triple Junction, Southwest Indian Ridge,” Russ. J. Earth Sci. 1 (3), 221–250 (1999).
N. M. Sushchevskaya, N. A. Migdisova, B. V. Belyatsky, and Peyve, A. A. “Genesis of enriched tholeiitic magmas in the western segment of the Southwest Indian Ridge, South Atlantic Ocean,” Geochem. Int. 41(1) 1–20 (2003).
M. Trieloff, J. Kunz, D. A. Clague, D. Harrison, and C. J. Allegre, “The nature of pristine noble gases in mantle plumes,” Science 288, 1036–1038 (2000).
A. B. Verchovsky, M. A. Sephton, I. P. Wright, and C. T. Pillinger, “Separation of planetary noble gas carrier from bulk carbon in enstatite chondrites during stepped combustion,” Earth Planet. Sci. Lett. 199, 243–255 (2002).
A. B. Verkhovskiy, E. K. Yurgina, Yu. A. Shukolyukov, “He and Ar in Midocean ridge basalt glasses and the outgassing of mantle magmas,” Geochem. Int. 28(9) 18–28 (1991).
ACKNOWLEDGMENTS
The authors thank the reviewer K.I. Lokhov for constructive criticism and useful suggestions, which allowed us to improve the manuscript. This study was supported by the Russian Foundation for Basic Research, project no. 16-05-00974.
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Buikin, A.I., Verchovsky, A.B. & Migdisova, N.A. N–C–Ar–He Isotopic Systematics of Quenched Tholeiitic Glasses from the Bouvet Triple Junction Area. Geochem. Int. 56, 1368–1383 (2018). https://doi.org/10.1134/S0016702918130037
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DOI: https://doi.org/10.1134/S0016702918130037