References
I.Ya. Nekrasov. Geochemistry, Mineralogy, and Origin of Gold Ore Deposits (Nauka, Moscow, 1991).
R. R. Large, L. Danyushevsky, C. Hollit, V. Maslenni- cov, S. Meffer, S. Gilbert, S. Bull, R. Scott, P. Emsbo, H. Thomas, B. Sinch, and J. Foster, “Gold and trace elements zonation in pyrite using a laser imaging technique: Implication for timing of gold in orogenic and Carlin-style sediment-hosted deposits,” Econ. Geol. 104(5), 635–668 (2009).
H. V. Thomas, R. R. Large, S. W. Bull, V. Maslennicov, R. F. Berry, R. Fraser, S. Frooud, and R. Moge, “Pyrite and pyrrhotite textures and compositions in sediments, laminated quartz veins and reefs at Bendigo Gold Mine, Australia: insight for ore genesis,” Econ. Geol. 106(1), 1–31 (2011).
N. V. Vilor, M. G. Kazharskaya, E. V. Chuparina, V. V. Kotkin, and S. Yu. Deis, “Distribution of gold concentration in the deposits of the Bodaibo ore district,” Rudy Met., No. 1, 34–43 (2007).
K. R. Kovalev, Yu. A. Kalinin, E. A. Naumov, M. K. Kolesnikova, V. I. Korolyuk, “Gold-bearing arsenopyrite in eastern Kazakhstan gold-sulfide deposits,” Russ. Geol. Geophys. 52(2), 178–192 (2011).
A. D. Genkin, F. E. Vagner, T. L. Krylova, and A. I. Tsepin, “Gold-bearing arsenopyrite and its formation condition at the Olympiada and Veduga gold deposits (Yenisei Range, Siberia),” Geol. Ore Dep. 44(1), 72–68 (2002).
M. Reich, S. E. Kesler, S. Utsunomya, C. S. Palenik, S. Chryssoulis, and R. C. Ewing, “Solubility of gold in arsenous pyrite,” Geochim. Cosmochim. Acta 66(11), 2781–2796 (2005).
T. M. Seward, “Thiocomplexes of gold in hydrothermal ore solutions,” Geochim. Cosmochim. Acta 37(2), 379–399 (1973).
T. A. Grigor’eva and L. S. Sukneva, “Effect of sulfur and stibium and arsenic sulfides on the gold solubility,” Geokhimiya, No. 10, 1534–1539 (1981).
T. M. Akhmedzhanova, I. Ya. Nekrasov, V. I. Tikhomirova, and A. Konyushok, “Gold solubility in the sulfidearsenous solutions at 200–300°C,” Dokl. Akad. Nauk SSSR 300(6), 1453–1456 (1988).
V. I. Tikhomirova, G. M. Akhmedzhanova, A. I. Nekrasov, and T. N. Dokina, “Study of the effect of arsenic and redox conditions on the gold solubility in the halogenic solutions at 200–300°C and pressure of 50 MPa,” in Experimental and Theoretical Modeling of Mineral Formation (Nauka, Moscow, 1998), pp. 326–339 [in Russian].
N. V. Vilor and L. A. Kaz’min, “Physicochemical modeling as applied to study of sulfoarsenide complexes in hydrothermal solutions,” Russ. Geol. Geophys. 48(6), 457–467 (2007).
N. V. Vilor, L. A. Kaz’min, and L. A. Pavlova, “Physicochemical modeling mineral formation at the gold deposits (Fe-As-S-Na-Cl-H2O system),” Vestn. SVNTs DVO RAN, No. 4, 52–64 (2011).
H. C. Helgeson, D. H. Kirkham, and G. C. Flowers, “Theoretical prediction of thermodynamic behavior of aqueous electrolytes at high pressure and temperatures: IV. Calculation of activity coefficients, osmotic coefficients and apparent molal and standard and relative partial molal properties to 600°C and 5 kbar,” Amer. J. Sci. 291, 1249–1516 (1981).
E. L. Shock, L. Sassani, M. Willes, and D. A. Sverjensky, “Inorganic species in geologic fluids: Correlation among standard molal thermodynamic properties of aqueous hydroxide complexes,” Geochim. Cosmochim. Acta 61(5), 907–950 (1997).
D. A. Sverjensky, E. L. Shock, and H. C. Helgeson, “Prediction of thermodynamic properties of aqueous metal complexes to 1000°C and 5 kbar,” Geochim. Cosmochim. Acta 61, 1359–1412 (1997).
N. N. Akinfiev and A. V. Zotov, “Thermodynamic description of chloride, hydrosulfide, and hydroxo complexes of Ag(I), Cu(I), and Au(I) at temperatures of 25–500°C and pressures of 1–2000 bar,” Geochem. Int., 39(10), 990–1006 (2001).
N. N. Akinfiev and A. V. Zotov, “Thermodynamic description of aqueous species in the system Cu-Ag-Au-S-O-H at temperatures of 0–600°C and pressures of 1–3000 bar,” Geochem. Int. 48(7), 714–720 (2010).
L. G. Benning and T. M. Seward, “Hydrosulfide complexing of Au (I) in hydrothermal solutions from 150–400°C and 500–1500 bars,” Geochim. Cosmochim. Acta 6(11), 1849–1871 (1996).
P. J. Renders and T. M. Seward, “The stability of hydrosulfide-sulfide complexes of Au (I) and Ag(I) at 25°C,” Geochim. Cosmochim. Acta 53(2), 245–253 (1989).
G. A. Pal’yanova, Physicochemical Peculiarities of Gold and Silver Behavior during Hydrothermal Ore Formation (SO RAN, Novosibirsk, 2008) [in Russian].
I. V. Zakirov, T. M. Dadze, N. G. Sretenskaya, T. A. Kashirtseva, V. A. Volchanskaya, “Gold solubility in low-density fluids in the Au—H2O-H2S-Cl system: Experimental data,” Geochem. Int. 47(3), 311–314 (2009).
F. Gibert, M. -L. Pascal, and M. Pichavant, “Gold solubility and speciation in hydrothermal solutions: Experimental study of the stability of hydrosulphide complex of gold (AuHS0) at 350–450°C and 500 bars,” Geochim. Cosmochim. Acta 62(17), 2931–2947 (1998).
V. B. Belevantsev, B. I. Peshchevitskii, and G. I. Shamovskaya, “Sulfide complexes of Au(I) in aqueous solutions,” Izv. Sib. Otd. Ross. Akad. Nauk, Ser. Khim., 1(2), 81–87.
T. M. Dadze, T. M. Akhmedzhanova, T. A. Kashirtseva, and R. Yu. Orlov, “The Au solubility in H2S-bearing aqueous solutions at 300°C,” Dokl. Earth Sci. 369A(9), 1275–1276 (1999).
A. V. Zotov, N. N. Baranova, and L. N. Bannykh, “Solubility of the gold sulfides Au2S and AuAgS in solutions containing hydrogen sulfide at 25–80°C and pressures of 1 and 500 bar,” Geochem. Int. 34(3), 216–221 (1996).
D. M. Shenberger and H. L. Barnes, “Solubility of gold in aqueous sulfide solutions from 150 to 350°C,” Geochim. Cosmochim. Acta 53(2), 269–278 (1989).
V. Zakaznova-Herzog and T. M. Seward, “A Spectrophotometric Study of the Formation and Deprotonation of Thioarsenite Species in Aqueous Solution at 22°C,” Geochim. Cosmochim. Acta 83, 48–60 (2012).
G. S. Pokrovsky, R. Gout, J. Shott, A. Zotov, and J.-C. Harrichoury, “Thermodynamic properties and stoichiometry of As (III) hydroxide complexes at hydrothermal conditions,” Geochim. Cosmochim. Acta 60(5), 737–749 (1996).
J. A. Tossell, “Theoretical studies of an arsenic oxide and hydroxide species in minerals and in aqueous solution,” Geochim. Cosmochim. Acta 61(8), 1613–1623 (1997).
K. V. Chudnenko, Thermodynamic Modeling in Geochemistry: Theory, Algorithms, Software, and Applications (“Geo”, Novosibirsk, 2010) [in Russian].
I. Ya. Nekrasov and A. A. Konyushok, “Heteropolynuclear gold complexes in the stibium-sulfide solutions,” Dokl. Akad. Nauk SSSR 266(6), 1463–1467 (1982).
J. A. Tossel, “The speciation of gold in aqueous solutions: a theoretical study,” Geochim. Cosmochim. Acta 60(1), 17–29 (1996).
C. A. Heinrich and P. J. Eadington, “Thermodynamic properties of the hydrothermal chemistry of arsenic and their significance for the paragenetic sequence of some cassiterite-arsenopyrite-base metal sulfide deposits,” Econ. Geol. 81(3), 511–528 (1986).
M. H. N. Srivastava and S. Ghosh, “Studies of thioarsenites. Part 1. Precipitation and dissolution of arsenious sulfide,” J. Indian. Chem. Soc. 35(5), 165–169 (1958).
N. A. Goryachev, O. V. Vikent’eva, N. S. Bortnikov, V. Yu. Prokof’ev, V. A. Alpatov, and V. V. Golub, “The world-class Natalka gold deposit, northeast Russia: REE patterns, fluid inclusions, stable oxygen isotopes, and formation conditions of ore,” Geol. Ore Dep. 50(5), 362–390 (2008).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.V. Vilor, L.A. Kazmin, N.A. Goryachev, 2014, published in Geokhimiya, 2014, No. 10, pp. 936–945.
Rights and permissions
About this article
Cite this article
Vilor, N.V., Kazmin, L.A. & Goryachev, N.A. Gold sulfoarsenide complexes in ore-forming hydrothermal solutions (thermodynamic modeling). Geochem. Int. 52, 882–890 (2014). https://doi.org/10.1134/S0016702914100103
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0016702914100103