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Geochemical zoning in ferromanganese crusts of Ita-MaiTai guyot

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Abstract

Samples of ferromanganese crusts dredged from Ita-MaiTai guyot (Magellan seamounts, Pacific Ocean) were studied. They are made up of a complete stratigraphic section of different-age layers, including unique oldest relict layers in some samples. The study of trace, rare-earth, and noble element (including Pt and Pd) distribution showed that old layers differ from young ones in terms of Co, TR, S, As, and P. In addition, composition of the crusts significantly varies depending on the spatial position of sample in the guyot. In some zones, crusts enriched in trace elements were generated both in the Pleistocene and Paleogene. Significant variations established in trace element composition of different-age layers indicate that trace element composition of the crusts notably evolved with time, which could be caused by productivity of biocenosis or change in the formation depth of crusts on the guyot due to vertical tectonic movements.

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References

  1. Ferromanganese Nodules of the World Ocean, Ed. by Yu. B. Kazmin (Nedra, Leningrad, 1984) [in Russian].

    Google Scholar 

  2. Ferromanganese Crusts and Nodules of Pacific Seamounts, Ed. by A. P. Lisitsina (Nauka, Moscow, 1990) [in Russian].

    Google Scholar 

  3. Cobalt-Rich Ores in the World Ocean, ed. by S. I. Andreev (VNII Okeangeologiya, St. Petersburg, 2002) [in Russian].

    Google Scholar 

  4. G. N. Baturin, Geochemistry of Oceanic Ferromanganese Nodules (Nauka, Moscow, 1986) [in Russian].

    Google Scholar 

  5. M. E. Mel’nikov, Deposits of Cobalt-Rich Manganese Crusts (FGUGP GNTs, Gelendzhik, 2005).

    Google Scholar 

  6. G. P. Glasby, “Manganese: Predominant Role of Nodules and Crusts,” in Marine Geochemistry, Ed. by D. Horst and Schulz Matthias Zabel (Springer Berlin Heidelberg New York, 2006), pp. 371–315.

  7. A. V. Dubinin, Geochemistry of Rare-Earth Elements in the Ocean (Nauka, Moscow, 2006) [in Russian].

    Google Scholar 

  8. J. R. Hein, A. Koschinsky, and A. N. Halliday, “Global Occurrence of Tellurium-Rich Ferromanganese Crusts and a Model for the Enrichment of Tellurium,” Geochim. Cosmochim. Acta 67, 1117–1127 (2003).

    Article  Google Scholar 

  9. L. I. Anikeeva, S. I. Andreev, and P. A. Aleksandrov, “Platinum Potential of the Ferromanganese Formations of the World Ocean,” in Platinum of Russia (Moscow, 2002), Vol. 3, pp. 338–345 [in Russian].

  10. J. R. Hein, B. McIntyre, and A. Koschinsky, “The Global Enrichment of Platinum Group Elements in Marine Ferromanganese Crust,” in Extended Abstracts of 10th International Platinum Symposium Platinum-Group Elements-from Genesis to Beneficiation and Environmental Impact, Oulu, Finland, 2005. (Oulu, 2005), p. 23.

  11. T. Kuhn, B. C. Bostick, A. Koschinsky, et al., “Enrichment of Mo in Hydrothermal Mn Precipitates: Possible Mo Sources, Formation Process and Phase Associations,” Chem. Geol. 199, 29–43 (2003).

    Google Scholar 

  12. Jiang Xuejun, Lin Xuehui, Shikui De Yao, and Guo Weidong, “Geochemistry of Lithium in Marine Ferromanganese Oxide Deposits,” Deep Sea Res. Part I: Oceanogr. Res. Pap. 54, 85–98 (2007).

    Article  Google Scholar 

  13. Chan Lui-Heung and Hein James R, “Lithium Contents and Isotopic Compositions of Ferromanganese Deposits from the Global Ocean,” in Deep Sea Research Part II: Topical Studies in Oceanography, 54 (11–13), 1147–1162 (2007).

    Article  Google Scholar 

  14. M. Frank, R. K. O’ Nions, J. R. Hein, and V. K. Bana-kar, “60 Myr Records of Major Elements and Pb-Nd Isotopes from Hydrogenous Ferromanganese Crusts: Reconstruction of Seawater Paleochemistry,” Geochim. Cosmochim. Acta 63(11–12), 1689–1708 (1999).

    Article  Google Scholar 

  15. B. L. Lewis and G. W. Luther, “III Processes Controlling the Distribution and Cycling of Manganese in the Oxygen Minimum Zone of the Arabian Sea,” DSRP II 47(7–8), 1541–1561 (2000).

    Google Scholar 

  16. J. J. Morgan, “Kinetics of Reaction Between O2 and Mn(II) Species in Aqueous Solutions,” Geochim. Cosmochim. Acta 69(1), 35–48 (2005).

    Article  Google Scholar 

  17. D. A. Crerar and H. L. Barnes, “Deposition of Deep-Sea Manganese Nodules,” Geochim. Cosmochim. Acta 38, 279–300 (1974).

    Article  Google Scholar 

  18. K. S. Johnson, K. H. Coale, W. M. Berelson, and R. M. Gordon, “On the Formation of the Manganese Maximum in the Oxygen Minimum,” Geochim. Cosmochim. Acta 60(8), 1291–1299 (1996).

    Article  Google Scholar 

  19. Ralf R. Haese, “The Biogeochemistry of Iron,” in Marine Geochemistry. 2nd Revised, Updated and Extended Edition Ed. by Horst D. Schulz Matthias Zabel (Springer-Berlin-Heidelberg-New York, 2006), pp. 241–260.

  20. G. P. Glasby and H. D. Schulz, “Eh, pH Diagrams for Mn, Fe, Co, Ni, Cu and As Under Seawater Conditions: Application of Two New Types of Eh, pH Diagrams To the Study of Specific Problems in Marine Geochemistry,” Aq. Geochem. 5, 227–248 (2003).

    Article  Google Scholar 

  21. N. F. Chelishchev, N. K. Gribanova, and G. V. Novikov, Sorption Properties of Oceanic Ferromanganese Nodules and Crusts (Nedra, Moscow, 1992) [in Russian].

    Google Scholar 

  22. O. S. Pokrovsky, G. S. Pokrovsky, J. Schott, and A. Galy, “Experimental Study of Germanium Adsorption on Goethite and Germanium Coprecipitation with Iron Hydroxide: X-Ray Absorption Fine Structure and Macroscopic Characterization,” Geochim. Cosmochim. Acta 70, 3325–3341 (2006).

    Article  Google Scholar 

  23. I. M. Varentsov, V. S. Putilina, and L. V. Zaitseva, “Study of Formation Mechanisms of Ferromanganese Crusts in Modern Basins. Communication 2. Experiments on Estimating Role of Major Ions of Seawater and Dissolved Organic Matter during Cu(II) Sorption on 7A MnO2 (bernessite),” Litol. Polezn. Iskop., No. 5, 88–100 (1988).

  24. A. M. Asavin, L. I. Anikeeva, V. A. Kazakova, et al., “Trace Element and PGE Distribution in Layered Ferromanganese Crusts,” Geokhimiya, No. 12, 1251–1279 (2008) [Geochem. Int. 46, 1179–1206 (2008)].

  25. R. A. Hodkinson and D. S. Cronan, “Regional and Depth Variability in the Composition of Cobalt-Rich Ferromanganese Crusts from the SOPAC Area and Adjacent Parts of the Central Equatorial Pacific,” Mar. Geol. 98, 437–447 (1991).

    Article  Google Scholar 

  26. Ph. A. Verlaan, D. S. Cronan, and Ch. L. Morgan, “A Comparative Analysis of Compositional Variations in and Between Marine Ferromanganese Nodules and Crusts in the South Pacific and Their Environmental Controls,” Progr. Oceanogr. 63, 125–158 (2004).

    Article  Google Scholar 

  27. T. G. Lee, J. R. Hein, K. Lee, et al., “Sub-Seafloor Acoustic Characterization of Seamounts near the Ogasawara Fracture Zone in the Western Pacific using Chirp (3–7 kHz) Subbottom Profiles,” in Deep-Sea Research Part I-Oceanographic Research Papers, 52 1932–1956 (2005).

    Article  Google Scholar 

  28. J. Marti, M. Hurlimann, G. J. Abley, and A. Gudmundsson, “Vertical and Lateral Collapses on Tenerife (Canary Islands) and Other Volcanic Ocean Islands,” Geology 25, 879–882 (1997).

    Article  Google Scholar 

  29. A. P. Koppers, H. Staudigel, M. S. Pringle, and J. R. Wijbrans, “Short-Lived and Discontinuous Intraplate Volcanism in the South Pacific: Hot Spots Or Extensional Volcanism,” Geochem. Geophys. Geosyst. 4(10), 1–49 (2003).

    Article  Google Scholar 

  30. V. A. Rashidov, “Magellan Seamounts (Pacific Ocean): State of Geological Knowledge,” Vestn. SVNTs DVO RAN, No. 2, 13–20 (2006).

  31. M. E. Mel’nikov and I. A. Pulyaeva, “Ferromanganese Crusts of the Markus-Wake and Magellan Seamounts of the Pacific Ocean: Structure, Composition, and Age,” Tikhookean. Geol., No. 4, 13–27 (1994).

  32. Glasby Geoffrey P., Ren Xiangwen, Shi Xuefa, and Irina A. Pulyaeva, “Co-Rich Mn Crusts from the Magellan Seamount cluster: the Long Journey through Time, Geo-Mar. Lett. 27, 315–332 (2007).

    Article  Google Scholar 

  33. M. E. Mel’nikov, I. N. Ponomareva, D. D. Tugolesov, and V. Kh. Rozhdestvenskii, “Results of Drilling of Cobalt-Bearing Manganese Crusts on Guyots of the Magellan Seamounts (Pacific Ocean),” Tikhookean. Geol. 24(5), 36–49 (2005).

    Google Scholar 

  34. Wang Yimin, Song Haowei, and Wang Xiaohong, “Ocean Manganese Nodule and Sediment Reference Materials,” Mar. Geores. Geotechnol., No. 16, 321–334 (1998).

  35. Wang Yimin, Luo Daihong, Gao Yushi, et al., “Preliminary Study on the Preparation of Four Pacific Ocean Polimetallic Nodule and Sediment Reference Materials,” GSPN-2, GSPN3, GSMS-2 and GSMS-3” Geost. Newslett. 22(2), 247–255 (1998).

    Google Scholar 

  36. Certificate on Standard Sample of Ferromanganese Nodule Composition (SDO4, SDO5, SDO6, SDO7) GSO3683-3689-87, GSO4231-88 Institute of Oceanology (Irkutsk. Gos. Univ., Moscow, 1987) [in Russian].

  37. http://www.crpg.cnrs-nancy.fr/SARM/geostandards//

  38. O. A. Tyutyunnik, D. N. Chkhetija, M. L. Getsina, et al., “Microelement Composition of Sediments of Crimea and Northwestern Caucasus As the Evidence of Global Anoxic Event,” Euras. J. Analyt. Chem. 3(1), 91–112 (2008).

    Google Scholar 

  39. E. Bonatti, T. Kraemer, and H. Rydell, “Classification and Genesis of Submarine Iron-Manganese Deposits,” in Ferromanganese Deposits on the Ocean Floor. National Science Foundation, Ed. by D. Horn, (Washington D.C., 1972), pp. 149–165.

  40. D. Puteanus and P. Halbach, “Correlation of Co Concentration and Growth Rate-A Method for Age Determination of Ferromanganese Crusts,” Chem. Geol. 69, 73–85 (1988).

    Article  Google Scholar 

  41. K. S. Jeonga, H. S. Junga, J. K. Kang, C. Morgan, and J. R. Heinmicroprobe, “Co Formation of Ferromanganese Crusts on Northwest Intertropical Pacific Seamounts: Electron Photomicrography and Micro-probe Chemistry,” Mar. Geol. 162(2–4), 541–559 (2000).

    Article  Google Scholar 

  42. K. W. Bruland and M. C. Lohan, “Controls of Trace Metals in Seawater,” in Treatise on Geochemistry Header 6.2, (Elsevier, 2003), pp. 23–44.

  43. L. P. Gromet, R. F. Dymek, L. A. Haskin, and R. L. Korotev, “The North American Shale Composite”: Its Compilation, Major Minor and Trace Element Characteristics,” Geochim. Cosmochim. Acta 48(12), 2469–2482 (1984).

    Article  Google Scholar 

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Correspondence to A. M. Asavin.

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Original Russian Text © A.M. Asavin, I.V. Kubrakova, M.E. Mel’nikov, O.A. Tyutyunnik, E.I. Chesalova, 2010, published in Geokhimiya, 2010, Vol. 48, No. 5, pp. 451–474.

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Asavin, A.M., Kubrakova, I.V., Mel’nikov, M.E. et al. Geochemical zoning in ferromanganese crusts of Ita-MaiTai guyot. Geochem. Int. 48, 423–445 (2010). https://doi.org/10.1134/S0016702910050010

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