Abstract
Mineral equilibria were analyzed in the system As-bearing rock-meteoric water. It was shown that carbonate rocks are the most probable source of As and Sr in the waters of the Datong Basin (People's Republic of China). The reason for groundwater enrichment in As is the shift of the equilibrium FeCO3 (siderite) + H2O = FeOOH(goethite) + CO2(g) + H2(g) to the left (toward siderite formation) owing to organic matter oxidation by atmospheric oxygen and an increase in the equilibrium partial pressure of CO2, while the Eh of the system remains below −0.30 ± 0.06 V.
Similar content being viewed by others
References
A. A. Yaroshevsky, “Abundances of Chemical Elements in the Earth’s Crust,” Geokhimiya, No. 1, 54–62 (2006) [Geochem. Int. 44, 48–55 (2006)].
V. V. Ivanov, Ecological Geochemistry of the Elements (Nedra, Moscow, 1996), Vol. 3 [in Russian].
D. N. Pachadzhanov, A. N. Bazarova, and I. P. Adamchuk, Paleohydrochemistry and Modes of Element Migration in the Supergene Zone (Dushanbe, 1988) [in Russian].
S. L. Shvartsev, Hydrogeochemistry of the Supergene Zone (Nedra, Moscow, 1989) [in Russian].
S. R. Krainov, B. N. Ryzhenko, and V. M. Shvets, Geochemistry of Groundwaters. Theoretical, Applied, and Ecological Aspects (Nauka, Moscow, 2004) [in Russian].
P. L. Smedley and D. G. Kinniburgh, “A Review of the Source, Behavior and Distribution of Arsenic in Natural Waters,” Appl. Geochem. 17, 517–568 (2002).
S. L. Shvartsev and Yanxing Wang, “Geochemistry of Sodic Waters in the Datong Intermountain Basin, Shanxi Province, Northwestern China,” Geokhimiya, No. 10, 1097–1109 (2006) [Geochem. Int. 44, 1015–1026 (2006)].
Yu. V. Shvarov, “Algorithmization of the Numeric Equilibrium Modeling of Dynamic Geochemical Processes,” Geokhimiya, No. 6, 646–652 (1999) [Geochem. Int. 37, 571–576 (1999)].
H. Liu, X. Xie, and Y. Wang, “Mineralogical and Geochemical Properties of Arsenic-Contaminated Aquifer Sediments, Datong Basin, North China,” in Water-Rock Interaction (WRI-12), Ed. by T. D. Bullen and Yanxin Wang (Taylor and Francis, Boca Raton, 2007), pp. 1069–1072.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Yanxin Wang, Teng Ma, B.N. Ryzhenko, O.A. Limantseva, E.V. Cherkasova, 2009, published in Geokhimiya, 2009, No. 7, pp. 757–768.
Rights and permissions
About this article
Cite this article
Wang, Y., Ma, T., Ryzhenko, B.N. et al. Model for the formation of arsenic contamination in groundwater. 1. Datong Basin, China. Geochem. Int. 47, 713–724 (2009). https://doi.org/10.1134/S0016702909070052
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0016702909070052