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Helium and argon isotopes in rocks and minerals of the Lovozero Alkaline Massif

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Abstract

The contents and ratios of helium and argon isotopes were studied in rocks of the Lovozero Massif and related rare-metal (loparite) deposits. The gases were extracted by melting (from whole-rock and mineral samples) and crushing (mainly from fluid inclusions) methods. The wide variations in the He and Ar isotopic compositions can be explained by the fact that the trapped fluid represents a mixture of variable proportions of mantle, crustal, and atmogenic components and radiogenic in situ produced gas. The obtained gas-geochemical data reflect the complex evolution of the considered ore-magmatic system and the similar trends of melt evolution and complementary fluid phase in the magmatic chamber, in general, in three-rock (urtite-foyaite-lujavrite) units and, in each individual layers, the relative closeness of the system during magmatic crystallization and initial epimagmatic processes. It was also found that the earliest magmatic mineral was loparite and that ore units and mineralization could be partially transformed during a comparatively late postmagmatic stage. An important role of paleometeoric waters in the low-temperature mineral formation was shown.

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References

  1. L. N. Kogarko, U. Kramm, and B. Grauert, “New Data on the Age and Genesis of Alkaline rocks of the Lovozero Massif (Rubidium and Strontium Isotopy),” Dokl. Akad. Nauk SSSR 260(4), 1000–1005 (1981).

    Google Scholar 

  2. U. Kramm and L. N. Kogarko, “Nd and Sr Isotope Signatures of the Khibina and Lovozero Agpaitic Centres, Kola Alkaline Province, Russia,” Lithos 32, 225–242 (1994).

    Article  Google Scholar 

  3. A. A. Arzamastsev, L. V. Arzamastseva, V. N. Glaznev, and A. B. Raevskii, “Petrologic-Geophysical Model for the Structure and Composition of Deep Levels of the Khibina and Lovozero Complexes, Kola Peninsula,” Petrologiya 6(5), 478–496 (1998) [Petrology 6, 434–450 (1998)].

    Google Scholar 

  4. A. A. Arzamastsev, F. Bea, B. V. Belyatskii, et al., “Paleozoic Processes of the Plume-Lithosphere Interaction in the Northeastern Part of the Baltic Shield: Duration, Volumes, and Magma Generation Conditions,” in Geology and Mineral Resources of the Kola Peninsula. Vol. 2. Minerals, Mineralogy, Petrography, and Geophysics (Poligraf, Apatity, 2002) [in Russian].

    Google Scholar 

  5. L. N. Kogarko, “Problems of the Genesis of Giant Apatite and Rare Metal Deposits of the Kola Peninsula, Russia,” Geol. Rudn. Mestorozhd. 41(5), 387–403 (1999) [Geol. Ore Dep. 41, 351–366 (1999)]

    Google Scholar 

  6. A. A. Arzamastsev, F. Bea, V. N. Glaznev, et al., “Kola Alkaline Province in the Paleozoic: Assessment of Composition of Primary Mantle Melts and Magma Generation Conditions,” Ross. Zh. Nauk Zemle 3(1), 1–35 (2001).

    Google Scholar 

  7. L. N. Kogarko, “Alkaline Magmatism and Enriched Mantle Reservoirs: Mechanisms, Time, and Depth of Formation,” Geokhimiya, No. 1, 5–13 (2006) [Geochem. Int. 44, 3–10 (2006)].

  8. L. N. Kogarko, T. Williams, and E. D. Osokin, “The Evolution of Loparite Compositions in the Lovozero Massif,” Geokhimiya, No. 4, 294–297 (1996) [Geochem. Int. 34, 262–265 (1996)].

  9. L. N. Kogarko, C. T. Williams, and A. R. Woolley, “Chemical Evolution and Petrogenetic Implications of Loparite in the Layered, Agpaitic Lovozero Complex, Kola Peninsula, Russia,” Mineral. Petrol. 74, 1–24 (2002).

    Article  Google Scholar 

  10. I. N. Tolstikhin, I. L. Kamenskii, B. Marti, et al., “Identification of the Lower Mantle Plume Material in the Devonian Alkaline-Ultrabasic-Carbonatite Complexes of the Kola Peninsula based on the Noble Gas Isotopy and Radioactive Element Studies,” (Apatity-Nancy-Brussels, 1999) [in Russian].

  11. I. N. Tolstikhin, I. L. Kamensky, B. Marty, et al., “Rare Gas Isotopes and Parent Trace Elements in Ultrabasic-Alkaline-Carbonatite Complexes, Kola Peninsula: Identification of Lower Mantle Plume Component,” Geochim. Cosmochim. Acta 66(5), 881–901 (2002).

    Article  Google Scholar 

  12. V. A. Nivin, I. L. Kamenskii, and I. N. Tolstikhin, “Helium and Argon Isotopic Composition in Rocks of the Ore-Bearing Units of the Lovozero Massif,” Geokhimiya, No. 1, 33–39 (1988).

  13. V. A. Nivin, I. L. Kamensky, and I. N. Tolstikhin, “Helium and Argon Isotope Abundances in Rocks of the Lovozero Alkaline Massif,” Isotopenpraxis 28, 281–287 (1993).

    Google Scholar 

  14. S. V. Ikorskii, I. L. Kamensky, and V. A. Nivin, “Helium Isotopic Composition in the Contact Zones of Alkaline Massifs and the Relative Duration of Their Formation,” in Proceedings of 19th All-Russian Seminar on Geochemistry of Magmatic Rocks with Participation of CIS, Moscow, Russia, 2000, (GEOKhI RAN, Moscow, 2000), pp. 63–64 [in Russian].

    Google Scholar 

  15. V. A. Nivin, S. V. Ikorskii, and I. L. Kamenskii, “Isotopic-Gas (He, Ar) Indicators of the Sources of the Paleozoic Alkaline Complexes of the Kola Province and Related Ore Deposits,” in Alkaline magmatism and Problems of Mantle Sources (Irkutsk, 2001), pp. 129–142 [in Russian].

  16. V. A. Nivin and S. V. Ikorskii, “Features of the Formation of the Lovozero Rare-Metal Deposits, Kola Peninsula, Based on Isotopic-Gas (He, Ar) Data,” in Proceedings of 2nd Intenational Seminar on Deep-Seated Magmatism, Magmatic Sources, and Plume Problems, Russia, 2002 (Irkutsk-Vladivostok, 2002), pp. 214–234 [in Russian].

  17. V. A. Nivin, S. V. Ikorskii, and A. A. Avedisyan, “Distribution of Hydrocarbon Gases and Helium Isotopes in the Contact Zone of the Lovozero Massif,” in Proceedings of Seminar on the Geochemistry of Magmatic Rocks. Scientific School “Alkaline Magmatism of the Earth”, Moscow, Russia, 2005 (Moscow, 2005), pp. 110–112 [in Russian].

  18. I. L. Kamenskii, I. N. Tolstikhin, I. V. Sharkov, and Yu. D. Pushkarev, “First Results of the Measurement of a Helium Isotopic Composition on a MI-1201 Single-Cascade Mass Spectrometer,” Geokhimiya, No. 3, 439–443 (1984).

  19. I. L. Kamensky, I. N. Tolstikhin, and V. R. Vetrin, “Juvenile Helium in Ancient Rocks: I. 3He Excess in Amphiboles from 2.8 Ga Charnockite Series: Crust-Mantle Fluid Intracrustal Magmatic Process,” Geochim. Cosmochim. Acta 54, 3115–3122 (1990).

    Article  Google Scholar 

  20. S. V. Ikorskii and I. L. Kamenskii, “Method of Rock Crushing in Glass Ampoules during Noble gas isotopic Studies,” in 15th Symposium on Isotope Geochemistry, Moscow, Russia, 1998 (Moscow, 1998), p. 115 [in Russian].

  21. B. A. Mamyrin and I. N. Tolstikhin, Helium Isotopes in Nature (Elsevier, New York, 1984).

    Google Scholar 

  22. A. B. Verkhovskii and Yu. A. Shukolyukov, Element and Isotopic Fractionation of Noble Gases in Nature (Nauka, Moscow, 1991) [in Russian].

    Google Scholar 

  23. I. N. Tolstikhin and B. Marty, “The Evolution of Terrestrial Volatiles: A View from Helium, Neon, Argon and Nitrogen Isotope Modeling,” Chem. Geol. 147, 27–52 (1998).

    Article  Google Scholar 

  24. P. G. Burnard, R. Hu, G. Turner, and X. W. Bi, “Mantle, Crustal and Atmospheric Noble Gases in Ailaoshan Gold Deposits, Yunnan Province, China,” Geochim. Cosmochim. Acta 63(10), 1595–1604 (1999).

    Article  Google Scholar 

  25. R. Z. Hu, Burnard P.G., X. W. Bi, et al. “Helium and Argon Isotope Geochemistry of Alkaline Intrusion-Associated Gold and Copper Deposits along the Red River-Jinshajiang Fault Belt, SW China,” Chem. Geol. 203, 305–317 (2004).

    Article  Google Scholar 

  26. C. Gautheron, M. Moreira, and C. Allegre, “He, Ne and Ar Composition of the European Lithospheric Mantle,” Chem. Geol. 217, 97–112 (2005).

    Article  Google Scholar 

  27. L. N. Kogarko and B. P. Romanchev, “Phase Equilibria in Alkaline Melts,” Zap. Vses. Mineral. O-va, Pt. 3 (Vyp. 2), 167–182 (1982).

  28. S. V. Ikorskii, V. A. Nivin, and V. A. Pripachkin, Geochemistry of Gases in Endogenous Complexes (Nauka, St. Petersburg, 1992) [in Russian].

    Google Scholar 

  29. V. A. Nivin, “Gas Concentrations in Minerals with Reference to the Problem of the Genesis of Hydrocarbon Gases in Rocks of the Khibiny and Lovozero Complexes,” Geokhimiya, No. 9, 976–992 (2002) [Geochem. Int. 40, 883–898 (2002)].

  30. J. Potter, A. H. Rankin, and P. J. Treloar, “Abiogenic Fisher-Tropsch Synthesis of Hydrocarbons in Alkaline Igneous Rocks; Fluid Inclusion, Textural and Isotopic Evidence from the Lovozero Complex, N.W. Russia,” Lithos 75, 311–330 (2004).

    Article  Google Scholar 

  31. V. A. Nivin and S. V. Ikorsky, “Helium Isotopes and Carbon in Fluid Inclusions of the Kola Foidolite-Syenite Complexes (Russia),” in Proceedings of 15th Biennial European Current Research on Fluid Inclusions, Potsdam, Germany, 1999 (Potsdam, 1999), Terra Nostra 99/6, pp. 221–222.

  32. N. Dauphas and B. Marty, “Heavy Nitrogen in Carbonatites of the Kola Peninsula: A Possible Signature of the Deep Mantle,” Science 286, 2488–2490 (1999).

    Article  Google Scholar 

  33. J. S. Ray, R. Ramesh, and K. Pande, “Carbon Isotopes in Kerguelen Plume-Derived Carbonatites: Evidence for Recycled Inorganic Carbon,” Mar. Geol. 170, 205–214 (1999).

    Google Scholar 

  34. L. N. Kogarko and V. E. Khain, “Alkaline Magmatism in the Earth’s History: A Geodynamic Interpretation,” Dokl. Akad. Nauk 377(5), 677–679 (2001) [Dokl. Earth Sci. 377, 359–361 (2001)].

    Google Scholar 

  35. T. Matsumoto, Y. Chen, and J. Matsuda, “Concomitant Occurrence of Primordial and Recycled Noble Gases in the Earth’s Mantle,” Mar. Geol. 185, 35–47 (2001).

    Google Scholar 

  36. Ph. Sarda, “Surface Noble Gas Recycling to the Terrestrial Mantle,” Earth Planet. Sci. Let. 228, 49–63 (2004).

    Article  Google Scholar 

  37. J. Yamamoto, I. Kaneoka, Sh. Nakai, et al., “Evidence for Subduction-Related Components in the Subcontinental Mantle from Low 3He/4He and 40Ar/36Ar Ratio in Mantle Xenoliths from Far Eastern Russia” Chem. Geol. 207, 237–259 (2004).

    Article  Google Scholar 

  38. A. A. Arzamastsev, B. V. Belyatskii, A. V. Travin, et al., “Dike Rocks in the Khibina Massif: Relations with the Plutonic Series, Age, and Characteristics of the Mantle Source,” Petrologiya 13(3), 295–318 (2005) [Petrology 13, 267–288 (2005)].

    Google Scholar 

  39. G. M. Virovlyanskii, “Influence of the Emplacement Depth and Erosion Level of the Khibiny and Lovozero Massifs on their Apatite Potential,” Izv. Akad. Nauk SSSR, Ser. Geol., No. 11, 90–98 (1975).

  40. I. N. Tolstikhin, V. S. Dokuchaeva, I. L. Kamensky, and Yu. V. Amelin, “Juvenile Helium in Ancient Rocks: II. U-He, K-Ar, Sm-Nd and Rb-Sr Systematics in the Monche Pluton. 3He/4He Ratios Frozen in Uranium-Free Ultramafic Rocks,” Geochim. Cosmochim. Acta 56, 987–999 (1992).

    Article  Google Scholar 

  41. Yu. A. Borshchevskii, S. L. Borisova, N. I. Medvedovskaya, et al., “Isotopic Features of the Minerals and Rocks of the Khibiny-Lovozero Complex and Some Genetic Aspects,” Zap. Vsesoyuz. Miner. O-Va 66(5), 532–540 (1987).

    Google Scholar 

  42. B. G. Pokrovskii, Crustal Contamination of Mantle Magmas Based on Isotopic Geochemical Data (Nauka, Moscow, 2000) [in Russian].

    Google Scholar 

  43. A. A. Ul’yanov, V. I. Ustinov, A. G. Turchkova, and I. V. Pekov, “Oxygen Isotopic Composition of Minerals from Highly Alkaline Rocks of the Khibiny Massif, Kola Peninsula, Russia,” Vestn. Mosk. Univ., Ser. 4: Geol., 54–63 (2001).

  44. I. N. Tolstikhin, I. L. Kamenskii, I. V. Sharkov, et al., “Isotopes of Light Inert Gases in Carbonates from the Kola Peninsula,” (Apatity, 1985).

  45. L. N. Kogarko, “Clinopyroxene Monitoring of the Chemical Evolution of Agpaite Magmas (Lovozero Massif, Kola Peninsula),” in Proceedings of All-Russian Seminar on Geochemistry of the Magmatic Rocks with Participation of CIS. School Alkaline Magmatism. Annual Session, Moscow, Russia, 2002, (Moscow, 2002), p. 48 [in Russian].

  46. V. A. Zaitsev, T. S. Williams, and L. N. Kogarko, “Compositional Evolution of Titanite in the Vertical Section of the Differentiated Complex of the Lovozero Massif,” in Proceedings of All-Russian Seminar on Geochemistry of the Magmatic Rocks with Participation of CIS. School alkaline Magmatism. Annual Session, Moscow, Russia, 2002, (Moscow, 2002), pp. 43–44 [in Russian].

  47. E. D. Osokin, “Rare-Metal Mineralization and Genetic Aspects of the Lovozero Massif,” in Ore Geochemistry and Geology of the Magmatogenic Deposits (Nauka, Moscow, 1980), pp. 168–178 [in Russian].

    Google Scholar 

  48. Ya. A. Pakhomovskii, G. Yu. Ivanyuk, and V. N. Yakovenchuk, Mineralogy of the Rocks of the Productive Complex of Mt. Kedykvyrpakhk, Lovozero Massif, Kola Peninsula, in Proceedings of 3rd Fersman Scientific School Devoted to 50th Anniversary of the Kola Branch of the Russian Mineralogical Community, Apatity, Russia, 2006, Ed. by Yu. L. Voitekhovskii, A. V. Voloshin, and O. B. Dudkin (K & M, Apatity, 2006), pp. 128–131 [in Russian].

    Google Scholar 

  49. V. N. Zyryanov, Phase Correspondence in the Alkali Feldspar and Feldspathoid Systems (Nauka, Moscow, 1981) [in Russian].

    Google Scholar 

  50. V. A. Nivin, S. V. Ikorskii, and O. B. Dudkin, “Helium and Argon Isotopes in the Apatites from the Khibiny Massif,” in Mineralogy in the Whole Meaning of the Word. Proceedings of 2nd Fersman Scientific Session of the Kola Branch of the Russian Mineralogical Society devoted to the 140 Ramsay Anniversary, Apatity, Russia, 2005, “Ed. by Yu. L. Voitekhovskii, A. V. Voloshin, and O. B. Dudkin, (K & M; Apatity-Moscow, 2005), pp. 129–132 [in Russian].

    Google Scholar 

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Original Russian Text © V.A. Nivin, 2008, published in Geokhimiya, 2008, No. 5, pp. 524–545.

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Nivin, V.A. Helium and argon isotopes in rocks and minerals of the Lovozero Alkaline Massif. Geochem. Int. 46, 482–502 (2008). https://doi.org/10.1134/S0016702908050042

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