Skip to main content
Log in

Simulation of metamorphism and fluid regime in the mineralized unit of the Pana Massif in relation to its PGE ore mineralization

  • Published:
Geochemistry International Aims and scope Submit manuscript

Abstract

This paper presents materials on one of the units with PGE ore mineralization in the Pana Massif: the results of a detailed petrographic study and microprobe analyses of silicate and sulfide minerals and of the examination of mineral assemblages, typomorphic features of minerals, their crystallization succession and P–T conditions of this crystallization in the mineralized unit and the host mineralized and barren rocks, and the distribution of the fluid phase in them. Metamorphic processes that accompanied the development of the sulfide and PGE mineralization zones are analyzed, and it is established that the metamorphic evolution was associated with changes in the mineralogy of the rock and the composition of fluid in it. This process was of a unidirectional and systematic character and can be realistically reproduced in physicochemical models. The results of our research make it possible to assay the effect of P–T parameters and the fluid regime on the component composition of the solid phases and volatile components during the origin and localization of the PGE ore mineralization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. C. Helgeson, “Evaluation of Irreversible Reactions in Geochemical Processes Involving Minerals and Aqueous Solutions. 1. Thermodynamic Relations,” Geochim. Cosmochim. Acta 32(8), 853–877 (1968).

    Article  Google Scholar 

  2. H. C. Helgeson, R. M. Garrels, and F. T. Mc Cenzie, “Evaluation of Irreversible Reactions in Geochemical Processes Involving Minerals and Aqueous Solutions. II. Applications,” Geochim. Cosmochim. Acta 33(4), 455–481 (1969).

    Article  Google Scholar 

  3. H. C. Helgeson, T. H. Brown, A. Nigrini, and T. A. Jones, “Calculation of Mass Transfer in Geochemical Processes Involving Aqueous Solutions,” Geochim. Cosmochim. Acta 34(5), 569–592 (1970).

    Article  Google Scholar 

  4. I. K. Karpov, A. I. Kiselev, and F. A. Letnikov, Computer Simulation of the Formation of Minerals in Nature (Nedra, Moscow, 1976) [in Russian].

    Google Scholar 

  5. I. K. Karpov, Physicochemical Numerical Simulations in Geochemistry (Nauka, Novosibirsk, 1981) [in Russian].

    Google Scholar 

  6. S. A. Kashik and I. K. Karpov, Physicochemical Theory of the Origin of Weathering Crust Zoning (Nauka, Novosibirsk, 1978) [in Russian].

    Google Scholar 

  7. I. L. Khodakovskii, V. P. Volkov, Yu. I. Sidorov, and M. V. Borisov, “Mineralogical Composition of the Rocks. Hydration and Oxidation of the Outer Shell of Venus”, Geokhimiya, No. 12, 1821–1835 (1978).

  8. Yu. V. Shvarov, “Calculation of an Equilibrium Composition in a Multicomponent Heterogeneous System,” Dokl. Akad. Nauk SSSR 229(5), 1224–1226 (1976).

    Google Scholar 

  9. Precambrian Magmatic Associations of the Northeastern Baltic Shield, Ed. by I. V. Bel’kova (Nauka, Leningrad, 1985) [in Russian].

    Google Scholar 

  10. F. P. Mitrofanov, Yu. N. Yakovlev, V. V. Distler, et al., “Kola Region as a New PGE-bearing Province”, in Geology and Genesis of the PGM Deposits (Nauka, Moscow, 1994), pp. 65–79 [in Russian].

    Google Scholar 

  11. A. U. Korchagin, E. M. Bakushkin, and L. A. Vinogradov, “Geological Structure of the Marginal Zone of the Pana Tundra Massif and Its PGM Mineralization”, in Geology and Genesis of the PGM Deposits (Nauka, Moscow, 1994), pp. 100–106 [in Russian].

    Google Scholar 

  12. Z. M. Voloshina, V. P. Petrov, L. I. Popova, and S. A. Rezhenova, “Metamorphic Assemblages in the Rocks of the Lower Layered Horizon of the Pana Tundra Intrusion”, Zap. Vseross. Mineral. O-va, No. 3, 57–65 (1998).

  13. B. E. Leake, “A Catalog of Analyzed Calciferous and Subcalciferous Amphiboles Together with Their Nomenclature and Associated Minerals,” Geol. Soc. Am. Spec. Paper (1974).

  14. R. Kretz, “Symbols for Rock-Forming Minerals”, Am. Miner. 68(1–2), 277–279 (1983).

    Google Scholar 

  15. R. G. Berman, “Thermobarometry Using Multi-Equilibrium Calculations: A New Technique, with Petrological Applications,” Can. Mineral. 29(4), 833–855 (1991).

    Google Scholar 

  16. R. G. Berman, “Internally-Consistent Thermodynamic Data for Minerals in the System Na2O-K2O-CaO-Al2O3-SiO2-TiO2-H2O-CO2,” J. Petrol. 29(2), 445–522 (1988).

    Google Scholar 

  17. V. K. Karzhavin, “Platinum Group Elements,” Vestn. OGGGN RAN 1(21), (2003); URL: http://www.scgis.ru/russian/cp1251/h_dgggms/1-2003/informbul-1_2003.html#1.1

  18. V. K. Karzhavin, “Sulfides of Platinum and Palladium. Thermodynamic Properties,” in Proceedings of the Annual Seminar on Experimental Mineralogy, Petrology, and Geochemistry, Moscow, Russia, 2004 (ONTI GEOKhI RAS, 2004), pp. 31–33.

  19. R. A. Lidin, V. A. Molochko, and L. L. Andreeva, Chemical Composition of Inorganic Compounds (Khimiya, Moscow, 2000) [in Russian].

    Google Scholar 

  20. V. K. Karzhavin, “Amphiboles: Thermodynamic Properties,” Geokhimiya, No. 12, 1724–1732 (1991).

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © V.K. Karzhavin, Z.M. Voloshina, 2006, published in Geokhimiya, 2006, No. 5, pp. 522–531.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Karzhavin, V.K., Voloshina, Z.M. Simulation of metamorphism and fluid regime in the mineralized unit of the Pana Massif in relation to its PGE ore mineralization. Geochem. Int. 44, 475–484 (2006). https://doi.org/10.1134/S0016702906050041

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0016702906050041

Keywords

Navigation