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Thermal Effect of Surface Catalysis in Subsonic Dissociated-Air Jets. Experiment on a High-Frequency Plasmatron and Numerical Modeling

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Experiments on heat transfer in subsonic dissociated-air jets are performed on 100 kW VGU-4 induction plasmatron. The heat fluxes to the water-cooled surfaces of copper, silver, tantalum, beryllium, niobium, gold, molybdenum, and quartz are measured at the stagnation point on a cylindrical flat-nosed model, 50 mm in diameter, having rounded edges at 50 and 100 hPa pressures in the low-pressure chamber and the high-frequency (HF) generator power of 30 to 70 kW. At the same pressures and the HF generator powers of 45 and 64 kW the convective heating of a specimen of sintered silicon carbide is studied in the surface temperature range from 1720 to 1910 K. The predominance of the surface catalyticity effect on the heat flux with respect to nitrogen and oxygen atom recombination is demonstrated. Under the experimental conditions the air plasma flow in the discharge channel of the plasmatron, the subsonic jet flow past the cylindrical model, and the heat transfer to the stagnation point on the model are numerically simulated. Basing on the comparison of the experimental and calculated data on the heat fluxes to the surfaces of metals (Tw = 300 K), quartz (Tw = 572–722 K), and silicon carbide (Tw = 1720–1910 K) the quantitative catalyticity gradation of the materials considered with respect to heterogeneous recombination of nitrogen and oxygen atoms is established.

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REFERENCES

  1. R. Goulard, “On catalytic recombination rates in hypersonic stagnation heat transfer,” Jet Propulsion 28(11), 737 (1958).

    Google Scholar 

  2. V.D. Berkut, V.M. Doroshenko, V.V. Kovtun, and N.N. Kudryavtsev, Nonequlibrium Physico-Chemical Processes in Hypersonic Aerodynamics (Energoizdat, Moscow, 1994) [in Russian].

    Google Scholar 

  3. V.L. Kovalev and A.F. Kolesnikov, “ Experimental and theoretical simulation of heterogeneous catalysis in aerothermochemisty (a review),” Fluid Dynamics 40(5), 669–693 (2005).

    ADS  Google Scholar 

  4. B. Massuti-Ballester, S. Pidan, G. Herdrich, and M. Fertig, “Recent catalysis measurements at IRS,” Adv. Space Res. 56(4), 742 (2015).

    ADS  Google Scholar 

  5. S.A. Vasil’evskii, A.N. Gordeev, and A.F. Kolesnikov, “Local modeling of the aerodynamic heating to the blunt body surface in subsonic high-enthalpy flow. Theory and experiment on high-frequency plasmatron,” Fluid Dynamics 52(1), 158—164 (2017).

    MATH  Google Scholar 

  6. M. Balat-Pichelin, J.M. Badie, R. Berjoan, and P. Boubert, “Recombination coefficient of atomic oxygen on ceramic materials under Earth re-entry conditions by optical emission spectroscopy,” Chem. Phys. 291, 181 (2003).

    Google Scholar 

  7. I.V. Kholodkov, N.V. Kholodkova, and S.A. Smirnov, “Heterogeneous recombination of nitrogen atoms on an aluminum foil surface under low-temperature plasma conditions,” High Temperature 54(5), 639–643 (2016).

    Google Scholar 

  8. E.N. Aleksandrov, B.E. Zhestkov, and S.N. Kozlov, “Simultaneous determination of the recombination probability of nitrogen and oxygen atoms on quartz,” High Temperature 52(1), 41–47 (2014).

    Google Scholar 

  9. C.D. Scott, “Catalytic recombination of nitrogen and oxygen on high temperature reusable surface insulation,” in: AIAA Progress in Astronautics and Aeronautics: Aerothermodynamics and Planetary Entry,Vol. 77, Ed. by A.L. Crosbie (AIAA, New York, 1981), pp. 192–212.

    Google Scholar 

  10. D.A. Steward, Y.-K. Chen, D.J. Bamford, and A.B. Romanovsky, “Predicting material surface catalytic efficiency using arc-jet tests,” AIAA 95-2013 (1995).

  11. S.A. Vasil’evskii, A.F. Kolesnikov, and M.I. Yakushin, “Determination of the effective probabilities of the heterogeneous recombination of atoms, when heat flow is influenced by gas-phase reactions,” High Temperature 29(3), 411–419 (1991).

    Google Scholar 

  12. A.N. Gordeev, A.F. Kolesnikov, and M.I. Yakushin, “An induction plasma application to “Buran’s” heat protection tiles ground tests,” SAMPE J. 28(3), 27–31 (1992).

    Google Scholar 

  13. G.N. Zalogin, B.A. Zemlyanskii, V.B. Knot’ko, L.A. Kuz’min, V.V. Lunev, I.N. Murzinov, and A.N. Rumynskii, “High-frequency plasmatron – a setup for investigations of aerophysical problems using high-enthalpy gas flows,” Kosmonavtika Raketostroenie No. 2, 22–32 (1994).

    Google Scholar 

  14. V.I. Vlasov, G.N. Zalogin, B.A. Zemlyanskii, and V.B. Knot’ko, “Methods and results of an experimental investigatyion of the catalytic activity of materials at high temperatures,” Fluid Dynamics 38(5), 815–825 (2003).

    ADS  Google Scholar 

  15. A.N. Gordeev and A.F. Kolesnikov, “Induction plasmatrons of VGU series,” in: Topical Problems of Mechanics, Physico-Chemical Mechanics of Liquids and Gases (Nauka, Moscow, 2010), p. 151 [in Russian].

    Google Scholar 

  16. V. Auweter-Kurtz, H.L. Kurtz, and S. Laure, “Plasma generators for re-entry simulation,” J. Propulsion Power 12(6), 1053–1061 (1996).

    Google Scholar 

  17. B. Bottin, M. Carbonaro, V. Van Der Haegen, and S. Paris, “Predicted and measured capability of the 1.2 MW plasmatron regarding re-entry simulation,” in: Proc. Third Europ. Symp. on Aerothermodynamics for Space Vehicles. ESTEC, Noordwijk, The Netherlands, 24–26 November 1998,ESA SP-426 (1999), pp. 553–560.

    ADS  Google Scholar 

  18. B.Eu. Zhestkov, D.V. Ivanov, V.V. Shvedchenko, I.V. Yegorov, W.P.P.Fischer, and J. Antonenko, “Calculated and experimental flat and wavy surface temperature distribution, ” AIAA Paper 799-0733 (1999).

  19. A. Bourdon, A. Bultel, A. Desportes, B. van Ootegem, and P. Vervisch, “Catalycity studies of TPS in a 90 kW plasmatron at CORIA,” Presented at the 2nd International Symposium “Atmospheric Reentry Vehicles and Systems”, Arcachon (France), March 26–29, 2001.

  20. O. Chazot, H.V. Krassilchikoff, and J. Thomel, “TPS ground testing in plasma wind tunnel for catalytic properties determination,” AIAA Paper 2008–1252 (2008).

  21. D.G. Fletcher and J.M. Meyers, “Surface catalyzed reaction efficiencies in oxygen plasmas from laser induced fluorescence measurements,” J. Thermophysics Heat Transfer 31(2), 410–420 (2017).

    Google Scholar 

  22. S.A. Vasil’evskii, A.F. Kolesnikov, and M.I. Yakushin, “Mathematical models for plasma and gas flows in induction plasmatrons,” in: Molecular Physics and Hypersonic Flows,Vol. 482, Ed. by M. Capitelli (Kluwer, 1996), p. 495.

    Google Scholar 

  23. A.F. Kolesnikov, A.N. Gordeev, and S.A. Vasil’evskii, “Heat transfer in subsonic flows of dissociated nitrogen: HF plasmatron experiment and numerical simulation,” High Temperatures 56(3), 398–403 (2018).

    Google Scholar 

  24. A.F. Kolesnikov, I.S. Pershin, S.A. Vasil’evskii, and M.I. Yakushin, “Study of quartz surface catalycity in dissociated carbon dioxide subsonic flows,” J. Spacecraft Rockets 37(5), 573 (2000).

    ADS  Google Scholar 

  25. A.F. Kolesnikov, A.N. Gordeev, and S.A. Vasil’evskii, “Effects of catalytic recombination on the surfaces of metals and quartz for the conditions of entry into the Martian atmosphere,” High Temperature 54(1), 29–37 (2016).

    Google Scholar 

  26. S.A. Vasil’evskii and A.F. Kolesnikov, “Numerical investigation of flow and heat transfer in the induction plasma of a high-frequency plasamtron,” in: Encyclopedia of Low-Temperature Plasma, Ser. B, Vol. VII-1, Part 2 (Yanus-K, Moscow, 2008), p. 220 [in Russian].

  27. A.F. Kolesnikov and M.I. Yakushin, “Determination of the effective probabilities of heterogeneous atom recombination from the heat fluxes to a surface in a dissociated-air flow,” Mat. Model 1(3), 44–60 (1989).

    MathSciNet  MATH  Google Scholar 

  28. V.P. Provotorov and V.V. Ryabov, “Investigation of nonequilibrium hypersonic shock layers,” Trudy TsAGI No. 2111, 142–155 (1981).

    Google Scholar 

  29. V.G. Voronkin and Yu.V. Yakhlakov, “Experimental investigation of heat transfer in the vicinity of the critical point with nonequilibrium physico-chemical transformations and determination of the rate constants for the recombination of nitrogen,” Fluid Dynamics 8(3), 450–455 (1973).

    ADS  Google Scholar 

  30. A. Kolesnikov, A. Gordeev, S. Vasil’evskii, and J.L. Vérant, “Technical approach and validation of reentry heating simulation for the Pre-X and EXPERT vehicles using the IPG-4 plasmatron,” in: Proc. Europ. Conf. for Aero-Space Sciences EUCASS2005 (CD-ROM),2005, Moscow, Russia.

  31. A. Kolesnikov, A. Gordeev, S. Vasil’evskii, and J.L. Vérant, “Predicting catalytic properties of SiC material for the Pre-X vehicle entry conditions,” in: Proc. 2nd Europ. Conf.  for Aero-Space Sciences EUCASS2007 (CD-ROM),2007, Brussels, Belgium.

  32. A.F. Kolesnikov, A.N. Gordeev, and S.A. Vasil’evskii, “ Modeling the stagnation point heating and determining the catalytic activity for the re-entry EXPERT vehicle,” in: Physico-Chemical Kinetics in Gasdynamics, Vol. 9 (2010); http://chemphys.edu.ru/issues/2010-9/articles/123/ [in Russian].

  33. A.F. Kolesnikov, “Conditions of simulation of stagnation point heat transfer from a high-enthalpy flow,” Fluid Dynamics 28(1), 131–137 (1993).

    ADS  MATH  Google Scholar 

  34. A.F. Kolesnikov, “The aerothermodynamic simulation in sub- and supersonic high-enthalpy jets: experiment and theory,” in: Proc. 2nd Europ. Symp. on Aerothermodynamics for Space Vehicles. ESA Publication Division, Noordwijk, The Netherlands,ESA SP-367, 1995, p. 583.

    ADS  Google Scholar 

  35. A.F. Kolesnikov, “Local similarity conditions of the thermochemical interaction between high-enthalpy gas flows and an undestructible surface,” High Temperature 52(1), 110–116 (2014).

    Google Scholar 

  36. S.T. Surzhikov, Thermal Radiation of Gases and Plasmas (Bauman Technical Univ., Moscow, 2004) [in Russian].

    Google Scholar 

  37. S.A. Vasilevskii, A.F. Kolesnikov, A.I. Bryzgalov, and S.E. Yakush, “Computation of inductively coupled air plasma flow in the torches,” J. Physics: Conf. Ser. 2018, 012027.

  38. S.V. Patankar and D.B. Spalding, Heat and Mass Transfer in Boundary Layers (Intertext Books, London, 1970).

    Google Scholar 

  39. I.V. Petukhov, “Numerical calculations of two-dimensional boundary layer flows,” in: Numerical Methods for Solving Differential and Integral Equations and Quadrature Formulas (Nauka, Moscow, 1964), pp. 304–325 [in Russian].

    Google Scholar 

  40. V.A. Bityurin, A.N. Bocharov, D.S. Baranov, A.V. Krasilnikov, V.B. Knotko, and Y.A. Plastinin, “Experimental study of flow parameters and MHD generator models at high frequency plasmatron,” in: 15th Intern. Conf. MHD Energy Conversion and 6th Workshop on Magnetoplasma Aerodynamics (Institute of High Temperatures of RAS, Moscow, 2005), pp. 444–458.

  41. P.G. Dickens and M.B. Sutcliffe, “Recombination of oxygen atoms on oxide surfaces. Part 1: Activation energies of recombination,” Transactions of the Faraday Society 60, 1272–1285 (1964).

    Google Scholar 

  42. A.N. Gordeev, A.F. Kolesnikov, and V.I. Sakharov, “ Experimental and numerical investigation of heat exchange between underexpanded high-enthalpy air jets and cylindrical models,” Fluid Dynamics 53(5), 702—710 (2018).

    MATH  Google Scholar 

  43. A. Viladegut and O. Chazot, “Empirical modeling of copper catalysis for enthalpy determination in plasma facilities,” J. Thermophysics Heat Transfer 34(1), 26–36 (2020).

    Google Scholar 

  44. D. Driver and S. Sepka, “Side arm reactor study of copper catalysis”, AIAA Paper 2015-2666.

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Funding

The study is carried out within the framework of State Assignments no. АААА-А20-120011690135-5 and with the partial support of the Russian Foundation of Fundamental Research (project no. 19-01-00056).

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Correspondence to A. F. Kolesnikov.

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Translated by M. Lebedev

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Vasil’evskii, S.A., Gordeev, A.N., Kolesnikov, A.F. et al. Thermal Effect of Surface Catalysis in Subsonic Dissociated-Air Jets. Experiment on a High-Frequency Plasmatron and Numerical Modeling. Fluid Dyn 55, 708–720 (2020). https://doi.org/10.1134/S0015462820050134

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