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Oxidation of styrene epoxide–acid binary system and styrene epoxide–acid–amine ternary system catalyzed by Co(II) salts

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Abstract

The Co(II) salt (nitrate, chloride)-induced acceleration of styrene epoxide (SE) consumption and oxidation by molecular oxygen in acetonitrile solutions of three- and four-component systems, SE–acetic acid–cobalt salt and SE–acetic acid–cobalt salt–aniline, was found and investigated. The heterolytic epoxide ring opening in SE and homolysis (oxidation) catalyzed by cobalt salts can be accomplished in the presence of acid co-catalyst. The competition between homolysis and heterolysis processes in the presence of metal-containing catalyst was discovered for the first time for this type of system. The cobalt catalyst is deactivated during the styrene epoxide conversion.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    L. V. Petrov & V. M. Solyanikov

Authors
  1. L. V. Petrov
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  2. V. M. Solyanikov
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Correspondence to L. V. Petrov.

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Original Russian Text © L.V. Petrov, V.M. Solyanikov, 2017, published in Doklady Akademii Nauk, 2017, Vol. 472, No. 4, pp. 412–415.

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Petrov, L.V., Solyanikov, V.M. Oxidation of styrene epoxide–acid binary system and styrene epoxide–acid–amine ternary system catalyzed by Co(II) salts. Dokl Phys Chem 472, 19–22 (2017). https://doi.org/10.1134/S0012501617020014

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  • DOI: https://doi.org/10.1134/S0012501617020014

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