Skip to main content
Log in

New pulse sequence for robust filtering of hyperpolarized multiplet spin order

  • Physical Chemistry
  • Published:
Doklady Physical Chemistry Aims and scope Submit manuscript

Abstract

A new Nuclear Magnetic Resonance (NMR) pulse sequence is proposed for manipulating ParaHydrogen Induced Polarization (PHIP) at high magnetic fields. The technique enables conversion of the multiplet spin order into net polarization, which is much easier to exploit in many practical applications of PHIP. The pulse sequence is easy to implement; moreover, it filters out all residual signals from thermally polarized spins. Such “background free” detection is promising for sensitivity enhancement in NMR spectroscopy and improved contrast in NMR imaging.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Natterer, J. and Bargon, J., Prog. Nucl. Magn. Reson. Spectrosc., 1997, vol. 31, pp. 293–315.

    Article  Google Scholar 

  2. Nikolaou, P., Goodson, B.M., and Chekmenev, E.Y., Chem. Eur. J., 2015, vol. 21, pp. 3156–3166.

    Article  CAS  Google Scholar 

  3. Nasibulov, E.A., Pravdivtsev, A.N., Yurkovskaya, A.V., et al., Z. Phys. Chem., 2013, vol. 227, pp. 929–953.

  4. Reineri, F., Bouguet-Bonnet, S., and Canet, D., J. Magn. Reson., 2011, vol. 210, pp. 107–112.

    Article  CAS  Google Scholar 

  5. Aguilar, J.A., Elliott, P.I.P., Lopez-Serrano, J., et al., Chem. Communs., 2007, pp. 1183–1185.

    Google Scholar 

  6. Ivanov, K.L., Petrova, M.V., Lukzen, N.N., and Sagdeev, R.Z., Dokl. Phys. Chem., 2009, vol. 427, part 1, pp. 121–124.

    Article  CAS  Google Scholar 

  7. Bittl, R. and Zech, S.G., Biochim. Biophys. Acta., 2001, vol. 1507, pp. 194–211.

    Article  CAS  Google Scholar 

  8. Dechent, J.F., Buljubasich, L., Schreiber, L.M., et al., Phys. Chem. Chem. Phys., 2012, vol. 14, pp. 2346–2352.

    Article  CAS  Google Scholar 

  9. Prina, I., Buljubasich, L., and Acosta, R.H., J. Phys. Chem. Lett., 2013, vol. 4, pp. 3924–3928.

    Article  CAS  Google Scholar 

  10. Buljubasich, L., Prina, I., Franzoni, M.B., et al., J. Magn. Reson., 2013, vol. 230, pp. 155–159.

    Article  CAS  Google Scholar 

  11. Kiryutin, A.S., Ivanov, K.L., Yurkovskaya, A.V., et al., Z. Phys. Chem., 2012, vol. 226, pp. 1343–1362.

    Article  CAS  Google Scholar 

  12. Segawa, T.F. and Bodenhausen, G., J. Magn. Reson., 2013, vol. 237, pp. 139–146.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. N. Pravdivtsev.

Additional information

Published in Russian in Doklady Akademii Nauk, 2015, Vol. 465, No. 1, pp. 54–57.

The article was translated by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pravdivtsev, A.N., Ivanov, K.L., Yurkovskaya, A.V. et al. New pulse sequence for robust filtering of hyperpolarized multiplet spin order. Dokl Phys Chem 465, 267–269 (2015). https://doi.org/10.1134/S0012501615110044

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0012501615110044

Keywords

Navigation