Abstract
3,5-Dioxo-1,7-heptanedials, 3,5-dioxo-1,7-heptanediols, and derivatives of 1,3-dioxo-1,7-heptanediboxylic acid have been synthesized for the first time by the low-temperature ozonolysis of 1,3-dioxepins. It has been shown that intermediate ozonolysis products, peroxy compounds, depending on decomposition conditions can produce corresponding individual dialdehydes, diols, and diesters with high selectivity.
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This work was supported by the Ministry of Education and Science of the Russian Federation (State assignment no. FEUR–2022-0007, “Petrochemical reagents, oils, and materials for heat power engineering”).
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Translated by I. Kudryavtsev
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Belyaeva, E.R., Borisova, Y.G., Raskildina, G.Z. et al. Synthesis of Polyfunctional O-Containing Compounds with Acetal Fragment by Low-Temperature Ozonolysis of 1,3-Dioxepins. Dokl Chem 514, 58–61 (2024). https://doi.org/10.1134/S0012500824600081
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DOI: https://doi.org/10.1134/S0012500824600081