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Synthesis of New Lithium-Conducting Copolymers and the Influence of Their Structure and Composition on Ionic Conductivity

Doklady Chemistry volume 502, pages 29–36 (2022)Cite this article

Abstract

A new polymeric electrolyte with mobile charges of one type has been synthesized. It is a block copolymer with non-ionic block of poly(2,2,3,3,4,4,5,5-octafluoropentyl methacrylate), which improves mechanical performance, and ionic block as a random copolymer of lithium 1-[3-(methacryloxy)-propylsulfonyl]-1-(trifluoromethanesulfonyl)imide with poly(ethylene glycol) methacrylate. A possibility has been shown for the tuning of ionic conductivity in a wide range (from 1 × 10–10 to 1 × 10–7 S cm–1, 25°C) by varying the ratio of macromolecular weights of neutral and ionic blocks and concentration of lithium monomer units in the ionic block.

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REFERENCES

  1. Yaroslavtsev, A.B., Stenina, I.A., Kulova, T.L, Skundin, A.M., and Desyatov, A.V., in: Comprehensive Nanoscience and Nanotechnology, 2nd ed., Andrews, D., Nann, T., and Lipson, R., Eds., Elsevier, Academic, 2019, vol. 5, pp. 165–206. https://doi.org/B978-0-12-803581-8.10426-6

    Google Scholar 

  2. Placke, T., Kloepsch, R., Dühnen, S., and Winter, M., J. Solid State Electrochem., 2017, vol. 21, pp. 1939–1964. https://doi.org/10.1007/s10008-017-3610-7

  3. Fan, X. and Wang, Ch., Chem. Soc. Rev., 2021, vol. 50, pp. 10486–10566. https://doi.org/10.1039/d1cs00450f

    CAS  Article  PubMed  Google Scholar 

  4. Mauger, A., Julien, C.M., Goodenough, J.B., and Zaghib, K., J. Electrochem. Soc., 2020, vol. 167, no. 7, p. 070507. https://doi.org/10.1149/2.0072007JES

    CAS  Article  Google Scholar 

  5. Chen, G., Niu, Ch., Chen, Y., Shang, W., Qu, Y., Du, Zh., Zhao, L., Liao, X., Du, J., and Chen, Y., Solid State Ionics, 2019, vol. 341, p. 115048. https://doi.org/10.1016/j.ssi.2019.115048

    CAS  Article  Google Scholar 

  6. Voropaeva, D.Yu., Novikova, S.A., and Yaroslavtsev, A.B., Usp. Khim., 2020, vol. 89, no. 10, pp. 1132–1155. https://doi.org/10.1070/RCR4956

    CAS  Article  Google Scholar 

  7. Zhang, H., Li, Ch., Piszcz, M., Coya, E., Rojo, T., Rodriguez-Martinez, L.M., Armand, M., and Zhou, Z., Chem. Soc. Rev., 2017, vol. 46, no. 3, pp. 797–815. https://doi.org/10.1039/C6CS00491A

    CAS  Article  PubMed  Google Scholar 

  8. Deng, K., Zeng, Q., Wang, D., Liu, Zh., Qiu, Zh., Zhang, Y., Xiao, M., and Meng, Y., J. Mater. Chem. A, 2020, vol. 8, no. 4, pp. 1557–1577. https://doi.org/10.1039/C9TA11178F

    CAS  Article  Google Scholar 

  9. Shaplov, A.S., Marcilla, R., and Mecerreyes, D., Electrochim. Acta, 2015, vol. 175, pp. 18–34. https://doi.org/10.1016/j.electacta.2015.03.038

    CAS  Article  Google Scholar 

  10. Voropaeva, D., Novikova, S., Xu, T., and Yaroslavtsev, A., J. Phys. Chem. B, 2019, vol. 123, no. 48, pp. 10217–10223. https://doi.org/10.1021/acs.jpcb.9b08555

    CAS  Article  PubMed  Google Scholar 

  11. Kayumov, R.R., Shmygleva, L.V., Evshchik, E.Yu., Sanginov, E.A., Popov, N.A., Bushkova, O.V., and Dobrovol’skii, Yu.A., Elektrokhimiya, 2021, vol. 57, no. 8, pp. 507–516. https://doi.org/10.31857/S0424857021060049

    Article  Google Scholar 

  12. Kayumov, R.R., Sanginov, E.A., Shmygleva, L.V., Radaeva, A.P., Karelin, A.I., Zyubin, A.S., Zyubina, T.S., Anokhin, D.V., Ivanov, D.A., and Dobrovolsky, Yu.A., J. Electrochem. Soc., 2019, vol. 166, no. 7, pp. F3216–F3226. https://doi.org/10.1149/2.0261907jes

    CAS  Article  Google Scholar 

  13. Shaplov, A.S., Vlasov, P.S., Armand, M., Lozinskaya, E.I., Ponkratov, D.O., Malyshkina, I.A., Vidal, F., Okatova, O.V., Pavlov, G.M., Wandrey, C., Godovikov, I.A., and Vygodskii, Ya.S., Polym. Chem., 2011, vol. 2, no. 11, pp. 2609–2618. https://doi.org/10.1039/c1py00282a

    CAS  Article  Google Scholar 

  14. Porcarelli, L., Shaplov, A.S., Salsamendi, M., Nair, J.R., Vygodskii, Y.S., Mecerreyes, D., and Gerbaldi, C., ACS Appl. Mater. Interfaces, 2016, vol. 8, no. 16, pp. 10350–10359. https://doi.org/10.1021/acsami.6b01973

    CAS  Article  PubMed  Google Scholar 

  15. Osada, I., Scrosati, B., and Passerini, S., Angew. Chem., Int. Ed. Engl., 2016, vol. 55, no. 2, pp. 500–513. https://doi.org/10.1002/anie.201504971

    CAS  Article  Google Scholar 

  16. Jiang, Y., Yan, X., Ma, Zh., Mei, P., Xiao, W., You, Q., and Zhang, Y., Polymers, 2018, vol. 10, no. 11, pp. 1237–1250. https://doi.org/10.3390/polym10111237

    CAS  Article  PubMed Central  Google Scholar 

  17. Sinha, K., Wang, W., Winey, K.I., and Maranas, J.K., Macromolecules, 2012, vol. 45, no. 10, pp. 4354–4362. https://doi.org/10.1021/ma300051y

    CAS  Article  Google Scholar 

  18. Perrier, S., Macromolecules, 2017, vol. 50, no. 19, pp. 7433–7447. https://doi.org/10.1021/acs.macromol.7b00767

    CAS  Article  Google Scholar 

  19. Chiefari, J., Mayadunne, R.T.A., Moad, C.L., Moad, G., Rizzardo, E., Postma, A., and Thang, S.H., Macromolecules, 2003, vol. 36, no. 7, pp. 2273–2283. https://doi.org/10.1021/ma020883+

    CAS  Article  Google Scholar 

  20. Bekanova, M.Z., Neumolotov, N.K., Jablanovic, A.D., Plutalova, A.V., and Chernikova, E.V., Polym. Sci. Ser. C, 2019, vol. 61, pp. 186–197. https://doi.org/10.1134/S1811238219010028

    CAS  Article  Google Scholar 

  21. Askadskii, A.A., Computational Materials Science of Polymers, Cambridge: Int. Sci. Publishing, 2003. p. 126.

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Funding

This work was financially supported by the Russian Science Foundation (project no. 21-13-00173). The study of polymer properties was performed using equipment of the Center for Molecular Structure Studies, Nesmeyanov Institute of Organoelement Compounds, RAS, with the support of the Ministry of Education and Science of the Russian Federation.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    D. O. Ponkratov, E. I. Lozinskaya, A. S. Shaplov, D. A. Khanin, E. S. Afanasyev, R. U. Takazova & Y. S. Vygodskii

  2. Luxembourg Institute of Science and Technology, L-4362, Esch-sur-Alzette, Luxembourg

    A. S. Shaplov

Authors
  1. D. O. Ponkratov
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  2. E. I. Lozinskaya
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  3. A. S. Shaplov
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  4. D. A. Khanin
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  5. E. S. Afanasyev
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  6. R. U. Takazova
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  7. Y. S. Vygodskii
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Corresponding author

Correspondence to D. O. Ponkratov.

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The authors declare no conflicts of interest.

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Translated by I. Kudryavtsev

The work is presented in the virtual issue “Young Scientists of the Russian Academy of Sciences.”

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Ponkratov, D.O., Lozinskaya, E.I., Shaplov, A.S. et al. Synthesis of New Lithium-Conducting Copolymers and the Influence of Their Structure and Composition on Ionic Conductivity. Dokl Chem 502, 29–36 (2022). https://doi.org/10.1134/S0012500822020021

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  • DOI: https://doi.org/10.1134/S0012500822020021

Keywords:

  • Li-conducting block copolymer
  • polymeric electrolyte
  • lithium battery
  • RAFT-polymerization